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Coercivity Enhancement in Nd2Fe14B Permanent Magnetic Powders through Rotating Diffusion Process with DyHx Powders

  • Choi, Moon-Hee;Yu, Ji-Hun;Kim, Dong-Hwan;Kim, In-Bae;Kim, Yang-Do
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.342-349
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    • 2011
  • [ $Nd_2Fe_{14}B$ ]permanent magnetic powders ($_iH_c$ = 9.2 kOe, $B_r$ = 12.2 kG) were produced by HDDR process. Their coercivity was enhanced to 12.6 kOe through the grain boundary diffusion process with dysprosium hydride ($DyH_x$). $DyH_x$ diffusion process was optimized through rotating diffusion process, resulting in distinct phases rich in Nd and Dy observable by field emission scanning microscopy and transmission electron microscopy. The mechanism of coercivity enhancement that resulted in restrain the coupling effect between $Nd_2Fe_{14}B$ grains is also discussed.

Coercivity of Hot-pressed Compacts of Nd-Fe-B-type HDDR-treated Powder

  • Abdul Matin, Md.;Kwon, Hae-Woong;Lee, Jung-Goo;Yu, Ji-Hun
    • Journal of Magnetics
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    • v.19 no.2
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    • pp.106-110
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    • 2014
  • $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ HDDR-treated powder was compacted by hot-pressing using different configurations of dies and heating rates. The die configurations were especially different in terms of the evacuation system that was used in heating for hot-pressing. The coercivity in the compacts was influenced by the evacuation system of the die and heating rate. In spite of the identical hot-pressing temperature and heating rate, coercivity was radically reduced above $600^{\circ}C$ in the compacts prepared in the closed-type die compared to that in the compacts prepared in the open-type die. The coercivity in the compacts prepared in the closed-type die decreased with increasing heating rate and the value further increased when extreme high heating rate was employed. $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ HDDR-treated powder contained a significant amount of residual hydrogen (approx. 1500 ppm) in the form of $Nd_2Fe_{14}BH_x$ hydride. The dramatic coercivity decrease in the compact prepared in the closed die is attributed to the disproportionation of $Nd_2Fe_{14}BH_x$ hydride. High coercivity is mainly due to the effective desorption of hydrogen or the suppression of hydrogen-related disproportionation upon hot-pressing.

Thermal Lens Compensation in a Fiber-Coupled Laser-Diode Pumped Ceramic Nd:YAG Laser (광섬유 연결 반도체레이저 여기 세라믹 Nd:YAG 레이저에서 열렌즈 효과의 보상)

  • Kim, Duck-Lae;Kim, Yeong-Sik;Kim, Byung-Tai
    • Korean Journal of Optics and Photonics
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    • v.18 no.3
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    • pp.208-215
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    • 2007
  • A fiber-coupled laser-diode pumped ceramic Nd:YAG laser for compensating the thermal tensing effect was developed. The thermal tensing effect was compensated using a convex lens, which was 25 mm away from the laser rod, with a focal length of 30 mm and an effective clear aperture of 22 mm. Without a compensator, the laser output power decreased suddenly above a pump power of 6 W. Using a compensator, the laser output power increased linearly according to the pump power. The beam propagation factor $M^{2}$ was 2.4 under a pump power of 12 W.

Magnetic Microstructures and Corrosion Behaviors of Nd-Fe-B-Ti-C Alloy by Ga Doping

  • Wu, Qiong;Zhang, Pengyue;Ge, Hongliang;Yan, Aru;Li, Dongyun
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.240-244
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    • 2013
  • The influences of Gallium doping on the magnetic microstructures and corrosion behaviors of Nd-Fe-B-Ti-C alloys are investigated. The cooling rate for obtaining fully amorphous structure is raised, and the glassforming ability is improved by the Ga addition. The High Resolution Transmission Electron Microscopy image shows that the ${\alpha}$-Fe and $Fe_3B$ soft magnetic phases become granular surrounded by the $Nd_2Fe_{14}B$ hard magnetic phase. The rms and $({\Delta}{\varphi})_{rms}$ value of Nd-Fe-B-Ti-C nanocomposite alloy thick ribbons in the typical topographic and magnetic force images detected by Magnetic Force Microscopy(MFM) decreases with 0.5 at% Ga addition. The corrosion resistances of $Nd_9Fe_{73}B_{12.6}C_{1.4}Ti_{4-x}Ga_x$ (x = 0, 0.5, 1) alloys are enhanced by the Ga addition. It can be attributed to the formation of more amorphous phases in the Ga doped samples.

