• The Journal of the Petrological Society of Korea
• /
• v.5 no.1
• /
• pp.89-107
• /
• 1996

Sr, Nd and Pb isotopic characteristics of alkaline lavas and tholeiites in Cheju Island show that the isotopic compositions of the former slightly overlap, but have relatively more depleted than the latter. However, in viewpoint of the two eruptional stratigraphies of tholeiites, the isotopic compositon of the older one is similar to those of alkaline rocks in Lava Plateau Stage after Lee (1982). These suggest that the parental magmas of alkaline lavas and tholeiites might have originated from the homogenous mantle sourve and that the characteristics of the mantle source to be partially melted might be different between the eruption stages. The isotopic signatures of the bolcanic rocks in Cheju Island overlap with those in Samoa Islands and South China Basin, indicating the DMM-EM IImixing trend. This is distingushed from the DMM-EM I trend of the Cenozoic volcanic rocks in Korea except for cheju Island and Northeastern China. The modelled binary mixing calculation between MM and EM IImaterials indicates that the mantle source of the volcanic rocks in Cheju Island has been mixed about less than 10% of enriched mantle material (EM II) with depleted mantle material (DMM). Concerned with the indentation model between North China Block (NCB) and South China Block (SCB) after Yin an Nie (1993), we suggest that the distinct isotopic features of DMM-EM I and DMM-EM IIof the Cenozoic volcanic rock in Korea as well as China can be explained by the difference of the nature of subcontinental lithospheric mantle as enriched mantle materials, i.e. EM I of NCB, while EM II of SCB.

• The Journal of the Petrological Society of Korea
• /
• v.25 no.1
• /
• pp.51-67
• /
• 2016

Geochemical characteristics of the Early Cretaceous igneous rocks from eastern China and the Gyeongsang Basin, Korean Peninsula has been summarized. They have wide range of lithological variation with extrusive picrite-basalt-andesite-trachyte-rhyolite and lamprophyre, and intrusive gabbro-diorite-monzonite-syenite-granite and diabase in eastern China, mostly belonging to the high-K calc-alkaline or shoshonitic series. The volcanic rocks intercalated with the Hayang Group sedimentary assemblages in the Gyeongsang basin are high-K to shoshonitic basaltic trachyandesites. The Early Cretaceous basaltic rocks studied mostly fall within the field of within-plate basalts on the Zr/Y-Zr and Nb-Zr-Y tectonic discrimination diagrams. On a Sr-Nd isotope correlation diagram, basaltic rocks from the North China block (NCB) and the continent-continent collision zone (CZ) between the North and South China blocks plot into the enriched lower right quadrant along the extension of the mantle array. The initial $^{87}Sr/^{86}Sr$ ratios of basaltic rocks from the South China block (SCB) are indistinguishable from those of the NCB and CZ basaltic rocks, but their ${\varepsilon}_{Nd}$ (t) values are relatively more elevated, plotting in right side of the mantle array. Basaltic rocks from the NCB and CZ are characterized by low $^{206}Pb/^{204}Pb(t)$ ratios, lying to the left of the Geochron on the $^{207}Pb/^{204}Pb(t)$ vs. $^{206}Pb/^{204}Pb(t)$ correlation. Meanwhile, the SCB basaltic rocks have relatively radiogenic Pb isotopic compositions compared with those of the NCB and CZ basaltic rocks. Basaltic rocks from the Hayang Group plot within the field of the NCB basaltic rocks in Sr-Nd and Pb-Pb isotope spaces. Metasomatically enriched subcontinental lithospheric mantle (SCLM) is likely to have been the dominant source for the early Cretaceous magmatism. Asthenospheric upwelling under an early Cretaceous extensional tectonic setting in eastern China and the Korean Peninsula might be a heat source for melting of the enriched SCLM. Metasomatic agents proposed include partial melts of lower continental crust delaminated and foundered into the mantle or subducted Yangtze continental crust, or fluid/melt derived from the subducted paleo-Pacific plate.

