• Bulletin of the Korean Chemical Society
• /
• v.15 no.5
• /
• pp.353-356
• /
• 1994

The $CN(B^2{\Sigma}^+)$ radical was produced in a jet using an electric dc discharge of the precursor $CH_3CN$ with inert carrier gases. The rotationally resolved Fourier transform emission spectra of the 0-0 band of the $(B^2{\Sigma}^+{\to}X^2{\Sigma}^+)$ transition of CN have exhibited different distribution of the intensity for the carrier gases He and Ar, respectively. From the analysis of intensity distribution in the spectra, the mechanism for rotational cooling process of CN radical in a supersonic expansion has been suggested.

• The Research Journal of the Costume Culture
• /
• v.11 no.1
• /
• pp.66-74
• /
• 2003

This study is to improve the worst lightfastness of a natural dye. To modify the fiber surface, low temperature oxygen plasma was carried out on silk fabric. The result is followed below after the examination of surface shape, dyeability, color change, UV absorbent influence and lightfastness. 1. When electric discharge outputs are 60W, 80W and 100w, and processing times are 10minutes, 20minutes and 40minutes, the etching effect of surface increased as electric discharge outputs and processing times increased. 2. When examined UV absorbent for 5hours, 10hours, 20hours, 40hours and 80hours, the value changes of E are 1.47, 2.51, 2.91, 3.71, 4.51 and 5.31 in case of Al pre-mordanting/ prasma 80W, 20min./ UVabsorbent 5% (100:1), 2.31, 2.47, 3.84, 3.90, 3.61 and 4.42 in case of Al pre-mordanting/prasma 80W, 20min.1 UV absorbent 5% (o.w.f.). The lightfastness decreased when UV absorbent increased. 3. Dyeability of the samples pre-treated with five different methods was in the following order: plasma processing for 20minutes at 60W/Al pre-mordanting > Al pre-mordanting > plasma processing for 20minutes at 60W > Al after-mordanting. non mordanting Plasma treatment had superior effect on dyeability. 4. When UV absorbent was applied in fabric, the sample under higher electric discharge out puts showed more effective in improving lightfastness.

• Water for future
• /
• v.24 no.2
• /
• pp.109-119
• /
• 1991

The river-bed variation and the sediment transport in an alluvial stream are very complicated physical phenomena, especially in a stream where the dam construction prevents the supply of earth and sand from upper tributaries Therefore, the mathematical modeling is needed to establish. The purpose of this study is to apply river-bed variation to the Han River downstream by the conception of gradually varied unsteady flow instead of that of steady flow in order to decrease errors. For the variation and forecast of river-bed, the numerical analysis has been made in this study by way of discharge variation and river-bed variation. In conclusion, the numerical analysis shows that river-bed variation, sediment transport , and their forecast have similarity to natural phenomena and that river-bed variation is greatly affected in sediment transport by discharge variation and retention time(duration). Therefore, the errors of numerical analysis can be reduced by the application of flood data instead of continuous discharge data.

• Water for future
• /
• v.29 no.1
• /
• pp.181-190
• /
• 1996

Quantitative computation of sediment discharge in alluvial channels is conducted by the determined method based on the incipient motion or the sediment transport concept. The derived formulation of sediment concentration in this study was developed in order to compute the total sediment discharge by a regression analysis method, one of the determined methods by the sediment transport concept. The used data set in derived formulation consists of the total 360 data including 135 and 225 measured data in natural channels and experimental channels, respectively. Also, the formulation by the multiple regression analysis was composed of independent bariables of flow depth, mean velocity, channel slope, Froude number and median diameter in bed materials.

• Journal of Ocean Engineering and Technology
• /
• v.36 no.4
• /
• pp.211-216
• /
• 2022

Since liquefied natural gas (LNG) is imported in a liquid state of about -162℃ to increase transportation efficiency in Korea, it must be vaporized in a gaseous state to supply it to consumers. Among them, ambient air vaporizer (AAV) has caught attention due to eco-friendly and low costs characteristics. However, there is a disadvantage that the performance of the heat exchanger is deteriorated due to frost due to mist and icing when used for a long time. In this paper, frost generation model in AAV vaporizer was investigated with numerically to examine utilizing the vaporizer performance with the frost generation behavior. The frost generation behavior of AAV vaporizers was examined with humidity, fin characteristic, and temperature effects. As for the LNG discharge temperature, the 12 fin vaporizer showed the highest discharge temperature when the atmospheric temperature was 25℃, and the 8 fin vaporizer had the lowest LNG discharge temperature when the atmospheric temperature was 0℃. In the case of frost formation, in the case of the 12 fin vaporizer, it was formed the most at the atmospheric temperature of 25℃, and the least was formed in the vaporizer at the 0℃ condition of the atmospheric temperature of 8 fins.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2006.05a
• /
• pp.613-617
• /
• 2006

Bed material in natural streams is affected by geological characteristics of upstream and acting focre by flow of stream. Acting force in streams are also affected by bed slope and discharge of streams. Yamamoto(1994) suggested that channel reaches with similar slope share similar characteristics values in representative bed material size, tractive force, channel width and depth. He also suggested that main factors dominating channel characteristics are mean annual discharge, epresentative bed material size and bed slope. Bed material shows physical and ecological characteristics of channels. In this research, characteristics of bed material in natural or close to natural streams were studied and compared with Janpanese stream data. In the result, characteristics of gravel and sand material can be presented in the term of non-dimensional tractive force, bed slope and bed material size.

