• Elastomers and Composites
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• 제24권4호
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• pp.276-289
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• 1989

This study deals with both effects of inorganic fillers to vulcanized rubbers such as NR, CR, EPDM, NBR & SBR and inorganic characteristics of domestic fillers in comparision with hard clay produced in the USA. The results were as follows. 1. Main ingredient of domestic clay "Ha-dong clay" was Halloysite, "No-ha Island" was Pyrophyllite with $\alpha$-Quartz, and both of "Hard clay" & "Hwa-soon clay" were proved to be Kaolinite by XRD, DT-TGA and chemical analysis by XRF. 2. Tensile strength value of SBR compounded with these fillers, was Hard clay $146kg\;f/cm^2$, Kaolinite $123kg\;f/cm^2$, Pyrophyllite $82kg\;f/cm^2$, Halloysite $80kg\;f/cm^2$, precipitated $CaCO_3\;27kg\;f/cm^2$, and ground $CaCO_3$ was $21kg\;f/cm^2$. These results showed the increase of seven times according to filler species. 3. The physical properties of non-crystalline rubbers, such as SBR, NBR & EPDM, compared with NR & CR, have been considerably changed according to crystalline phase, particle size, shape and surface structure of fillers. Especially, tensile strength value in case of SBR & EPDM, was differentiated about 1.5 times by the particle size of fillers. 4. In SBR, physical properties of rubber compounded with Kaolinite which was surface treated with fatty acid and silane, almost approach to the value of hard clay. 5. Delayed cure time of Kaolinite and decrease of rubber properties by $CaCO_3$ can be improved by blending kaolinite & $CaCO_3$ in the ratio of 2:1.

• Elastomers and Composites
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• 제40권1호
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• pp.22-28
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• 2005

본 연구에서는 실리카/고무 복합재료의 기계적 계면 물성과 열안정성에 대한 산소플라즈마의 영향에 대하여 살펴보았다. 실리카의 표면특성은 XPS와 접촉각 측정을 통하여 살펴보았다. 실리카/고무 복합재료의 기계적 물성과 열안정성은 각각 인열에너지 ($G_{IIIC}$)와 열중량분석(TGA)를 통하여 관찰하였다. 실험결과, 플라즈마 처리시간이 증가함에 따라 실리카 표면에 산소가 함유된 극성 관능기의 도입량이 증가하였으며, 이에 따라 고무 복합재료의 인열에너지와 열안정성이 향상되었다. 이러한 결과는 NBR과 같은 극성고무가 산소가 함유된 관능기가 도입된 실리카와 상대적으로 높은 상호작용을 하기 때문으로 판단된다.

• 공업화학
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• 제22권2호
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• pp.149-154
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• 2011

연료전지 스택 작동환경에서의 열노화 특성을 살펴보기 위하여 다양한 고무 compound의 내열 및 압축 영구 줄음률의 평가를 실시하고, 스택의 장시간 운전을 통해 접합할 수 있는 대상액인 $H_2SO_4$, $H_2O$, LLC (Ethylene glycol : $H_2O=50:50$)에 대하여 장시간 평가를 실시하였다. NBR과 EPDM은 시간이 경과할수록 침적액의 변색하는 것을 알 수 있었으며, VMQ는 $H_2SO_4$ 분위기에서 시간에 따라 고무가 노화되는 것을 TGA, SEM, EDS 분석을 통하여 확인하였다.

• 대한원격탐사학회지
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• 제38권6_3호
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• pp.1861-1869
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• 2022

최근 기후변화에 따라 세계적으로 산불이 빈번해지고 피해 규모가 커지면서, 이에 따른 산림 생태계 파괴, 인명 및 재산 피해가 증가하고 있다. 위성기반 산불피해지수는 객관적이고 신속한 산불피해지 파악을 가능하게 하고, 북한과 같이 접근이 불가능한 지역에 대한 분석에 유용하다. 이 단보에서는 전통적으로 사용되어 온 Normalized Burn Ratio (NBR)를 비롯하여, 식생활력도를 나타내는 Normalized Difference Vegetation Index (NDVI), 그리고 최근에 개발된 Fire Burn Index (FBI)와 Forest Withering Index (FWI)를 이용하여 북한지역 산불피해지 탐지를 수행하고, 4가지 지수의 비교 평가를 통해 한반도 적용 방안을 모색하였다. 향후 중소형 산불에 대한 적용가능성 검토와 딥러닝 영상인식의 활용 등이 추가적으로 연구되어야 할 것이다.

• 연구논문집
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• 통권24호
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• pp.175-188
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• 1994

Water seal is composed of metal case, garter spring, and NBR. Axisymmetric, large deformation non-linear contact problems were solved by using the finite element method for the evaluation of performance of the water seal. Effects of the interference between seal and shaft, and the garter spring on the seal characteristics were considered in this analysis. The contact force and sealing performance increased as the interference and spring stiffness increases. And middle seal is main role sealing performance. Further research efforts are required to consider the effects of the garter spring stiffness, the eccentricity by the shaft or case, and the water pressure.