• The Journal of the Petrological Society of Korea
• /
• v.10 no.1
• /
• pp.27-35
• /
• 2001

The charnockite of Jirisan area occurs within the Precambrian high grade metamorphic terrane associated with anorthosite body as many foreign examples. Sm-Nd ages were determined from whole rock-garnet pairs, which turned out $1827\pm$32($2\sigma$) Ma for the massive charnockite and $1820\pm$22(2$\sigma$) Ma for the foliated charnockite with $$\varepsilon$_{Nd}(T)$ of $-5.5\pm$0.2 and $-6.0\pm$0.5 respectively. $^{87}Sr/^{86}Sr$ initial ratios calculated with the these ages are 0.71319 and 0.71532 respectively. The fact that massive and foliated charnockites show identical age, identical Nd isotopic initial ratio, and similar Sr isotopic initial ratios suggest that they were generated at the same time from the same material even through their present textures are different. Initial ratios of Nd and Sr of the charnockites are quite distinct from the mantle values indicating the influence of continental crust. Sm-Nd age determined from the titanium bearing anorthositic rocks intruding the anorthosite body, using mineral separates of garnet, plagioclase, and mafic fraction, is $1792\pm$90(2$\sigma$) Ma with $$\varepsilon$_{Nd}(T)=-3.9$\pm$0.2$. The ^${87}Sr/^{86}Sr$ initial ratios calculated with this age are 0.70616~0.70619. The charnockites and the anorthositic rocks occurring in contact each other also reveal the same age within the error, which suggest a genetic relationship between them. However, chemical compositions of the charnockites and Hadong-Sancheong anorthosites cannot be explained by igneous differentiation. Their differences in Nd and Sr initial isotopic ratios indicate different source materials. Therefore, temporal association between them suggests the possibility of the anorthosite acting as a thermal source for the generation of the charnockite as other studies.

• The Journal of the Petrological Society of Korea
• /
• v.21 no.2
• /
• pp.235-247
• /
• 2012

Peridotite xenoliths hosted by alkali basalts from South Korea occur in Baengnyeong Island, Jeju Island, Boeun, Asan, Pyeongtaek and Ganseong areas. K-Ar whole-rock ages of the basaltic rocks range from 0.1 to 18.9 Ma. The peridotites are dominantly lherzolites and magnesian harzburgites, and the constituent minerals are Fo-rich olivine ($Fo_{88.4-92.0}$), En-rich orthopyroxene, Di-rich clinopyroxene, and Cr-rich spinel (Cr# = 7.8-53.6). Hydrous minerals, such as pargasite and phlogopite, or garnet have not been reported yet. The Korean peridotites are residues after variable degree of partial melting (up to 26%) and melt extraction from fertile MORB mantle. However, some samples (usually refractory harzburgites) exhibit metasomatic enrichment of the highly incompatible elements, such as LREE. Equilibration temperatures estimated using two-pyroxene geothermometry range from ca. 850 to $1050^{\circ}C$. Sr and Nd isotopic compositions in clinopyroxene separates from the Korean peridotites show trends between depleted MORB-like mantle (DMM) and bulk silicate earth (BSE), which can be explained by secondary metasomatic overprinting of a precursor time-integrated depleted mantle. The Korean peridotite clinopyroxenes define mixing trends between DMM and EM2 end members on Sr-Pb and Nd-Pb isotopic correlation diagrams, without any corresponding changes in the basement. This is contrary to what we observe in late Cenozoic intraplate volcanism in East Asia which shows two distinct mantle sources such as a DMM-EM1 array for NE China including Baengnyeong Island and a DMM-EM2 array for Southeast Asia including Jeju Island. This observation suggests the existence of large-scale two distinct mantle domains in the shallow asthenosphere beneath East Asia. The Re-Os model ages on Korean peridotites indicate that they have been isolated from convecting mantle between ca. 1.8 and 1.9 Ga.

