• The Korean Journal of Ceramics
• /
• 제6권1호
• /
• pp.32-36
• /
• 2000

Pyrolytic preparations of Ti-Al-N ceramics from three blended precursors were investigated. The precursors were prepared stirring ($HA1N^{i}Pr_m$ and an aminolysis product of $Ti(NMe_2)_4$ with $MeHNCH_2CH_2$NHMe in $C_6/H_6$ . IR and $^1H\;NMR $analyses suggested that essentially no Ti-N-Al bonds were present in the precursors. Pyrolysis of the precursors under $NH_3-N_2$led to the formation of brown solids with ceramic yields of about 30%, and the Ti-Al ratios in the pyrolyzed products were close to those of the precursors. XRD analysis of the pyrolyzed product from the precursor with Ti:Al=5:1 indicated the formation of a NaCl-type compound as the only crystalline phase. Pyrolysis of the precursor with Ti:Al=2:1 led to the formation of AlN besides the major NaCl-type compound. A ceramic composite containing AlN and the NaCl-type compound was formed by pyrolysis of the precursor with Ti:Al=1:2.

• Smart Structures and Systems
• /
• 제26권2호
• /
• pp.157-174
• /
• 2020

The guided wave technique is commonly used in structural health monitoring as the guided waves can propagate far in the structures without much energy loss. The guided waves are conventionally generated by the surface-mounted piezoelectric wafer active sensor (PWAS). However, there is still lack of understanding of the wave propagation in layered structures, especially in structures made of anisotropic materials such as carbon fiber reinforced polymer (CFRP) composites. In this paper, the Rayleigh-Lamb wave strain tuning curves in a PWAS-mounted unidirectional CFRP plate are analytically derived using the normal mode expansion (NME) method. The excitation frequency spectrum is then multiplied by the tuning curves to calculate the frequency response spectrum. The corresponding time domain responses are obtained through the inverse Fourier transform. The theoretical calculations are validated through finite element analysis and an experimental study. The PWAS responses under the free, debonded and bonded CFRP conditions are investigated and compared. The results demonstrate that the amplitude and travelling time of wave packet can be used to evaluate the CFRP bonding conditions. The method can work on a baseline-free manner.

• 한국응용과학기술학회지
• /
• 제14권2호
• /
• pp.87-91
• /
• 1997

서로 다른 씨클로펜타디엔 유도체가 ${\pi}$-결합된 최초의 비스무스 화합물인 ${\eta}^5-C_5(CH_3)_5Bi({\eta}^5-C_5H_5)_2$이 디펜타메틸씨클로펜타디에닐 비스무스디메틸아미드 $Cp{\ast}_2BiNMe_2[Cp{\ast}=C_5(CH_3)_5]$와 씨클로펜타디에닐 모노머와의 반응으로 합성되었다. 반응조건은 에테르 용매하에 -78$^{\circ}C$ 반응온도 조건하에서 얻어졌다. 합성된 반응물을 노르말 헥산 용매에서 재결정시킨 결과, 검은색 결정이 60% 수율로 얻어졌다. 그리고 재결정시킨 반응물을 190K에서 X-선 단결정 구조 분석 방법에 의해 그 구조를 밝혔다. 그 결과 결정계의 격자계는 I2/a, a=1756.00 picometer, b=906.00 picometer, c=2211.00 picometer, ${\beta}$=104.04, Z=8로 확인되었다. 여기서 a, b, c는 결정�Ю� 상수이고, ${\beta}$는 결정격자 상수인 b와 c간의 각도이며, Z는 단위 결정 격자당 분자의 갯수이다.