• Computers and Concrete
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• 제11권3호
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• pp.253-270
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• 2013

The aim of the present paper is to show the application of optimization strategies for the cost of beams in reinforced concrete buildings and to propose pre-sizing parameters. In order for these goals to be met, an optimization software program was developed. The program combines the analysis of structures by the grid model, reinforced concrete sizing, and the simulated annealing optimization heuristic. Sizing is compliant with the NBR 6118 (2007) Brazilian standard, according to which flexural, shearing, torsion, and web reinforcements and serviceability limit states (deflection and crack width limitation) are checked. Besides the dimensions of the situations mentioned above, the influence the cost of each material (steel, concrete and formwork) has on the overall cost of structures was also determined.

• Elastomers and Composites
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• 제19권1호
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• pp.13-31
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• 1984

The purposes of this dissertation are to demonstrate that DSC theromoanaytical methods of vulcanization can provide useful informations on the vulcanization characteristics of industrial formulations and also provides the potential basis for a rapid and complete method of sulfur and vulcanizing accelerator analysis for quality control. The influences of those factors such as heating rate, scan temperature, vucanizing accelerator's type and concentration upon vulcanization exotherm in NR and NBR compounds in the presence of vulcanizing accelerators such as TMTD,MBTS,DPG,TMTM,CBS, and MBT were evaluated by means of DSC. In order to examine the credibility in the DSC method, the same samples which were used for DSC method were studied to compare the DSC results with the ODR (Oscillating Disk Rheometer) data. The results obtained were as follows 1. In the DSC dynamic experiments, the observed enthalpy results from vulcanization depends upon the heating rate; In the range of 2 to $20^{\circ}C/min$ of heating rate, as the heating rate was increased the enthalpy change was also increased. However, over the heating rate of $30^{\circ}C/min$ it was observed that the enthalpy change was decreased as the heating rate was further increased. Without regard to the change of enthalpy, tremendous instantaneous heat evolving was observed in the range of high heating rates. 2. For the samples which are added with various vulcanizing accelerators, the activation energies of vulcanization were as follows; 3. Regarding to the influences of vulcanizining accelerator's types upon the characteristics of vulcanization exotherm, NR and NBR compounds in the presence of thiuramsulphide compounds type accelerators such as TMTD, TMTM, were exhibited sharper and higher vulclanization exotherm than others. From the resuts of DSC thermograms which was distributed in even shape in the broad temperature range, it was clearly shown that the guanidine compounds type accelerator such as DPG acts as a delayed acting accelerator. 4. In the comparison of DSC and ODR results, the dependency of temperature in the cure rate and the observed conversions show good agreements between two results. 5. In the same curatives, by the comparison of glass transition temperatures, it was possible to predict relative values of maximum torques. Consequently, from the present studies, it is shown that the DSC thermoanalytical method can provide an alternate new method for rapid and complete quality control analysis of rubber industry.

• 디지털융복합연구
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• 제19권7호
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• pp.189-197
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• 2021

우리나라는 기술사업화 활성화를 위하여 기술이전·사업화 전문기관을 지속적으로 육성하고 있으며 다양한 형태로 구성되고 있다. 하지만 이러한 전문기관의 유형과 지원형태에 따른 성과에 대한 연구가 제한적으로 이루어지고 있다. 이에 본 연구는 기술이전·사업화 전문기관의 유형을 구분하여 복합활용성과와 기술을 수용한 기업의 성과를 측정하고자 한다. 이를 위하여 기업 외부기술 도입 및 활용을 추진한 380개기업을 대상으로 OLS 및 NBR 회귀분석 방법을 활용하여 가설검증을 실시하였다. 분석결과 기술이전·사업화 전문기관을 복합 활용 할수록 기업성과에 긍정적인 영향을 주고, 외부기술도입의 항목에 따라 기업성과에 상이한 영향을 주는 것으로 나타났다. 또한 산업성장단계가 초기일수록 산업이 안정화되는 영역의 기업성과가 높은 것으로 나타났다. 이를 통해 기업차원에서 기술이전·사업화 전문기관의 활용과 기업의 외부기술을 도입전략 시사점을 제시하였다.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.67-76
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• 2022

We developed a technology that can measure the hydrogen uptake and diffusivity of rubber materials by using the volumetric analysis method and diffusivity analysis program through the measurement of the water level in the graduated cylinder. In this method, hydrogen gas is charged at a certain pressure for a certain period of time for a rubber material exposed to a high-pressure hydrogen gas environment, and then the pressure is reduced to measure the change in the water level in the graduated cylinder in real time, and based on the measured value, it is a technology that can evaluate hydrogen uptake and diffusivity using diffusivity analysis program. Using this method, the hydrogen uptake and diffusivity of the NBR material were measured with respect to the change in the type and weight ratio of the filler used to improve the physical properties of the rubber material. In addition, uncertainty analysis was performed on the diffusivity measurement method.

• 대한기계학회논문집A
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• 제33권4호
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• pp.321-328
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• 2009

Shock absorption performances of various rubbers were investigated by using drop impact test. Several types of rubber such as NR, NBR, EPDM, SR and PUR with three respective levels of shore hardness were used for the test. As in the cases, the absorbed impact energies in rubbers were measured under seven different loads against impact energy between 5-80J. The impact absorption efficiencies of the rubbers then were evaluated by means of both single impact energy condition and summation of all impact energy applied condition. As shown in the results, PUR and EPDM have better shock absorption performances than other rubbers. Further analysis was extended to determine a shear modulus of SR through the finite element implementation with Blatz-Ko model. As can be seen, relatively higher level of absorption energy results in a decreasing shear modulus.