• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.823-826
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• 2013

A low-${\varepsilon}$ solid-state NMR(Nuclear Magnetic Resonance) probe was developed for the spectroscopic analysis of two-dimensional $^{15}N-^1H$ heteronuclear dipolar coupling in dilute membrane proteins oriented in hydrated and dielectrically lossy lipid environments. The system employed a 800 MHz narrow-bore magnet. A solenoid coil strip shield was used to reduce deleterious RF sample heating by minimizing the conservative electric fields generated by the double-tuned resonator at high magnetic fields. The probe's design, construction, and performance in solid-state NMR experiments at high magnetic fields are described here. Such high-resolution solid-state NMR spectroscopic analysis of static oriented samples in hydrated phospholipid bilayers or bicelles could aid the structural analysis of dilute biological membrane proteins.

• 한국초전도저온공학회지:초전도와저온공학
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• 제20권2호
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• pp.15-22
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• 2018

The present article briefly overviews the plan for a new project on joint technology for HTS wires/cables and describes the development plan for the world's highest field NMR magnet, which is a major development item in the project. For full-fledged social implementation of superconducting devices, high temperature superconducting (HTS) wire is a key technology since they can be cooled by liquid nitrogen and they can generate a super-high magnetic field of >>24 T at liquid helium temperatures. However, one of the major drawbacks of the HTS wires is their availability only in short lengths of a single piece of wire. This necessitates a number of joints being installed in superconducting devices, resulting in a difficult manufacturing process and a large joint resistance. In Japan, a large-scale project has commenced, including two technical demonstration items: (i) Development of superconducting joints between HTS wires, which are used in the world's highest field 1.3 GHz (30.5 T) NMR magnet in persistent current mode; the joints performance is evaluated based on NMR spectra for proteins. (ii) Development of ultra-low resistive joints between DC superconducting feeder cables for railway systems. The project starts a new initiative of next generation super-high field NMR development as well as that of realization of better superconducting power cables.

• 한국자기학회지
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• 제20권2호
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• pp.68-74
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• 2010

핵자기공명은 물질 내부의 국소적인 스핀 환경에 대한 정보를 제공하기 때문에 자성체 연구에 대단히 유용하다. 자성체 내 이온의 원자가 혹은 자기모멘트, 스핀들의 기울어짐각, 오비탈 상태 등을 직접 측정할 수 있게 해주며 자성이온들의 위치나 자구와 자구벽의 변화 등에 대한 정보를 제공한다. 이렇게 정보를 제공할 수 있는 단순화된 원리를 적용사례를 들어 설명한다.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2001년도 학술대회 논문집
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• pp.121-124
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• 2001

The research results on the superconducting magnet for whole body MRI are presented. The magnet consists of main coil with 6 solenoid coils, shielding coil with 2 solenoid coils and 6 sets of cryogenic shim coil. The ferromagnetic shim assembly is installed on the inside wall of the room temperature bore for shimming inhomogeneous field components generated due to manufacturing tolerances, installation misalignments and external ferromagnetic materials near the magnet. Also, the magnet is enclosed with the horizontal type cryostat with 80cm room temperature bore to keep the magnet under the operating temperature. The magnetic field distributions within the imaging volume were measured by the NMR field mapping system. Through the test, the central field of magnet was 1.5 Tesla and the field homogeneity of 9.3 ppm has been obtained on 40cm DSV(the diameter of spherical volume) and using this magnet, comparatively good images for human body, fruits and water phantoms have been achieved.

• 한국자기공명학회논문지
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• 제17권2호
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• pp.81-85
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• 2013

Various fluorine-containing materials are used in electronic devices like LCD display panels and Li-ion batteries. The structural conformation of fluorine in fluorinated materials is an important contributing factor that influences the chemical and physical properties. The conformation can be changed by heat and stress during manufacture or use. Understanding the conformational changes is critical for understanding the performance and durability of electronic devices. Solid-state NMR spectroscopy could be widely used for the analysis of various fluorine-containing materials for electronic devices. However, conventional CPMAS probes cannot be used for in-situ analysis of fluorine-containing electronic devices like LCD panels and Li-ion batteries. In this paper, we show the design, construction, and optimization of a $^{19}F-^{13}C$ double-resonance solid-state NMR probe for a 400MHz wide-bore magnet with a flat square coil for in-situ analysis of fluorine-containing electronic devices without observing fluorine background signals. This custom-built probe does not show any fluorine background signals, and can have higher efficiency for lossy samples.

