• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.42 no.5
• /
• pp.62-66
• /
• 2010

Cellulosic materials were dissolved by NMMO(N-methylmorpholine-N-oxide) and CED (Cupriethylene diamine), respectively, to measure their DPs (degrees of polymerization) by using viscometer. We changed cellulose DPs by applying various amounts of low intensity electron-beam radiation to the cellulosic materials. NMMO is environmental-friendly, non-toxic, and biodegradable organic cellulose solvent and used industrially because of its high cellulose dissolving power and high solvent recovery ratio. The cellulose DP measurement results using these two different chemicals were correlated highly ($R^2$ >0.95). It was also found that cellulose with high DP was dissolved more easily in NMMO than CED. In addition, NMMO method gave more higher resolution in the measurement.

• Advances in concrete construction
• /
• v.16 no.6
• /
• pp.317-325
• /
• 2023

Strength prediction and correlation of concrete is done using experimental and analytical methods. Main objective is to correlate the experimental and simulated values of compressive strength of concrete mix using Fly Ash (FA) and Silica Fume (SF) by partial replacement of cement in concrete. Mix proportion was determined using IS method for M40grade concrete. Hundred and forty-seven cubes were cast and tested using Universal Testing Machine (UTM). Genetic Algorithm (GA) model was developed using C++ program to simulate the compressive strength of concrete for various proportions of FA and SF replacements individually at 3% increments. Experiments reveal that 12 percent silica fume replacement produced maximum compressive strength of 35.5 N/mm², 44.5 N/mm² and 54.8 N/mm² moreover 9 percent fly ash replacement produced a maximum strength of 31.9 N/mm², 37.6 N/mm² and 51.8 N/mm² during individual material replacement of concrete mix. Correlation coefficient for each curing period of fly ash and silica fume replaced mix were acquired using trend lines. The correlation coefficient is found to be approximately 0.9 in FA and SF replaced mix irrespective of the mix proportion and age of concrete. A higher and positive correlation was found between the experimental and simulated values irrespective of the curing period in all the replacements.

• Journal of the Korean Chemical Society
• /
• v.20 no.1
• /
• pp.19-34
• /
• 1976

The crystal structure of sodium sulfisoxazole hexahydrate, $C_{11}H_{12}N_3O_3SNa{\cdot}6H_2O$,has been determined by X-ray diffraction method. The compound crystallizes in the monoclinic space group $$P2_1}c$$ with a = 15.68(3), b = 7.70(2), c = 17.94(4)${\AA}$, ${\beta}$ = $118(2)^{\circ}$ and Z = 4. A total of 1717 observed reflections were collected by the Weissenberg method with $CuK{\alpha}$ radiation. Structure was solved by heavy atom method and refined by block-diagonal least-squares methods to the R value of 0.14. The conformational angle formed by the S-C(l) bond with that of N(2)-C(7), when the projection in taken along the S-N(2), is $73^{\circ}.$ The benzene ring is planar and makes an angle of $60^{\circ}$ with the plane of the isoxazole ring, which is also planar. The sodium atom has a distorted octahedral coordination of N(l) and five oxygen atoms from hydrate molecules. Sodium sulfisoxazole hexahydrate shows fourteen different hydrogen bondings in the crystal. These are six $O-H{\cdots}O-H bonds, three $O-H{\cdots}O$ bonds, two $O-N{\cdots}N,$ one $N-H{\cdots}O,O-H{\cdots}N,N-H{\cdots}O-H$ bond, with the distances in the range of 2.71 to $3.04{\AA}.$.