• Economic and Environmental Geology
• /
• v.41 no.3
• /
• pp.299-314
• /
• 2008

The NE-trending Honam shear zone is a broad, dextral strike-slip fault zone between the southern margin of the Okcheon Belt and the Precambrian Yeongnam Massif in South Korea and is parallel to the trend of Sinian deformation that is conspicuous in Far East Asia. In this paper, we report geochemical and isotopic(Sr and Nd) data of mylonitic quartz-muscovite Precambrian gneisses and surrounding foliated hornblende-biotite granitoids near the Myeongho area in the Yecheon Shear Zone, a representative segment of the Honam Shear Zone. Foliated hornblende-biotite granitoids commonly plot in the granodiorite field($SiO_2=61.9-67.1\;wt%$ and $Na_2O+K_2O=5.21-6.99\;wt%$) on $SiO_2$ vs. $Na_2O+K_2O$ discrimination diagram, whereas quartz-muscovite Precambrian orthogneisses plot in the granite field. The foliated hornblende-biotite granitoids are mostly calcic and calc-alkalic and are dominantly magnesian in a modified alkali-lime index(MALI) and Fe# [$=FeO_{total}(FeO_{total}+MgO)$] versus $SiO_2$ diagrams, which correspond with geochemical characteristics of Cordilleran Mesozoic batholiths. The foliated hornblende-biotite granitoids have molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 0.89 to 1.10 and are metaluminous to weakly peraluminous, indicating I type. In contrast, Paleoproterozoic orthogneisses have peraluminous compositions, with molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 1.11 to 1.22. On trace element spider diagrams normalized to the primitive mantle, the large ion lithophile element(LILE) enrichments(Rb, Ba, Th and U) and negative Ta-Nb-P-Ti anomalies of foliated hornblende-biotite granitoids and mylonitized quartz-muscovite gneisses in the Yecheon Shear Zone are features common to subduction-related granitoids and are also found in granitoids from a crustal source derived from the arc crust of active continental margin. ${\varepsilon}_{Nd}(T)$ and initial Sr-ratio ratios of foliated hornblende-biotite granitoids with suggest the involvement of upper crust-derived melts in granitoid petrogenesis. Foliated hornblende-biotite granitoids in the study area, together with the Yeongju Batholith, show not changing contents of specific elements(Ti, P, Zr, V and Y) from shear zone to the area near the shear zone. These results suggest that no volume changes and geochemical alterations in fluid-rich foliated hornblende-biotite granitoids may occur during deformation, which mass transfer by fluid flow into the shear zone is equal to the mass transfer out of the shear zone.

• The Journal of the Petrological Society of Korea
• /
• v.15 no.2 s.44
• /
• pp.60-71
• /
• 2006

The Seokmodo consists mainly of biotite granite and granodiorite. The biotite granite is divided into the south and the north part by granodiorite. There occurs high temperature hot spring of which temperature is up to $72^{\circ}C$. The Rb-Sr isotopic data for the biotite granite define whole-rock isochron ages of $207{\pm}70$ Ma with initial Sr isotopic ratio of 0.7132 in north part and $132{\pm}50$ Ma with initial Sr isotopic ratio of 0.7125 in south part, suggesting that the magma be derived from the crustal source material. The geochemical characteristics of the biotite granite and hornblende granodiorite indicate that they were crystallized from calc-alkaline under syn-collisional tectonic environment. The samples of hot spring were collected at March 2005 and March 2006. The $^{87}Sr/^{86}Sr$ ratios of hot spring are 0.714507 and 0.714518, respectively and correspond to those oi the granite being occurred at the south part. The similarity of $^{87}Sr/^{86}Sr$ ratios between the granite and hot spring strongly suggests that the hot spring might be derived from the Seokmodo biotite granite.

• Economic and Environmental Geology
• /
• v.31 no.2
• /
• pp.149-158
• /
• 1998

Volcanic rocks including rhyolitic tuff, rhyolite and welded tuff in the Bupyeong silver mine area form a topographic circular structure known as a resurgent caldera. Granitic rocks are emplaced inside and outside area of the circular structure. K-Ar dating and Nd-Sr isotope studies were carried out to invesitigate the origin and petrogenetic evolution of the rhyolitic and granitic magma in the Bupeong silver mine area. Whole rock K-Ar age ranges from 208 to 131 Ma for rhyolitic rocks. Radiometric ages for the granitic rocks are 167.6 Ma for pink feldspar biotite granite from inside granitic pluton of the circular volcanic body, 178.8 Ma for the Kimpo hornblende biotite granite and 111.8 Ma for the Songdo foliated granite from outside granitic plutons of the volcanic body. The radiometric age data indicates that the volcanic activities which are partly overlapped by granite plutonic activities in the Bupyeong mine area had recorded early Jurassic and early Cretaceous in age. Initial Sr and Nd isotopic ratios of the rhyolitic rocks ($^{87}Sr/^{86}Sr$=0.710~0.719 and $^{143}Nd/^{144}Nd$=0.5115~0.5118) are similar to those of granitic rocks ($^{87}Sr/^{86}Sr$=0.709~0.716 and $^{143}Nd/^{144}Nd$=0.5115~0.5116) from inside granite stock. This means that similar source materials of felsic magma responsibles for the Bupyeong volcanic rocks and inside plutonic rocks. Based on the Nd and Sr isotopic compositions, rhyolitic and granitic magmas in the Bupyeong area originated from the partial melting of the old continental crust which has Nd model age ranging from 1500 to 2900 Ma. This is analogous to those of the other Jurassic granitoids in South Korea.

