• Title/Summary/Keyword: Nd$_2$O$_3$

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Calcium Aluminate Phosphor Supported $TiO_2$ Nanoparticles (산화(酸化)티탄 나노입자(粒子)가 담지(擔持)된 칼슘 알루미늄 형광체(螢光體))

  • Thube, Dilip R.;Kim, Jin-Hwan;Kang, Suk-Min;Ryu, Ho-Jin
    • Resources Recycling
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    • v.18 no.4
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    • pp.24-30
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    • 2009
  • Rare earth based calcium aluminate phosphor ($CaAl_2O_4:Eu^{2+}$, $Nd^{3+}$) supported $TiO_2$ nanoparticles are synthesized by using sol-gel method, which are further characterized using powder X-ray diffraction (XRD), fourier transform infrared (FT-IR), diffuse reflectance UV-Visible spectroscopy (DRS UV-Vis) and transmission electron microscopy (TEM). The XRD pattern of as-prepared and sintered phosphor supported $TiO_2$ does not show the tendency to change the crystal structure from anatase to rutile phase up to $600^{\circ}C$. This indicates that the phosphor support might inhibit the densification and crystallite growth by providing dissimilar boundaries. The diffuse reflectance spectral (DRS) measurements showed shift towards longer wavelength indicating reduction in the band-gap energy as compared to free $TiO_2$. The FT-IR spectra of phosphor supported $TiO_2$ nanoparticles show shift in the peak positions to lower wavelengths. This indicates that the $TiO_2$ nanoparticles are not free, but covalently bonded to the phosphor support. TEM micrographs show presence of crystalline and spherical $TiO_2$ nanoparticles (8 - 15 nm diameter) dispersed uniformly on the surface of phosphor.

Structural Diversity of Five New Lanthanide Coordination Polymers Tuned by Different Salt Anions

  • Tao, Yinhua;Lou, Yongbing;Li, Yang;Chen, Jinxi
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1417-1421
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    • 2014
  • Five new lanthanide coordination polymers, $[Ln_2(1,4-NDC)_2(1,4-HNDC)_2(phen)_2]_n$ (Ln = Er (1), Yb (2)), and $[Ln_2(1,4-NDC)_3(phen)_2(H_2O)_2]_n$ (Ln = Nd (3), Gd (4), Er (5)) ($1,4-H_2NDC$ = 1,4-naphthalenedicarboxylic acid, phen = 1,10-phenanthroline), have been successfully prepared via the reaction of corresponding trivalent lanthanide salt, $1,4-H_2NDC$ and phen in the presence of NaOH and pyridine under hydrothermal condition. Pyridine plays a key role in the synthesis of these lanthanide coordination polymers. Single-crystal X-ray diffraction analyses indicate that compounds 1-5 all form a 2-D network while different salt anions result in the diversity of crystal structures. These lanthanide coordination polymers showed a considerable thermal stability in TGA analyses.

An experimental study of heat transfer in a submerged water jet (서브머지드 단일수분류의 열전달에 관한 실험적 연구)

  • Ohm, Ki-Chan
    • Journal of the Korean Solar Energy Society
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    • v.25 no.4
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    • pp.101-110
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    • 2005
  • An experimental study of heat transfer of submerged water jet impinging normally on a flat plate is presented. Heat transfer measurements obtained with Reverse cone type nozzle(Rcone) were compared to those obtained with Cone type nozzle(Cone) and Square edged type nozzle(Vert) of the same diameter(D=8mm) for different jet velocities in the range of $3{\sim}7m/s(Re_D=30000{\sim}70000)$ and various nozzle-to target spacings($H/D=2{\sim}10$). The local Nusselt number profiles exhibited a sharp drop for $r/D{\leq}0.5$ and 2nd, 3rd peaks revealed at r/D=2, 3 respectively, followed by a slower decrease there after. The peaks were weakened with increasing the nozzle-to target spacing and decreasing the jet velocity. The stagnation Nusselt number of the Reverse cone type nozzle was larger than those of the other two nozzles for H/D=2. 10, but Cone type nozzle had the highest value for $H/D=4{\sim}8$. Also average Nusselt number of the Reverse cone type nozzle was higher than those of the other two nozzles at $H/D=2{\sim}10$, except for $V_o=7ms$ of H/D=6.