• Journal of Ecology and Environment
• /
• v.38 no.4
• /
• pp.517-528
• /
• 2015

Litter decomposition is an important process in terrestrial ecosystem. However, studies on decomposition are rare, especially in evergreen broadleaf trees. We collected the leaf litter of five evergreen broadleaf trees (Daphniphyllum macropodum, Dendropanax morbifera, Castanopsis cuspidata var. thunbergii, Machilus thunbergii and Quercus acuta), and carried out a decomposition experiment using the litterbag method in Ju-do, Wando-gun, Korea for 731 days from December 25, 2011 to December 25, 2013. Among the five experimental tree species, C. cuspidata var. thunbergii distribution was limited in Jeju Island, and D. macropodum was distributed at the highest latitude at Mt. Baekyang (N 35°40′). About 2% of the initial litter mass of D. macropodum and D. morbifera remained, while 20.9% remained for C. cuspidata var. thunbergii, 30.4% for M. thunbergii, and 31.6% for Q. acuta. D. macropodum litter decayed four times faster (k = 2.02 yr^-1) than the litter of Q. acuta (k = 0.58 yr^-1). The decomposition of litter was positively influenced by thermal climate such as accumulated mean daily air temperature (year day index) and precipitation, as well as by physical characteristics such as thickness (R²=0.939, P = 0.007) and specific leaf area (SLA) (R² = 0.964, P = 0.003). The characteristics of chemical composition such as lignin (R² = 0.939, P = 0.007) and water-soluble materials (R² = 0.898, P = 0.014) showed significant correlations with litter decomposition. However, the nutrients in litter showed complicated species-specific trends. The litter of D. macropodum and D. morbifera had fast decomposition despite their low nitrogen concentration and high C/N ratio. This means that the litter decomposition was more strongly affected by physical characteristics than chemical composition and nutrient content. On the other hand, the litter of Q. acuta which had the slowest decay rate had a high amount of N and low C/N ratio. Thus, the decomposition of Q. acuta litter was more affected by the P content of the litter than the N content, although all litter had similar physical characteristics.

• The Korean Journal of Pesticide Science
• /
• v.7 no.2
• /
• pp.100-107
• /
• 2003

To improve the growth inhibitory activity against the shoot and root of rice plant (Oryza sativa L) and barnyard grass (Echinochloa crus-galli), a series of N-substituted phenyl-3,4-dimethylmaleimdes derivatives as substrates were synthesized and then their the inhibitory activities of protoporphyrinogen oxidase (1.3.3.4), protox were measured. The quantitative structure-activity relationships (QSAR) between structures and the inhibitory activities were studied quantitatively using the 2D-QSAR method. And also, molecular sharp similarity between the substrate derivatives and protogen, substrare of protox enzyme were studied. The activities of the two plants indicated that barnyard grass had a higher activity than the rice plant and their correlation relationships have shown in proportion for each. Accordingly, the results of SARs suggest that the electron donating groups as $R_2=Sub.X$ group will bind to phenyl ring because the bigger surface area of negative charged atoms in the substrate molecule derivatives may increase to the higher the activity against barnyard grass. Based on the molecular shape similarity, when the derivatives and protogen, subsbrate of protox enzyme were superimposed by atom fitting, the similarity indices (S) were above 0.8 level but the correlation coefficients (r) between S values and the activities showed not good.

• Proceedings of the KIEE Conference
• /
• 2006.07c
• /
• pp.1621-1622
• /
• 2006

This paper presents the effect of driving waveform for piezoelectric bend mode inkjet printhead with optimized mechanical design. Experimental and theoretical studies on the applied driving waveform versus jetting characteristic s were performed. The inkjet head has been designed to maximize the droplet velocity, minimize voltage response of the actuator and optimize the firing frequency to eject ink droplet. The head design was carried out by using mechanical simulation. The printhead has been fabricated with Si(100) and SOI wafers by MEMS process and silicon direct bonding method. To investigate how performance of the piezoelectric ceramic actuator influences on droplet diameter and droplet velocity, the method of stroboscopy was used. Also we observed the movement characteristics of PZT actuator with LDV(Laser Doppler Vibrometer) system, oscilloscope and dynamic signal analyzer. Missing nozzles caused by bubbles in chamber were monitored by their resonance frequency. Using the water based ink of viscosity of 4.8 cps and surface tension of 0.025N/m, it is possible to eject stable droplets up to 20kHz, 4.4m/s and above 8pL at the different applied driving waveforms.