• 한국자기학회지
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• 제5권1호
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• pp.79-85
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• 1995

초전도 자석의 공간상 자기장 분포를 균일하게 할 때 사용하기 위한 정밀한 자기측정 장치를 개발하였다. 개발한 장치는 연속파 핵자기공명(CW-NMR)을 이용하였고 2.8 T에서 5.8 T까지의 자기장 범위에서 공간상 자기장 분포를 0.3 ppm 이상의 분해능으로 측정할 수 있다. NMR 시료로는 직경 4 mm, 높이 4 mm의 체적에 물을 넣어 사용하였으며, 10 T 이상 의 강자기장을 측정할 경우를 고려하여 중수를 시료로 이용한 실험도 하였다. 이 장치는 기존의 NMR 자기장측정 장비에 비해 훨씬 저럼한 가격으로 제작 가능하다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 D
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• pp.3210-3212
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• 2000

We designed and manufactured 300MHz NMR RF Transceiver. NMR system is composed of NMR Spectrometer, Superconductive Magnet and Pulse Programmer, GUI. NMR RF Transceiver is composed of transmitter, receiver, frequency synthesizer. T/R switch, main power amp., RF coil. To phase modulation, transmitter is composed of mixer, splitter and combiner et al. To weak signal detection, receiver is composed of pre-amp., filter, mixer et al. Each module is manufactured PCB. And installed NMR system to detect chemical component of specimen. In result, we can get the information of specimen.

• Journal of Biosystems Engineering
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• 제21권3호
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• pp.336-342
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• 1996

A 4.1MHz$1^H$ Nuclear Magnetic Resonance(NMR) sensor was designed and manufactured to evaluate the internal quality of fruits. The magnet console having 963gauss magnetic field induction was used for the NMR sensor. To optimize and evaluate the NMR sensor, glycerol and sugar-water solutions were used. $^1$H(proton) resonance signals were used to estimate the sugar contents in fruits. Artificial neural network models were developed to predict sugar contents in fruits from the proton resonance signals. The standard errors of prediction(SEP) were 0.565(apple), 0.394(pear) and 0.415(kiwi), respectively. The result implied that it was possible to evaluate apple, pear and kiwi into 3 grades using the NMR sensor.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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• pp.305-312
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• 1996

A 4.1MHz 1H Nuclear Magnetic Resonance (NMR) sensor was designed and manufactured to evaluate the internal quality of fruit. The magnet console having 963 gauss magnetic field induction was used for the NMR sensor. To optimize evaluate the NMR sensor, glycerol and sugar-water solutions were used. 1H(proton) resonance signals were use of to estimate the sugar contents in fruits the proton resonance signals and were validated . The standard errors of predictions(SEP) were 0.565(apple) , 0.394(pear) and 0.415(kiwi) respectively. The result implied that is possible to evaluate apple , pear and kiwi into 3 grades using the NMR sensor.

• 한국초전도ㆍ저온공학회논문지
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• 제5권1호
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• pp.92-96
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• 2003

This paper deals with the characteristics of persistent current switch (rCS) system fer applied HTS magnet system. To apply the high-Tc superconductor in superconducting machine such as motror, generator, MAGLEV, MRI, and NMR, the study on high-Tc superconducting persistent current mode must be performed. In this experiment, the PCS system consists otd superconducting magnet, PCS and magnet power supply. The superconducting magnet was fabricated by connecting four double pancake coils (DPCs) in series. The PCS was inductive double pancake coil type and heated up by the SUS 303L tape heater. The optimal length of PCS was calculated and thermal quench state of PCS was simulated by using finite element method(FEM) and compared with experimental results. The optimal energy to normalize the PCS was calculated and introduced. Finally, the persistent current was observed with respect to various ramping up rate and magnitude of charging current.