Comparison of Dry Matter Production in Reed canarygrass Varieties (Reed canarygrass 품종의 건물 생산성 비교)

  • 이주삼;류수훈;이경은
    • Asian Journal of Turfgrass Science
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    • v.7 no.2_3
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    • pp.121-127
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    • 1993
  • This experiment was carried out to compare the varietal differences of dry matter production in rend canarygrass. The varieties examined were Common, Venture, Castor, Palaton and Venture. Reed canarygrass was harvested three times annually, 1st cut(1O, May), 2nd cut(31, July), and 3rd cut(10, Oct.), respectively. The results were summarized as follows ; 1. Dry matter yield were not significant difference between varieties and for the interaction of variety$\times$cut. But, there was significant difference between cuts. 2. There was not significant difference in dry matter yield between the first cut and second cut. But, the dry matter yield of the third cut was poor than the other two cuts. Thus, the average dry matter yield of varieties were 806.1 kg, 730.8kg and 495.8kg /l0a in the first, second and third cut, respectively. 3. In Venture and Palaton, the percentage of dry matter distribution in spring was higher than that of other varieties. In Common, Castor and Vantage, they were not significantly different between the percentage of dry matter distribution in each cut. Above the results suggested that the first group of varieties(Venture and Palaton) were suited to meadow and last group of varieties(Common, Castor and Vantage) were suited to pasture. 4. Average total dry matter yield of varieties was 2,032kg /l0a/yr,(ranged from 1,922kg to 2,180 kg /l0a /yr.)

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Laser beam Surface Modification(1): Non-melting Processes (Laser beam 표면개질 (I) : 비용융에 의한 표면개질)

  • 김정수;서정훈
    • Journal of Welding and Joining
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    • v.15 no.5
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    • pp.25-35
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    • 1997
  • 현재, 표면개질에 주로 많이 사용되는 레이저는 세 종류로서, C $O_{2}$$laser(파장길이:10.6.\mum),$ Nd:YAG(neodymium-doped yettrium aluminum garnet) $laser(파장길이:1.06.\mum)$ 및 excimer laser(157~350nm) 등이다. 이 외에도 초기에는 ruby레이저빔이 사용되기도 하였으나, 현재는 많이 사용되고 있지 않다. 레이저 빔에 의한 표면개질에는 몇가지 장점이 있는데, 이러한 장점은 주로 급속가열과 급속냉각 효과에 기인하는 것이다. 즉, 1) 급냉효과에 의한 미세한 결정입자 형성, 2) 불안정상 (metastable phase) 또는 비정질 상 생성, 3) 열역학적 용해도 보다 높은 용해도. 4) 편석이 없는 균질한 미세조직, 5) 극히 낮은 기공도, 6) 좁은 열영향 부위, 7) 표면층과 모재 사이의 높은 결합력 등이다. 이 외에도 공정상의 장.단점들이 Ref.5, 6에 잘 요약 정리되어 있다. 지금까지 국내에서 레이저 표면개질에 대한 조사가 몇몇 있었으나, 본 조사에서는 보통 많이 다루어지지 않은 부분, 즉 충격경화 및 표면제어에 비중을 두었으며, 비용융 부분(I)과 용융부분(II)을 분리하여 정리하였다.