• 한국초전도학회:학술대회논문집
• /
• v.9
• /
• pp.147-151
• /
• 1999

YBCO step-edge Josephson junction were fabricated on sapphire substrates. The steps were formed on R-plane sapphire substrates by using Ar ion milling with PR masks. The step angle was controlled in the wide range from 25$^{\circ}$ to 50$^{\circ}$ by adjusting both the Ar ion incident angle and the photoresist mask rotation angle relative to the incident Ar ion beam. CeO$_2$ buffer layer and in-situ YBa$_2Cu_3O_{7-{\delta}}$ (YBCO) thin films was deposited on the stepped R-plane sapphire substrates by pulsed laser deposition method. The YBCO film thickness was varied to obtain the ratio of film thickness to step height in the range from 0.5 to 1. The step edge junction exhibited RSJ-like behaviors with I$_cR_n$ product of 100 ${\sim}$ 300 ${\mu}$V, critical current density of 10$^3$ ${\sim}$ 10$^5$ A/ cm$^2$ at 77 K.

• Microbiology and Biotechnology Letters
• /
• v.40 no.4
• /
• pp.319-324
• /
• 2012

Production of liquid starters using wheat bran as a medium for Rhizopus oryzae N174 and the changes in their characteristics noted during storage were investigated in this study. The optimal culture conditions of the liquid starters were determined to be 5~15% (w/v) wheat bran and 48~72 hrs of incubation. The effects of liquid starters with different storage periods and temperatures (-18, 4, 10 and $25^{\circ}C$) on the quality of wheat nuruk were evaluated. According to the results of the pH, acidity, reducing sugar and enzyme activities, it was found that liquid starter using wheat bran preserved for one day, at any temperature, is the best method of storage for seed cultures for R. oryzae N174.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.13 no.6
• /
• pp.545-550
• /
• 2000

In order to synthesize Ba-ferrite particles by molten salt method KCl and NaCl were added to basic composition to 50% by weight. X was varied from 0.0 to 1.0 to control the magnetic properties in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ and 1 mol% of $SiO_2$was added to control the aspect ratio of hexagonal platelets. And the effects of reaction temperatures were examined by varying the temperature from 85$0^{\circ}C$ to 120$0^{\circ}C$ with 5$0^{\circ}C$ intervals. Eutectic composition of NaCl and KCl lowered the crystallizing temperature of Ba-ferrite in molten salts than using KCl and NaCl separatly. The morphology of resulting Ba-ferrite particles was clearly hexagonal-shaped plates. $H_{c}$ and $M_{r}$ were decreased when F $e^{3+}$ was substitued with $Co^{2+}$ and $Ti^{4+}$ from x=0 to x=1.0 in $BaFe_{12-2x}$/ $Co_{x}$ / $Ti_{x}$ / $O_{19}$ . Adding 1mol% $SiO_2$in molten salt method increased the size but shortened c-axis of the hexagonal ferrites and this result is an opposite phenomenon compared with the result in solid-statge reaction.n.ion.n.

• Journal of the Society of Naval Architects of Korea
• /
• v.51 no.3
• /
• pp.193-202
• /
• 2014

This paper presents a new method of sampling the climatic data for infrared signature analysis. Historical hourly data from a stationary marine buoy of KMA(Korean Meteorological Administration) are used to select a small number of sample points (N=100) to adequately cover the range of statistics(PDF, CDF) displayed by the original data set (S=56,670). The method uses a coarse bin to subdivide the variable space ($3^5$=243 bins) to make sample points cover the original data range, and a single-point ranking system to select individual points so that uniform coverage (1/N = 0.01) is obtained for each variable. The principal component analysis is used to calculate a joint probability of the coupled climatic variables. The selected sample data show good agreement to the original data set in statistical distribution and they will be used for statistical analysis of infrared signature and susceptibility of naval ships.