• Bulletin of the Korean Chemical Society
• /
• 제35권1호
• /
• pp.236-242
• /
• 2014

Isospecific propylene polymerization behavior of meta- and para-Lewis base (E) functionalized unbridged zirconocenes ($[1-(E_n-Ph)-3,4-Me_2C_5H_2]_2ZrCl_2$, E = $NMe_2$, OMe; n = 1 or 2) was investigated under bulk conditions. Catalytic activity of the zirconocenes, and molecular weight and isotacticity of polypropylenes are found to be dependent on the position and number of the Lewis base functional groups in the zirconocenes. All the crude polypropylenes possess a broad molecular weight distribution and multi-melting transitions, indicating an involvement of multi-catalytic active species in the polymerization. The highest [mmmm] value of an isotactic portion of the polypropylenes reached 89%, which is higher than that (85%) from the well-known $C_2$-symmetric EBIZr (rac-$Et(Ind)_2ZrCl_2$) catalyst. These results support that the in situ generated, rigid rac-like cation-anion pair through the Lewis acid-base interactions between the functional groups of zirconocenes and methylaluminoxane anion is effective in the formation of isotactic polypropylene under bulk propylene polymerization conditions.

• Bulletin of the Korean Chemical Society
• /
• 제31권10호
• /
• pp.2903-2908
• /
• 2010

Protein S-nitrosation is common in cells under nitrosative stress. In order to model proteins with S-nitrosocysteine (CysSNO) residues, we first developed an Amber force field for S-nitrosoethanethiol (EtSNO) and then transferred it to CysSNO. Partial atomic charges for EtSNO and CysSNO were obtained by a restrained electrostatic potential approach to be compatible with the Amber-99 force field. The force field parameters for bonds and angles in EtSNO were obtained from a generalized Amber force field (GAFF) by running the Antechamber module of the Amber software package. The GAFF parameters for the CC-SN and CS-NO dihedrals were not accurate and thus determined anew. The CC-SN and CS-NO torsional energy profiles of EtSNO were calculated quantum mechanically at the level of B3LYP/cc-pVTZ//HF/6-$31G^*$. Torsional force constants were obtained by fitting the theoretical torsional energies with those obtained from molecular mechanics energy minimization. These parameters for EtSNO reproduced, to a reasonable accuracy, the corresponding torsional energy profiles of the capped tripeptide ACE-CysSNO-NME as well as their structures obtained from quantum mechanical geometry optimization. A molecular dynamics simulation of myoglobin with a CysSNO residue produced a well-behaved trajectory demonstrating that the parameters may be used in modeling other S-nitrosated proteins.

• Bulletin of the Korean Chemical Society
• /
• 제34권8호
• /
• pp.2335-2339
• /
• 2013

Relative reactivity of various Al-substituted dialkylalans ($AlR_2(X)$) in reduction of acetone has been studied with density functional theory and MP2 method. Formation of the alan dimers and the alan-acetone adduct, and the transition state for the Meerwein-Ponndorf-Verley (MPV) type reduction of the adduct were calculated to figure out the energy profile. Formation of dimeric alans is highly exothermic. Both the relative free energies for acetone-alan adduct formation and the TS barriers for the MPV type reduction with respect to alan dimers and acetone were calculated and they show the same trend. Based on these energetic data, relative reactivity of alans is expected to be; $AlR_2(Cl)$ > $AlR_2(OTf)$ > $AlR_2(O_2CCF_3)$ > $AlR_2(F)$ > $AlR_2(OMs)$ > $AlR_2(OAc)$ > $AlR_2(OMe)$ > $AlR_2(NMe_2)$. The energy profile is relatively well correlated with the experimental order of the reactivity of Al-substituted dialkylalans. It is noted that the substituents of alans have initial effects on the relative free energies for the carbonyl-adduct formation. Therefore, an $AlR_2(X)$ which forms a more stable carbonyl-adduct is more reactive in carbonyl reduction.

• 무역학회지
• /
• 제46권4호
• /
• pp.113-130
• /
• 2021

This study aims to analyze the WTO-inconsistent aspects of the single rate presumption of the United States in establishing and imposing anti-dumping duties for non-market economy exporters. By examining the drafting history in the GATT/WTO negotiations and the practice of the single rate presumption for non-market economies by the United States from a comparative perspective, it critically addresses the inherent lack of pertinent disciplines under the framework of the WTO Anti-Dumping Agreement in establishing dumping margins for exporters of non-market economies. The WTO Dispute Settlement Body leaves open the possibility of allowing the investigating authority to consider multiple exporters and the exporting country as a single entity. However, the study argues that it is difficult in practice for the investigating authority to make a single-entity decision in a WTO-consistent manner. The study also finds an incompatibility in the notion between establishing dumping margins for 'individual' exporters and 'non-market economies.' A proper discipline for non-market economies under the multilateral anti-dumping norm needs to be reconsidered in the era of persistent trade conflicts between the United States and China.