• The Journal of the Petrological Society of Korea
• /
• v.9 no.3
• /
• pp.121-141
• /
• 2000

Granitic and pophyroblastic gneisses are widely distributed in the Seungju-Suncheon area, the southwestern part of the Sobacksan Massif. Two groups of metamorphic P-T conditions are recognized from granitic gneiss. $622-760^{\circ}C/6.2~7.4\;kbar$(Group I) are estimated from garnet cores and samples with weak retrograde metamorphism. $606~785^{\circ}C/3.7~5.4\;kbar$(Group II) are estimated from garnet rims which have lower pyrope and higher spessartine contents due to the effect of retrograde metamorphism. The metamorphic P-T conditions estimated from porphyroblastic gneiss are $489~669^{\circ}C$, 2.1~4.8 kbar which are similar to the P-T conditions of Group II in the granitic gneiss. The whole rock-garnet Sm/Nd isotopic ages determined from granitic and porphyroblastic gneisses are, respectively, $1417{\pm}52\;Ma\;and\;1421{\pm}14\;Ma$. These date indicate that intermediate-P/T type metamorphism represented by Group I may have occurred between the intrusion of granite gneiss and the intrusion of porphyroblastic gneiss(between 1890 Ma~2120 Ma) and two gneisses experienced low-P/T type metamorphism after the intrusion of porphyroblastic gneiss at 1417~1421 Ma.

• Ocean and Polar Research
• /
• v.45 no.2
• /
• pp.89-102
• /
• 2023

Climate and environmental changes in the Arctic Ocean due to global warming have been linked to extreme climate change in mid-latitude regions, including the Korean Peninsula, requiring a better understanding of the Arctic climate system based on the paleo-analog. This review introduces three paleoenvironmental research cases using neodymium isotopes (¹⁴³Nd/¹⁴⁴Nd, ε_Nd) measured on two different fractions of marine sediments: silicate-bound 'detrital' and Fe-Mn oxide-dominated 'authigenic' fractions. In the first case, detrital ε_Nd in core HH17-1085-GC on the continental shelf off northern Svalbard was used for tracing changes in sediment provenance and associated glacier behavior over the last 16.3 ka. The second case showed the potential use of authigenic ε_Nd as a quasi-conservative water mass tracer. Three prominent ε_Nd peaks and troughs observed in core PS72/410-1 from the Mendeleev Ridge in the western Arctic Ocean over the past 76 ka suggested episodic meltwater discharge events during 51~46, 39~35 and 21~13 ka BP. The last case proposed the use of the difference between authigenic and detrital ε_Nd as a proxy for reconstructing glacier fluctuation. The idea is based on the assumption that enhanced glacial erosion during glacier advances can supply sufficient freshly-exposed rock substrate for incongruent weathering, potentially leading to greater isotopic decoupling between bedrock and dissolved weathering products as recorded in detrital and authigenic ε_Nd, respectively. Thus, it would be worthwhile to take advantage of sedimentary ε_Nd to improve our understanding of past environmental changes in polar regions.

• Nuclear Engineering and Technology
• /
• v.25 no.2
• /
• pp.259-264
• /
• 1993

Ion chromatographic method has been applied for burnup measurement of irradiated nuclear fuel by dynamic system using 1-octanesulfonate as a cation exchanger and $\alpha$-hydroxyisobutyric acid as an eluant. A number of elution techniques were evaluated for the optimum separation of plutonium, uranium and neodymium. These elements were individually separated and collected by gradient elution between 0.05 M and 0.40 M of $\alpha$-hydroxyisobutyric acid in a single column, and finally determined by isotope dilution mass spectrometry. The burnup data from this method were compared with those from conventional anion exchange method. The results showed a good agreement within 3.5 % of difference between two methods.