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The Relationship Between Hope, Health Locus of Control & General Health of Nursing Students (간호학생의 희망과 건강통제위, 건강상태와의 관계 연구)

  • Park Chun-Ja
    • The Journal of Korean Academic Society of Nursing Education
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    • v.4 no.2
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    • pp.159-171
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    • 1998
  • The purpose of this study is to explore the relationships between hope, health locus of control and general health of nursing students. The subjects of this study were 161 female students of National Nursing School in Seoul. Data was collected through a questionnaire from May 11 to May 23, 1998. The tools used for this study were Hope scale developed by Miller and Power, Multidimensional Health Locus of Control Scale developed by Wallston and Wallston and General Health Scale(Modified Conel Medical Index) developed by Nam Ho Chang. Data were analysed in an the $SPSS/pc^+$ program using frequency for the demographic characteristics, 1-test and ANOVA for relationship between the variables and demographic characteristics and for it's differences of hope and general health control. Peason correlation coefficient for relationship between the 3 variables, hope, health locus of control, and general health. The results of this study were as follows ; The 1st hypothesis : that 'Between hope, health locus of control (HLC) and general health of nursing students will have positive relationship', was supported(=.2883, p=.000). The 2nd hypothesis; that 'The hope score of nursing students in HLC-internal group will be higher than others' was supported(F=5.22, p=.0063). The 3rd hypothesis ; that 'The general health of nursing students in HLC -internal group will be higher than others' was accepted(F=2.94, p=.0554). The 4th hypothesis ; that 'Hope, HLC and general health of nursing students according to demographic characteristics will be different ' was accepted in part. o In hope the more age, the higher score. o In HLC the group of non religious have higher score(t=-2.02, p=.045). o No experienced addmission was revealed HLC-internal group(t=-1.91, p=.058). o Non religious group has a tendency to dependent upon on powerful other person(t=-1.99, p=.049). o The hope score of nursing students was very high(4.49/6point). o The general health status of nursing students was vert good(92.88/114point). o Most of nursing students was in HLC-internal group(81.4%). o The most frequent complaints of nursing students was dizziness suddenly developed(68.4/114point), very nervous in small thing(67.83/114) and very nervous to others critics(68.4/114) in turn. In conclusion, the students who have high score of hope, in HLC-internal group have good general health. Hope inspiring not only makes one's good health but also makes others good health and powering hope. For good health person who are in HLC-internal group have powerful hope, keeping good health would be a good stretegy to change the student's HLC and make them good health and hope powering then it would be a good method to change the HLC to HLC-internal group.

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A Frequency Adjustable Double Lorentz CRLH Transmission Line using DGS (DGS를 이용한 주파수 가변 DL-CRLH 전송선로)

  • Lim, Jong-Sik;Lee, Jae-Hoon;Lee, Jun;Jeong, Yong-Chae;Han, Sang-Min;Ahn, Dal
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.8
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    • pp.1429-1435
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    • 2010
  • In this paper, a double lorentz composite right left handed(DL-CRLH) transmission line is designed using defected ground structure (DGS) and varactor diodes. Previously, the diode has been adopted only selectively for one of parallel or series resonators, and the balanced frequency as well as triple band frequencies were fixed. However in the proposed DL-CRLH transmission line, the balanced frequency, where the resonant frequencies of the series-connected parallel resonator and shunt-connected series resonator are the same, is adjustable. In addition, the triple band frequencies are controlled, too. The measured balanced frequency varies between 3.42~4.8GHz according to the controlled bias voltage. Under the same bias condition for the balanced frequency, the adjusted frequencies are 2.22~2.77GHz, 3.7~5.2GHz, 7.32~8.23GHz, 3.42~4.8GHz, and 4.44~5.92GHz for the conditions that ${\beta}d=+0.5{\pi}$, $-0.5{\pi}$, 2nd $+0.5{\pi}$, ${\omega}_{\infty}$, and ${\omega}_o$, respectively.

