• Title/Summary/Keyword: ND4

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Characteristics of Cryolite as an Electrolyte for Reduction of Nd$_2$O$_3$ (네오디뮴 산화물의 전해환원시 전해질로서 빙정석의 특성)

  • 남상욱;백영현
    • Journal of the Korean institute of surface engineering
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    • v.26 no.2
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    • pp.82-86
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    • 1993
  • An attempt was made to reduce directly Nd2O3 in a cryolited based fluoride bath. Neodymium metal was electrodeposited on the iron cathode to produce the Fe-Nd eutectic alloy in a liquid state at 90$0^{\circ}C$. Graphite was adopted for the anode and pure iron for the cathode. Electrolyte was composed of Na3AlF6 50wt.%. AlF3 34wt.% and Nd2O3 16wt.%. Analysis of typical alloy product showed Al 63.4wt.% Fe 26.9wt.% and Nd 7.0 wt.% The enrichment of neodymium in the alloy couldn't be obtained because aluminum codeposited with ne-odydmium. Experimental results proved that the cryolited based electrolyte was unstable for the electrolysis of rare earth oxides even though their prominent solubilities.

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Magnetic properties of high performance NdFeB perpendicular thin film (고성능 NdFeB 수직 박막자석의 자기적 특성)

  • 김만중;양재호;김윤배;김택기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.802-805
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    • 2000
  • Anistropic [Ta/NdFeB/Ta] thin film was sputtered on heated Si substrate by Nd$\_$17/Fe$\_$74/B$\_$9/ target. The grain size of the films increased according to the increase of substrate temperature, and the film deposited at 650$^{\circ}C$ showed optimum coercivity. 4$\pi$M$\_$r/, $\_$i/H$\_$c/ and (BH)$\_$max/ measured perpendicular to the film plane of thin film deposited at 650$^{\circ}C$ are 12.3 kG, 9.9 kOe and 37 MGOe, respectivly.

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Optical Properties of a Proton-implanted Nd:CNGG Planar Waveguide

  • Zhu, Qian-Lin;Lin, Ming-Fu;Chen, Jing-Yi;Wang, Zhong-Yue;Liu, Chun-Xiao
    • Current Optics and Photonics
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    • v.3 no.2
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    • pp.172-176
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    • 2019
  • The work reports on the fabrication of an optical planar waveguide in the Nd:CNGG crystal by the 0.4-MeV hydrogen ion implantation with a fluence of $8.0{\times}10^{16}ions/cm^2$. The nuclear energy loss of the implanted hydrogen ions was derived by using SRIM 2013 code. The microscope image of the proton-implanted Nd:CNGG crystal cross section was captured by a metallographic microscope. The transmittance spectra were recorded before and after the ion implantation. The light intensity distribution of the planar waveguide at 632.8 nm was experimentally measured to validate its effect on one dimension confinement. The investigation shows that the proton-implanted Nd:CNGG waveguide is a candidate for an optoelectronic integrated device.

The Naturally Occurring Levels of Nitrate and Nitrite in Livestock Products (축산물 중 천연유래 질산염 및 아질산염 함유량 조사)

  • Choi, Jae-Chun;Park, So-Ra;Lim, Ho-Soo;Ko, Kyung-Yuk;Kim, Meehye
    • Journal of Food Hygiene and Safety
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    • v.30 no.3
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    • pp.265-271
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    • 2015
  • This study was done in order to investigate the naturally occurring levels of nitrate and nitrite in livestock products. Total samples of 458 consisting of meats (n = 223), processed meat products (n = 51), raw milks (n = 30), processed milk products (n = 142), eggs (n = 5) and processed egg products (n = 7) were analyzed for contents of nitrate and nitrite by ion chromatography (IC). That methods showed good results in terms of linearity, limit of detection (LOD), limit of quantitation (LOQ), recovery, reproducibility and uncertainty. Nitrate and nitrite were detected in 167 and 40 samples, respectively. The nitrate levels (mg/kg) were not detected (ND)~40.23 for modified milks, ND~37.97 for sauce meats, ND~32.40 for process cheeses, ND~31.50 for processed egg products, ND~27.73 for dry milks, ND~24.76 for sausages, ND~22.45 for bacons, ND~21.55 for natural cheeses, ND~20.82 for hams and fermented milks, ND~13.57 for eggs, ND~12.77 for butters, ND~9.31 for milks and ND~3.88 for meats while the nitrite levels (mg/kg) were ND~17.35 for processed egg products and ND~1.92 for meats. In conclusion, the result of this study of nitrate and nitrite in livestock products could be used as one of scientific base datum to determine whether they are naturally occurring or not, including ingredients and their percentage, manufacturing processes, other papers relating to naturally occurring levels of them, and so on.