• Journal of the Korean Applied Science and Technology
• /
• v.28 no.1
• /
• pp.85-94
• /
• 2011

Expanded graphites were used as anode materials of high power Li-ion secondary battery. The expanded graphite was prepared by mixing the graphite with $HClO_4$ as a intercalation agents and $KMnO_4$ as a oxidizing agents. The physical and electrochemical properties of prepared expanded graphites through the variation of process variables such as contents of intercalation agent and oxidizing agent, and heat treatment temperature were analyzed for determination of optimal conditions as the anode of high power Li-ion secondary battery. After examing the electrochemical properties of expanded graphites at the different preparing conditions, the optimal conditions of expanded graphite were selected as 8 wt.% of oxidizing agent, 400 g of intercalation agent for 20 g of natural graphite, and heat treatment at $1000^{\circ}C$. The sample showed the improved charge/discharge characteristics such as 432 mAh/g of initial reversible capacity, 88% of discharge rate capability at 10 C-rate, and 24 mAh/g of charge capacity at 10 C-rate. However, the expanded graphite had the problems of potential plateaus like natural graphite and lower initial efficiency than the natural graphite.

• Ocean and Polar Research
• /
• v.36 no.2
• /
• pp.87-101
• /
• 2014

Recently, more attention has been paid to the geomorphological changes in the Nakdong River Estuary, because those changes are caused by artificial activities including weirs, reclamation and construction. In order to analyze quantitatively the recent geomorphological variability in the Nakdong River Estuary, we surveyed the depth and elevation of submarine topography near Jinwoodo and Sinjado from March 2007 to February 2012. A statistical method (based on Digital Shoreline Analysis System) and an Empirical Orthogonal Functions method were used to evaluate the morphological changes. According to the statistical variables (DCE, NDC, EPR, LRR), the highest amount and rate of accumulation were recorded around the Gadeokdo whereas the greatest amount of erosion appeared around the coast off the eastern part of Sinjado. In particular, a dynamic variation of morphology was clearly observed in the vicinity of the sub-tidal channel located between Jinwoodo and Sinjado, which seems to be attributable to channel migration. As a result of the EOF method, the first mode (48.7%) is most closely related to the pattern of morphological variability that might be associated with the westerly movement of sediment by longshore current. The spatial variability of the second mode (16.6%) was high in the shoreface of Sinjado, showing a 4-year periodicity of temporal variability. The strong correlation (coefficient 0.73) between the time coefficient and suspended sediment discharge from Nakdong River emphasizes the role of sediment discharge to deposition in this area. The spatial variability of the third mode (11.3%) was distributed mainly around the coast off the eastern part of Sinjado, which is related to the movement of the coastline of Sinjado. Based on the last 5 year's data, our results suggest that the study area is characterized on the whole by a depositional pattern, but the extent of sedimentation is different locally.

• Korean Chemical Engineering Research
• /
• v.57 no.5
• /
• pp.672-678
• /
• 2019

The electrochemical properties of pitch-coated natural graphite(NG) were investigated as an anode for lithium-ion batteries. The anode materials were prepared by heat-treatment of mixture of NG and petroleum pitch at $1000^{\circ}C$. The pitches with various softening points were used as carbon precursor. The physical properties of anode materials were analyzed by TGA, SEM, PSA and BET. As the softening point increased, the thickness of the coating layer increased and the specific surface area decreased. The electrochemical performances were investigated by initial charge/discharge efficiency, cycle stability, cyclic voltammetry, rate performance and electrochemical impedance spectroscopy. The carbon-coated NG using pitch with softening points of $250^{\circ}C$ showed an initial discharge capacity of 361 mAh/g and a coulombic efficiency of 92.6%. Also, the rate performance(5 C/0.2 C) was 1.6 times higher than that of NG, and it had a capacity retention (90%) after 50 cycles at 0.5 C.

• Proceedings of the SAREK Conference
• /
• 2007.11a
• /
• pp.105-112
• /
• 2007

Recently developed raised floor heating system is not only capable of basic function to reduce noise between floors, but also is a multi-functional floor heating system enabling natural ventilation. The procedure of this system for natural ventilation is to import outdoor air through bottom space of the floor heating system, circulate indoor space and discharge it out of ceiling. In winter, powerless natural ventilation is possible with buoyancy effect caused by temperature difference between outdoor and indoor. And it also allows saving of energy by importing pre-heated air in bottom space of the floor heating system. To evaluate ventilation performance of this system, on-site measurement was conducted in 2 test laboratories, and the nominal air change rate was satisfied as 0.4$\sim$0.8 h-1 under the condition of outdoor temperature $5^{\circ}C{\sim}-5^{\circ}C$, which was evaluated as highly possible to be applied as a natural ventilation system in multi-family houses.