ANISOTROPY CONSTANTS OF $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ COMPOUNDS (RE=RARE EARTH)

  • Kim, H.T.;Kim, Y.B.;Park, W.S.;Kim, C.S.;Kim, T.K.;Jin, Han-Min
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.683-686
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    • 1995
  • Using by the x-ray diffractometry(XRD), the thermomagnetic analysis(TMA), a scanning electron microscopy (SEM-EDX), we knew that the $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ (RE=Ce,Pr,Nd,Sm,Gd,Tb) compounds were formed to tetragonal $ThMn_{12}$-type structure having a uniaxial magnetocrystalline anisotropy with easy magnetization c-axis. The intrinsic magnetic properties of those were determined by fitting the two magnetization curves of experimental and calculation magnetization. The anisotropy constant $K_{1}$ of this compounds was in the range of $1.75\;-\;9.2\;MJ/m^{3}$ and approximately one order higher than $K_{2}$. $SmFe_{11}Ti$ had the highest anisotropy of $K_{1}\;=\;9.2\;MJ/m^{3}$, $K_{2}\;=\;0.4\;MJ/m^{3}$ and ${\mu}_{o}H_{A}=\;19.8\;T$ among the compounds, substitution of any other rare earth elements for Sm decreased magnetocrystalline anisotropy.

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Filtration of dispersed nanoparticles using cyclone and ultrasonic atomization (초음파 무화 및 사이클론을 이용한 분산된 나노입자의 여과법)

  • Jung, Jihee;Kim, Moojoon;Kim, Jungsoon
    • The Journal of the Acoustical Society of Korea
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    • v.41 no.1
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    • pp.9-15
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    • 2022
  • In order to overcome the limitation of conventional nanoparticle dispersion methods such as sonicator or homogenizer, a filtration method using an ultrasonic atomization effect and cyclones was proposed in this study. A 0.5 wt% suspension was made with Al2O3 powder with an average diameter of 250 nm. The suspension was filtered by the proposed method after pre-dispersing using a sonicator and a homogenizer, respectively. As the result, in the case of the suspension after pre-dispersing with a sonicator, the particle size distribution of the filtered suspension started showing up a single normal distribution indicating the mode of the average diameter only after the 3rd cyclone process. On the other hand, in the case of the suspension with the homogenizer pre-dispersion, similar results appeared from the 2nd cyclone process. Filtration of various types of nanoparticles is expected to be possible by adjusting ultrasonic atomization frequency and manipulating the design of the cyclone.

Natural Background and Enrichment Characteristics of the Stream Sediments from the Hamyang-Sancheong Area (함양-산청지역 하상퇴적물의 자연배경치 및 부화특성)

  • Park, Young-Seog;Park, Dae-Woo;Kim, Jong-Kyun
    • Economic and Environmental Geology
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    • v.42 no.3
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    • pp.195-206
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    • 2009
  • We investigated natural background and enrichment characteristics and predicted geochemical disaster for stream sediments in the Hamyang-Sancheong area. Stream sediments samples were collected 95 ea in study area. The stream sediments were well known that had not possibility of contamination effect and represented drainage basins. We got the major and hazardous elements concentrations by XRF, ICP-AES and NAA analysis methods. Acid decomposition for the ICP-AES has been used $HClO_4$ and HF with $200^{\circ}C$ heating at 1st and after that $HClO_4$ HF and HCl with $200^{\circ}C$ heating at 2nd stage. We could know the characteristics that concentration of Cu and Co decreased when concentration of $SiO_2$ increased in correlation analysis. The enrichment factor of the stream sediments was below 2 in study area. This result indicated that study area belonged to moderate enrichment. The stream sediments of Hamyang area were enriched in order of Pb>Th>Cr>V>Co>Cu and those of Sancheong area were enriched in order of Pb>Th>Cr>Co>V>Cu. The enrichment factor(E.F.) of the Pb, Cr, Co and V was similar between Hamyang and Sancheong area. The enrichment factor of the Th was higher in Hamyang area and that of the Cu was higher in Sancheong area. The enrichment factor of the Pb was highly enriched in all study area than earth crust mean. But we could know that study area was not exposed to the pollution of the Pb through the tolerable level.