Expression and Localization of Keap1 During Amelogenesis in the Developing Molar Germ of Rats

  • Kim, Sun-Hun;You, Yong-Ouk;Ko, Hyun-Mi;Kim, Hyun-Jin
    • International Journal of Oral Biology
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    • v.43 no.4
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    • pp.177-183
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    • 2018
  • The objective of this study was to examine the expression pattern of Kelch-like ECH-associated protein 1 (Keap1) in the maxillary $2^{nd}$ molar germs of rats. We used the maxillary $2^{nd}$ molar germs in rats' pup at postnatal day 3 (bell stage), 6 (crown formation stage) and 9 (root formation stage). The investigation on mRNA and protein levels were done using reverse transcription - polymerase chain reaction and western blot. Localization of Keap 1 in the maxillary $2^{nd}$ molar germs were revealed through immunofluorescence staining. Keap1 from the maxillary 2nd molar germs were mostly manifested on postnatal day 3 and dramatically decreased on postnatal day 6 and 9 at mRNA and protein levels, while amelogenin and ameloblastin increased during the development of maxillary 2nd molar germs. During immunofluorescence analysis, the strong immunoreactivity against Keap1 was detected in the apical side of ameloblasts at the presecretory and secretory stages. However, Keap1 expression was hardly observed in the ameloblasts at the maturation stage. These results shows that Keap1 is strongly expressed in the presecretory and secretory ameloblasts of amelogenesis, and suggest that Keap1 may be a crucial molecule for the regulatory mechanisms tasked with the formation of enamel layer.

Effect of Mixed Glucomannan and WheyCalcium on the Serum Cholesterol and Blood Glucose in Rats (글루코만난과 유청칼슘의 혼합물이 흰쥐의 혈청콜레스테롤 및 혈당에 미치는 영향)

  • Lee Sook Kyung;Sin Gang Lae;Kim Young Han
    • Journal of Food Hygiene and Safety
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    • v.20 no.1
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    • pp.69-72
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    • 2005
  • This study was performed to investigate the effect of mixed glucomannan(G) and wheycalcium(W) on the level of serum cholesterol in rats(Female Sprague-Dawley) fed high cholesterol diet($1.0\%$ : HCD) and also on the level of blood glucose in rats fed high glucose diet ($70\%$ : HGD) for 4 weeks. The results were follows as 1. The level of serum cholesterol were decreased in the rank order HCD>HCDG>HCDGW>ND, 2. HCDG showed a decrese of about $23.84\%$ but HCDGW showed a decrese of about $42.38\%$ compared with the increasing rate of HCD in serum cholesterol, 3. The level of blood glucose were decreased in the rank order HGD>HGDG>HGDGW>ND, 4. HGDG showed a decrese of about $6.63\%$ but HGDGW showed a decrese of about $36.14\%$ compared with the increasing rate of HGD in blood glucose, 5. The mixture of glucomannan and wheycalcium on the serum cholesterol and blood glucose in rats was most effect of all.

Environmental Adaptation of Tall Fescue varieties in Mauntainous pastures V. Effect of Final cutting time in autumn on the dry Weight ofplant ( DW ) and yield components of the 2nd growth (Tall fescue 품종의 환경적응성 V. 가을철 예취시기가 2번초의 개체중과 수량구성요소에 미치는 영향)

  • 이주삼;신영재;박훈정;한성윤;조익환
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.14 no.2
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    • pp.76-81
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    • 1994
  • This experiment was carried out to select the best adaptable varieties of Tall fescue in mountainous pastures of Taekwalyon area. The evaluation was based on the data of varietial differences in the dry weight of plant@W) and yield components of the 2nd growth. Nine varieties of Tall fescue examined were Barcel, Barvetia, Demeter, Enforcer, Forager, Fuego, Johnstone, Safe and Stef. And, the final cutting times were Sept. 30 ($C_1$), Oct.14 ($C_2$),Oct. 28 ($C_3$), and Nov. 11($C_4$). The reults were summarized as follows: 1. Barcel and Forager with many tillers per plant(NT) showed a high dry weight of plant@W) of the 2nd growth. 2. The dry weight of plant(DW) of the 2nd growth indicated significantly positive correlation with the number of tillers per plant(NT), but there was not significant correlation with the dry weight of tiller(WT). 3. The maximum dry weight of plant@W) of the 2nd growth was obtained at $C_3$(28 Oct.). 4. The dry weight of the 2nd growth showed an inverse relations with the dry weight of the 1st growth as affected by various final cutting time in growth period of autumn.

