• Journal of Energy Engineering
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• v.22 no.1
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• pp.44-50
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• 2013

This study was experimentally investigated NOx and CO emissions characteristics with various equivalence ratios using premixed type of burner installed small heat exchanger. The effectiveness of heat exchanger and the entropy generation number were also calculated. As results, the heat transfer rate increases with increasing equivalence ratio due to increase the flame temperature. According to the emission characteristics and the effectiveness, the optimal operating equivalence ratio is 0.75 in the range of this experiment. Consequently, the area of the heat exchanger should be increased to reduce the entropy generation number and to increase the effectiveness.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.203-204
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• 2003

광화학 스모그 현상은 전 세계를 비롯하여 서울에서도 새로운 사회 현안으로 부각되고 있다 (Ghim and Chang, 2000). 광화학 반응에 의해 오존 농도가 증가할 수 있고, 광화학 반응으로 생성된 이차 에어로졸은 시정을 악화시킨다. 광화학 반응에 의해 생성된 이차 에어로졸은 대부분이 미세입자이다. 이차 에어로졸과 오존은 NOx와 VOCs (volatile organic compounds)같은 전구물질 사이의 복잡한 반응으로부터 생성된다. 그러므로 서울의 광화학 스모그 발생을 제어하기 위해서는 오존과 미세입자의 특성을 이해하는 것이 필수적이다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.171-173
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• 2003

광화학스모그 챔버의 성능을 평가하기 위하여 파장별 광도시험, 광원의 NO$_2$ 광분해 상수, pure air experiment 등 성능실험을 수행하고, VOCs 종류 및 VOCs/NOx 비가 오존생성 및 입자상물질의 생성에 미치는 영향과 온도, 습도가 오존생성에 미치는 영향 등을 평가하였다. (중략)

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.949-955
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• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.2
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• pp.193-204
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• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.1
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• pp.103-110
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• 2012

The flow field, fuel-air mixing, and behaviors of turbulent flames have been investigated using the large eddy simulation (LES) numerical technique in a premixed swirl combustor equipped with EV double cone burners. Recirculation zones are generated by the swirl burner, and lean premixed flames are formed within a distance of 0.2 m from the tip of the burner. NOx emission of 0.46 ppm is predicted at 1 atm and an air/fuel ratio of 38.7. However, most of the CO generated in a flame front continues to be oxidized as it moves toward the exit, and CO emission of 5.45 ppm is predicted at the exit. The NOx emission can be reduced by decreasing the pressure and air/fuel ratio. The characteristics of NOx emission have been investigated through RANS simulations for various fuel injection types, and it is found thereby that five-lance-hole injection produces the lowest NOx emission rate.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.89-94
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• 2011

DeNOx characteristics of hybrid SNCR-SCR process have been investigated in a pilot scale flow reactor. DeNOx efficiency of SNCR reaction was about 80% at $970^{\circ}C$ and hybrid SNCR-SCR process showed 92% at $940^{\circ}C$ with NSR = 2.0. Compared to SNCR process alone, hybrid SNCR-SCR process was more effective at cool side, which is lower than $940{^{\circ}C}$. It should be also noted that ammonia slip from hybrid SNCR-SCR process was below 1ppm at the condition of higher space velocity and the required catalyst volume can be decreased to 2/3 of SCR process. Key factors for DeNOx efficiency of hybrid SNCR-SCR process were found to be $NH_3$ concentration and NOx selectivity of urea injected in SNCR process.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2247-2254
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• 2000

This study was carried out to investigate the reaction characteristics of NOx with reagents to grope the power consumption rate reduction and NOx removal rate improvement for the non-thermal plasma denitrification process. The experiments were performed using the real flue gas and wire-plate type plasma reactor. and the flow rate of real flue gas is $20Nm^3/hr$. Paraffinic and olefinic hydrocarbons and ammonia were used as reagents. Olefinic hydrocarbon oxidizes NO more actively than paraffinic hydrocarbon under the non-thermal plasma conditions, resulting in the generation of large amount of $NO_2$ and a very small amount of CO. When the initial NOx concentration increases. oxidation rate of NO decreases and the consumption rate of olefinic hydrocarbon increases significantly. On the other hand. $NH_3$ did not promote reduction reaction with NO under non-thermal plasma conditions. however, there was a tendency that the NHa was effective to remove the $NO_2$ oxidized by olefinic hydrocarbon.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.75-82
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• 2004

The conditional moment closure(CMC) model has been implemented in context with the unstructured-grid finite-volume method which efficiently handle the physically and geometrically complex turbulent reacting flows. The validation cases include a turbulent nonpremixed $CO/H_2/N_2$ Jet flame and a turbulent nonpremixed $H_2/CO$ flame stabilized on an axisymmetric bluff-body burner. In terms of mean flame field, minor species and NO formation, numerical results has the overall agreement with expermental data. The detailed discussion has been made for the turbulence-chemistry interaction and NOx formation characteristics as well as the comparative performance for CMC and flamelet model.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.659-669
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• 1997

The effects of exhaust gas recirculation on diesel engine combustion and soot/NOx emissions are numerically studied. The primary and secondary atomization is modelled using the wave instability breakup model. Autoignition of a diesel spray is modelled using the Shell ignition model. Soot formation is kinetically controlled and soot oxidation is represented by a model which account for surface chemistry. The NOx formation is based on the extended Zeldovich NOx model. Effects of injection timing and concentration of $O_{2}$ and CO$_{2}$ on the pollutant formation and the combustion process are discussed in detail.