Elimination of respiratory pathogens in endemically infected swine herds by nursery depopulation (Nursery depopulation 기법에 의한 돼지 호흡기질병 상재돈군의 호흡기 병인체 전파방지에 관한 연구)

  • Kim, Bong-hwan;Joo, Han-soo
    • Korean Journal of Veterinary Research
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    • v.37 no.4
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    • pp.755-763
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    • 1997
  • Recently new technologies for the establishment of high health herds are becoming efficient tools in the control of PRRS virus and secondary infections. Medicated early weaning(MEW) and nursery depopulation(ND) have shown to be one of the most successful procedures in the eradication and control of pathogens. Indirect evidence of the role of PRRSV in precipitating secondary infection comes from successful improvement in growth and in decreasing mortality on farms that have eliminated PRRSV through ND. Hence the present experiments were conducted in an effort to compare ND with MEW procedures as a means of eliminating PRRSV controlling secondary pathogens and improving performance of pigs in endemically infected swine herds. Following MEW and ND procedures practiced in the farms, some benefits obtained were as follows: 1. A decrease in PRRSV circulation in the nursery, but no entire elimination. 2. Decrease in the frequency of secondary bacteria and in the use of antibiotics. 3. Mycoplasma hyopneumoniae infection was prevented during the nursery stage. 4. ND protocol had a lower cost and management changes than MEW techniques. 5. Nursery performance was improved after the depopulation, cleaning and disinfection procedures, even though PRRSV still being cycled in the old nursery rooms. These studies revealed that the MEW and ND protocols are not always successful for PRRS virus elimination but it's great effect on control of secondary pathogens and improvement of performance make MEW and ND an efficient tools for the establishment of healthier and more efficient herds.

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Heat Treatment Condition for Preparing $Nd_{1+x}Ba_{2-x}Cu_{3}O_{7-\delta}$ Superconductors

  • Fan Zhan guo;wha, Soh-Dea;zhan, Si-Ping;Li Yingmel;Lim Byongjae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.624-627
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    • 2001
  • Two kinds of Nd$_{1+x}$Ba$_{2-x}$Cu$_3$O$_{7-{\delta}}$, the sintering samples and zone melting samples, were heat treated under pure Ar at 95$0^{\circ}C$. The substitution of Nd ion for Ba ion in the Nd$_{1+x}$Ba$_{2-x}$Cu$_3$O$_{7-{\delta}}$ before and after the heat treatment were investigated by XRD. In order to know the effects of the heat treatment, the T$_{c}$ and J$_{c}$ of samples with the heat treatment and those without the heat treatment by Ar were comparatively studied. The results show that the substitution of Nd for Ba decreased, T$_{c}$, and J$_{c}$ increased after the treatment under Ar at 95$0^{\circ}C$. The Nd$_{1+x}$Ba$_{2-x}$Cu$_3$O$_{7-{\delta}}$ samples were oxygenated under pure oxygen at 30$0^{\circ}C$. From the XRD pattern it was found that the sample with x< 0.4 could transfer from tetragonal phase to orthorhombic phase after the oxygenation, but the sample with x>0.4 could not make the phase transition even after a long time oxygenation.ion even after a long time oxygenation.ation.n.ation.ation.

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Separation of Neodymium from NdEeB Permanent Magnetic Scrap (NdFeB계 영구자석 스크랩으로부터 네오디뮴의 분리회수)

  • Yoon Ho-Sung;Kim Chul-Joo;Lee Jin-Yeung;Kim Sung-Don;Kim Joon-Soo;Lee Jae-Chun
    • Resources Recycling
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    • v.12 no.6
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    • pp.57-63
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    • 2003
  • In this study, the separation of neodymium was investigated from NdFeB permanent magnet scrap. Decomposition and leach-ing process of NdFeB permanent magnet scrap by oxidation roasting and sulfuric arid leaching were examined. Neodymium could be separated from iron by double salt precipitation using sodium sulfate. The optimum conditions established for decom-position and leaching are as follows: oxidation roasting temperature is $500^{\circ}C$ for sintered scrap and $700^{\circ}C$ for bonded scrap, concentration of sulfuric acid in leaching solution is 2.0 M, leaching temperature and time is $50^{\circ}C$ and 2 hrs, and pulp density is 15%. The leaching yield of neodymium and iron was 99.4% and 95.7% respectively. The optimum condition for separation of neodymium by double-salt precipitation was 2 equivalents of sodium sulfate and $50^{\circ}C$ The yield of neodymium was above 99.9%.

