• Title/Summary/Keyword: Nano fillers

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A Review on the Flammability and Flame Retardant Properties of Natural Fibers and Polymer Matrix Based Composites

  • Prabhakar, M.N.;Shah, Atta Ur Rehaman;Song, Jung-Il
    • Composites Research
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    • v.28 no.2
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    • pp.29-39
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    • 2015
  • Natural fibers reinforced polymer composites are being used in several low strength applications. More research is going on to improve their mechanical and interface properties for structural applications. However, these composites have serious issues regarding flammability, which are not being focused broadly. A limited amount of literature has been published on the flame retardant techniques and flammability factor of natural fibers based polymer matrix composites. Therefore, it is needed to address the flammability properties of natural fibers based polymer composites to expand their application area. This paper summarizes some of the recent literature published on the subject of flammability and flame retardant methods applied to natural fibers reinforced polymer matrix composites. Different factors affecting the flammability, flame retardant solutions, mechanisms and characterization techniques have been discussed in detail.

Facile mass production of thermally reduced graphene oxide

  • Lee, Seung-Jun;Park, Sung-Jin
    • Carbon letters
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    • v.13 no.1
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    • pp.48-50
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    • 2012
  • Mass production of graphene-based materials, which have high specific surface area, is of importance for industrial applications. Herein, we report on a facile approach to produce thermally modified graphene oxide (TMG) in large quantities. We performed this experiment with a hot plate under environments that have relatively low temperature and no using inert gas. TMG materials showed a high specific surface area (430 $m^2g^{-1}$). Successful reduction was confirmed by elemental analysis, X-ray photoelectron spectroscopy, thermogravimetic analysis, and X-ray diffraction. The resulting materials might be useful for various applications such as in rechargeable batteries, as hydrogen storage materials, as nano-fillers in composites, in ultracapacitors, and in chemical/bio sensors.

Improvement Field Emission Uniformity in Carbon Nanotube Composite using Zinc Nano-Fillers

  • Jeon, Sung-Yun;Park, Jae-Hong;Lee, Jong-Hak;Shin, Jun-Ho;Park, Sung-Min;Prashant, Alegaonkar;Yoo, Ji-Beom
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.772-774
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    • 2007
  • The improvement in the field emission parameters, luminescent uniformity, degradation rate and half life has been observed for the thin-multi wall carbon nanotube (t-MWCNT) composite, after incorporating the Zn nanoparticles. The Zn nanoparticles $(diameter\;{\sim}\;100\;{\pm}15\;nm)$ has been incorporated to synthesize the Zn-t-MWCNT composite.

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Electrical Properties of Silicone Rubber Filled with Surface Treated Alumina Trihydrate

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.3
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    • pp.134-140
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    • 2006
  • The effect of surface treatment of fillers on the mechanical, electrical properties, and tracking performance of silicone rubber insulators have been investigated. For base polymer, $\alpha,\;\omega$) vinyl poly(dimethyl-methylphenyl) siloxane(VPMPS) containing dimethyl siloxane and methylphenyl siloxane was prepared by the equilibrium polymerization. High voltage silicone rubber composites(HVSRC) were prepared from VPMPS, nano-silica, and alumina trihydrate (ATH) modified by various coupling agents. Bound rubber of uncured silicone rubber, cross-linking density of the vulcanizate as well as the mechanical, electrical properties, and tracking performance were measured.

Preparation and Properties of in situ Polymerized Poly(ethylene terephthalate)/Fumed Silica Nanocomposites

  • Hahm, Wan-Gyu;Myung, Hee-Soo;Im, Seung-Soon
    • Macromolecular Research
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    • v.12 no.1
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    • pp.85-93
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    • 2004
  • We have prepared poly(ethylene terephthalate) (PET) nanocomposites filled with two different types of fumed silicas, hydrophilic (FS) and hydrophobic (MFS) silicas of 7-nm diameter, by in situ polymerization. We then investigated the morphological changes, rheological properties, crystallization behavior, and mechanical properties of the PET nanocomposites. Transmission electron microscopy (TEM) images indicate that the dispersibility of the fumed silica was improved effectively by in situ polymerization; in particular, MFS had better dispersibility than FS on the non-polar PET polymer. The crystallization behavior of the nanocomposites revealed a peculiar tendency: all the fillers acted as retarding agents for the crystallization of the PET nanocomposites. The incorporation of fumed silicas increased the intrinsic viscosities (IV) of the PET matrix, and the strong particleparticle interactions of the filler led to an increased melt viscosity. Additionally, the mechanical properties, toughness, and modules of the nano-composites all increased, even at low filler content.