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The Spatial Coherence Characteristics of Wavefront of NBUR Nd:YAG Laser Output Beam (NBUR Nd:YAG 레이저 위상파면의 공간적 가간섭성 특성)

  • 박대윤;최승호;이승걸
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.288-295
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    • 1995
  • We have studied about spatial wavefront analysis of a pulsed laser output beam by means of an imaging unstable ring resonator with an infinite Fresnel number. We have constructed a Newtonian telescope type NBUR (Negative Branch Unstable Ring) Nd:YAG laser with 4 plane mirrors. Provided that the NBUR resonator is under self imaging condition, the resonator could be reduced diffraction effects which were occuring to the beam transmitting through the circular aperture of scraper mirror in the resonator. We have observed enhancement in the spatial coherence of wavefronts of laser beam due to the iterative round trips of the self imaging beam inside the ring resonator. The information on the spatial wavefronts was determined by the fringe patterns from Mach-Zehnder interferometer and the fringe analysis by means of the Fourier transform method showed the distortion of wavefronts of less than 0.2), In comparison with a standing wave type resonator, we have confirmed that the spatial coherence of the NBUR Nd:YAG laser output beam was enhanced as much as 75%. s 75%.

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Preparation of Iron Nano-particle by Slurry Reduction Method from Leaching Solution of Spent Nd magnet (폐네오디뮴 자석 침출용액으로부터 Slurry 환원법을 이용한 철 Nano 분말 제조)

  • Ahn, Jong-Gwan;Gang, Ryunji;You, Haebin;Yoon, Ho-Sung
    • Resources Recycling
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    • v.23 no.6
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    • pp.22-29
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    • 2014
  • Recycling process of iron should be developed for efficient recovery of neodymium (Nd), rare metal, from acid-leaching solution of Nd magnet. In this study, $FeCl_3$ solution as iron source was used for preparation of iron nano particles with the condition of various factors, such as, reductant, and surfactant. $Na_4P_2O_7$ and Polyvinylpyrrolidone (PVP) as surfactants, $NaBH_4$ as reductant, and palladium chloride ($PdCl_2$) as a nucleation seed were used. Iron powder was analyzed by using XRD, SEM for measuring shape and size. Iron nano particles were prepared at the ratio of 1:5 (Fe (III) : $NaBH_4$). Size and shape of iron particles were round-form and 50 ~ 100 nm size. Zeta-potential of iron at the 100 mg/L of $Na_4P_2O_7$ was negative value, which was good for dispersion of metal particle. When $Na_4P_2O_7$ (100 mg/L), PVP($FeCl_3:PVP$ = 1 : 4, w/w) and Pd($FeCl_3:PdCl_2$ = 1 : 0.001, w/w) were used, iron nano particles which were round-shape, well-dispersed and near 100 nm-sized range. In this condition, $FeCl_3$ solution changed with spent Nd leachate solution, and then it is possible to be made round-formed iron nano particles at pH 9 and at the reaction bath over 20 L which is not include any surfactant.

Kinematical Analysis of Tichonkich Motion in Parallel Bars (평행봉 Tichonkich 동작의 운동학적 분석)

  • Park, Jong-Hoon;Back, Jin-Ho
    • Korean Journal of Applied Biomechanics
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    • v.15 no.3
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    • pp.21-30
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    • 2005
  • The purpose of this study is helps to make full use for perfect performance by grasping the defects of Tichonkich motion performed by athlete CSM For this, the study analyzed kinematical variables through Tichonkich motions performed at the first selection competition(1st trial) and final selection competition(2nd trial) for the dispatch to the 28th Athens Olympic Games using the three-dimensional cinematographical method with a high-speed video camera, and obtained the following results. 1. During Tichonkich motion, the execution time of up swing and the right hand moving to the left bar was shorter in the 2nd trial than the 1st one, while the execution time of down swing, the support of the left bar and the right hand moving to the right bar was longer in the 2nd trial than the 1st trial. 2. The horizontal position of COG in the 2nd trial was -35cm in the 1st stage, 42cm in the 3rd stage and 29cm in the 4th stage, that is, it showed a great swing focused on the circular movement compared to the 1st trial, while the vertical position of COG was -59cm in the 2nd stage, that is, it showed a small swing focused on a up and down movement. Also the 5th stage vertical position was 98cm, and the 6th stage vertical position was 95cm in the 2nd trial which were higher than those of the 1st trial, so it has provided magnificence required in the modern gymnastics. 3. And it was indicated that the horizontal velocity at the down swing phase proceeded forward more rapidly in the 2nd trial than that in the 1st trial, and the reverse ascent made a rapid vertical rise lessening left and right velocity change. And in the 5th stage, the 2nd trial was kept very slower in horizontal, vertical and left and right velocity that in the 1st trial, so it reached a handstand with leisurely movement. 4. In the 2nd trial, shoulder joint of the 1st, 2nd, 3rd stages kept a larger angle than that in the 1st trial, that is, it made a great swing while in the 1st trial, it showed a swing movement dependent on kick movement by the flexion and extension of hip joint. Also in the 2nd trial, the body formed a vertical posture with both hands supporting the left bar and hip joint was kept larger as $198^{\circ}$ and $190^{\circ}$ in the 5th and 6th stage than that in the 1st trial, so it made a handstand with the body uprightly stretched out, and magnificent and stable movement.