Influence of Roller Speed on Magnetic Properties and Structures of α-Fe/Nd2Fe14B Nanocomposite Magnets Prepared by Melt-spinning

  • Pei, Wenli;Lian, Fazeng;Fu, Meng;Zhou, Guiqin;Takahashi, M.
    • Journal of Magnetics
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    • v.9 no.4
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    • pp.101-104
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    • 2004
  • The crystallization behaviours of nanocomposite made by a function of quenching rate (roller speed) were studied. The results showed that there was one step c$\mathbb{r}$ystallization process for the alloy quenched at roller speed of 32 m/s, which could be shown as, Am (amorphouse) + ${\alpha}-Fe/Nd_2Fe_{14}B$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$ . For the alloy quenched at roller speed of 40 m/s, there was steps crystallization process taking place at different temperatures, which could be shown as, Am ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{23}B_3+Nd_2Fe_{14}B+Am`$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$. The presence of transition phase ($Nd_2Fe_{23}B_3$) was harmful to get fine and uniform grain size during crystallization process. Uniform microstructures and high magnetic properties could be attained for the as-quenched alloy containing less amorphous phase and no presence of transition phase during annealing treatment. For the alloy prepared at roller speed of 32 m/s, the following properties were obtained, $B_r= 0.904 T,_iH_c = 801 kA/m, (BH)_{max} = 122 kJ/m^3 and M_r/M_s = 0.6$.

Ln-resin and HIBA Method for La-Ce and Sm-Nd Isotope Measurement (La-Ce 및 Sm-Nd 동위원소계 측정을 위한 란탄-레진법과 HIBA(Hydroxy Isobutyric Acid)분리법의 상호비교)

  • Lee, Seung-Gu;Lee, Hyomin;Asahara, Yoshihiro;Lee, Mi-Jeong;Choo, MiKyeong;Lee, SeungRyeol
    • The Journal of the Petrological Society of Korea
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    • v.21 no.4
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    • pp.431-439
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    • 2012
  • A column chemistry is the most useful tools for isolating the elements of interest in isotope geochemistry. Here we introduce the chemical experimental procedure for Sm, Nd, La and Ce separation such as Teflon powder or Ln-resin method using HDEHP of KIGAM, KBSI, KOPRI and ${\alpha}$-HIBA(${\alpha}$-Hydroxy Isobutyric acid) method of Nagoya University, Japan. This technical report will provide an useful information in selecting the experiment method for rare earth element isotope system study such as Sm-Nd and La-Ce isotope system.

Investigation of seroepidemiology of Mycoplasma hyopneumoniae infection and establishment of on-farm eradication protocol (Mycoplasma hyopneumoniae 감염의 혈청역학적조사 및 농장에서의 근절방안 설정)

  • Seok, Ho-bong;Joo, Han-soo
    • Korean Journal of Veterinary Research
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    • v.39 no.6
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    • pp.1218-1223
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    • 1999
  • The purposes of this study are to examine seroprevalence of Mycoplasma hyopneumoniae infection in pigs of different age groups, and retrospectively determine if nursery depopulation (ND) could influence the seroprevalence of M hyopneumoniae infection in nurseries. Sera of 4, 8, 12, 16, and 20 weeks old pigs from 7 farms were first selected from a serum bank to examine serologic profiles for M hyopneumoniae infections. Availability of representative sera in the serum bank was a major criterion for farm selection. The sera were tested for M hyopneumoniae antibodies by an enzyme linked immunosorbent assay (ELISA) using Tween-20 extracted antigen. Serum samples were also selected from 15 of 34 swine farms that previously participated in a ND study. In order to evaluate M hyopneumoniae infection following ND, ELISA was performed with sera of 8~10 weeks old nursery pigs collected prior to and after ND for up to 12 months from the 15 farms. Serological profiles showed positive ELISA titers for 2 of 7 farms at 8 weeks, 4 of 7 farms at 12 weeks, 6 of 7 farms at 16 weeks, 6 of 6 farms at 20 weeks of age. Prior to ND, 11 of the 15 farms had positive titers in sera of 8~10 weeks old pigs. Sera of 8~10 weeks old pigs collected from 7 of the 11 farms (63.6%) were ELISA antibody negative for up to 12 months following ND. In conclusion, seroconversion to M hyopneumoniae was detected commonly between 10~16 weeks of age, indicating the occurrence of natural infection during the nursery age. The ND appeared to be an effective method to prevent M hyopneumoniae infection within the nursery pig in some farms.

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