Application of concrete nanocomposite to improvement in rehabilitation and decrease sports-related injuries in sports flooring

  • Hao Wang;Huiwu Zhang
    • Advances in concrete construction
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    • v.15 no.2
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    • pp.75-84
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    • 2023
  • Currently, polymer matrix nanocomposites (PMCs) are a prominent area of research due to their outstanding mechanical, thermal, and durability properties. The increase in recent studies justifies the possibility of using PMCs in structural retrofitting and reconstruction of damaged infrastructure and serving as new structural material. Using nanotechnology, nanocomposite panels in flooring combine concrete and steel, providing a very high level of performance. In sports flooring, high-performance concrete has become a challenge for reducing sports injuries and refinement in rehabilitation. As a composite material, this type of resistant concrete is one of the most durable and complex multi-phase materials. This article uses polyvinyl alcohol polymer (PVC) and multi-walled carbon nanotubes as concrete matrix fillers. Solution methods have been used for dispersing PVC and carbon nanotubes in concrete. The water-cement ratio, carbon nanotube weight ratio, and heat treatment parameters influenced the concrete nanocomposite's tensile and compressive strength. The dispersion of carbon nanotubes in cement paste and the observation of nano-microcracks in concrete was evaluated by scanning electron microscope (SEM).

Preparation of Urethane Nanocomposites with Inorganic Nano Fillers and Their Physical Properties (무기계 나노분말 충전 폴리우레탄 나노복합재료의 제조 및 물성)

  • Yang Yun-Kyu;Hwang Taek-Sung;Hwang Eui-Hwan
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.129-134
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    • 2006
  • Nanocomposites of polyurethane were prepared from inorganic nano particles, $Na^+-montmorillonite$ (MMT), silica, $CaCO_3$, and surface modified MMT and their properties were investigated. It was shown that the molecular weight and polydispenity of nanocomposites of polyurethane were 20000 to 28000 and 1.0 to 2.0, respectively. d-Spacing for nanocomposites of MMT were increased than that of pure MMT. Initial degradation temperature of nanocomposites were 250 to $280^{\circ}C$. And also, the range of weight loss for nanocomposites were decreased and the end of thermal degradation was observed at higher temperatures about $50^{\circ}C$. The elongation at break for $CaCO_3$ filled nanocomposites were the highest among the nanocomposites used in this study. studied. It was found that the tensile strength increased with increasing the filler contents while the silica nanocomposite exhibited the lowest increase and the $CaCO_3$ nanocomposite the highest.

The Characterization and Coatings on 304 Stainless Steel by Laser Induced Fluorescence Spectroscopy using the High Resolution Charge Coupled Device (레이저 유도형광분광기에서 고정밀 전하장치를 이용한 304 스테인레스 스틸의 코팅과 특성)

  • Kim, Ki-Jun;Lee, Jou-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.385-390
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    • 2016
  • In our study, ceramics coatings by additives of nano alumina and magnesia have cured on 304 stainless steel at $170^{\circ}C$ 2h. We designed and experimented the coated specimens that were characterized by laser induced fluorescence spectroscopy using the charge coupled device and scanning electronic microscopy(SEM). The result was revealed the ceramic coatings added fillers has more excellent on adhesive property and scratch resistance, and less weight loss in acid solution than ceramic coatings non-added fillers. Therefore, this study has designed and manufactured the electromagnetic spectrometry with CCD and then analyzed the coatings on 304 stainless steel using the High Resolution Charge Coupled Device in improving the corrosion resistance of 304 stainless steel. Nowadays, coatings of stainless steel have increased by industrial demand in hygienes, aviation, instrumentations and robotics as the industry special application develops.

Organic-Inorganic Hybrid Materials Technology for Gas Barrier (가스 차단을 위한 유.무기 하이브리드 소재기술)

  • Kim, Ki-Seok;Pa가, Soo-Jin
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.112-117
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    • 2011
  • Recently, high growth potential of barrier materials industry including high performance packing materials was expected with increasing the national income and well-being culture. As high barrier materials, polymer nanocomposites have considerable attractions due to their excellent physical properties compared to conventional composite materials. In general, polymer nanocomposites were consisted of polymer matrix and inorganic fillers, such as layered silicate, carbon nanotubes, and metal- or inorganic nanoparticles. Among these materials, layered silicate which was called as the clay was usually used as nano-fillers because of naturally abundant and most economical and structural properties. Clay-reinforced polymer nanocomposites have various advantages, such as high strength, flammability, gas barrier property, abrasion resistance, and low shrinkage and used for automotive and packing materials. Therefore, in this paper, we focused on the need of gas barrier materials and materials-related technologies.

High-Performance Ionic Polymer-Metal Composite Actuators Based on Nafion/Conducting Nanoparticulate Electrospun Webs (나피온/전도성 나노입자 전기방사 웹을 이용한 고성능 이온성 고분자-금속 복합체 구동기의 제조)

  • Jung, Yo-Han;Lee, Jang-Woo;Yoo, Young-Tai
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.434-439
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    • 2012
  • To improve the performance of ionic polymer-metal composite (IPMC) actuators, Nafion films sandwiched with Nafion/conducting nanoparticulate electrospun webs were used as polymer electrolytes of IPMC. Multiwalled carbon nanotube (MWNT) and silver were the conducting nanoparticulates and the nanoparticles dispersed in a Nafion solution were electrospun. IPMCs with the Nafion/conducting nanoparticulate electrospun webs displayed improved displacements, response rates, and blocking forces. MWNT was superior to silver in terms of displacement and blocking force, and the webs without the conducting fillers also caused enhanced performances compared with the conventional IPMCs. These improvements were attributed to an elevated electrolyte flux through highly porous interlayers and capacitance induced by well dispersed conducting fillers, and low interfacial resistance between electrolyte and electrodes.