• 한국환경농학회지
• /
• 제33권4호
• /
• pp.271-281
• /
• 2014

BACKGROUND: Application of the transfer functions derived from local soil data is necessary in order to develop proper management protocols for agricultural soils contaminated with heavy metals through phytoavailability control of the heavy metals. The aim of this study was to derive the transfer functions of Korean agricultural soils affected by the abandoned mining sites and evaluate suitability of the derived transfer functions. METHODS AND RESULTS: 142 agricultural soils affected by the abandoned mining sites were collected and analyzed. Two extraction methods, including 1 M $NH_4NO_3$ extraction and 0.01 M $Ca(NO_3)_2$ extraction were applied to determine phytoavailable metal pools in soils. Multiple stepwise regression of phytoavailable metal pools against the corresponding total metal concentration and soil properties was conducted to derive suitable transfer functions for estimating phytoavailable heavy metal pools. Applicability of the derived transfer functions was examined by calculating NME and NRMSE. CONCLUSION: Soil pH and organic matter were valid variables for derivation of the transfer functions which were applicable for estimating phytoavailable metal concentrations in the soils being contaminated by heavy metals. In addition, it was confirmed that transfer functions need to be developed based on local soil conditions to accurately estimate heavy metal-phytoavailability.

• 대한구순구개열학회지
• /
• 제5권1호
• /
• pp.27-42
• /
• 2002

This study was designed to evaluate the morphology and the position of the mandible in the complete unilateral cleft lip and palate patients, Craniofacial skeletal morphology pattern was analyzed on the lateral cephalometric radiographs of the 50 subjects of complete unilateral cleft lip and palate, the 50 normal and 50 class III, Each group was divided into child and adult sub-groups, All the data were tested statistically. The results were as follows: I, In the comparison with the normal group, complete cleft group showed smaller angular, condylar length, clockwisely rotated mandible and larger NMe/SGo(p<0.01). 2, In the comparison with the class III group, the complete cleft group showed significantly smaller angular, condylar, ramal, body length of the mandible(p<0,01). 3. As for the position of the mandibular condyle to the cranial base, the class III group was the most anterior, the normal group was the most posterior and the complete cleft group was in the middle(p<0.05). 4. In the comparison with child group, the normal adult group showed smaller mandibular angle and mandibular plane angle, but not the other two groups. And the complete cleft group and the class III group showed the similar change. The normal and class III group showed increased XiCd/XiPog, but not the complete cleft group(p<0.01).

• 한국환경과학회지
• /
• 제19권8호
• /
• pp.983-999
• /
• 2010

Wind power energy is one of the favorable and fast growing renewable energies. It is most important for exact analysis of wind to evaluate and forecast the wind power energy. The purpose of this study is to improve the performance of numerical atmospheric model by data assimilation over a complex coastal area. The benefit of the profiler is its high temporal resolution and dense observation data at the lower troposphere. Three wind profiler sites used in this study are inhomogeneously situated near south-western coastal area of Korean Peninsula. The method of the data assimilation for using the profiler to the model simulation is the three-dimensional variational data assimilation (3DVAR). The experiment of two cases, with/without assimilation, were conducted for how to effect on model results with wind profiler data. It was found that the assimilated case shows the more reasonable results than the other case compared with vertical observation and surface Automatic Weather Station(AWS) data. Although the effect of sonde data was better than profiler at a higher altitude, the profiler data improves the model performance at lower atmosphere. Comparison with the results of 4 June and 5 June suggests that the efficiency with hourly assimilated profiler data is strongly influenced by synoptic conditions. The reduction rate of Normalized Mean Error(NME), mean bias normalized by averaged wind speed of observation, on 4 June was 28% which was larger than 13% of 5 June. In order to examine the difference in wind power energy, the wind power density(WPD) was calculated and compared.