• Korean Journal of Crystallography
• /
• v.6 no.2
• /
• pp.80-87
• /
• 1995

The structure of Tetrapropionyloxycalix[4]arene(C40H40O8) has been studied by X-ray diffraction method. The crystal is monoclinic a=13.921(3), b=13.552(2), c=19.840(5)Å, β=110.38(2)°, Z=4 T=297K, Dc=1.23gcm-3, F(000)=1376, Systematic absences : hkl none, h0l : h+l=2n, 0k0: k=2n define space group P21/n. The structure was solved by direct method and refined by full-matrix least-squares methods to final R of 0.06 for 2514 observed reflections. The macrocycle exists in partial cone conformation. Three propionyl groups direct toward the exterior of the macrocycle cavity.

• Journal of the Korean Chemical Society
• /
• v.14 no.1
• /
• pp.51-59
• /
• 1970

The apparent molal volumes(${\phi}_v$) of the homologous salts $RNH_3Cl$, where R varies from methyl-($CH_{3^-}$) to n-butyl-(n-$C_4H_{9^-}$) in a series of methanol-water mixtures have been determined at 30$^{\circ}C$ by means of a float method to fifth decimal places down to 0.01 m. The values of ${\phi}_r$ extrapolated to infinite dilution give partial molal volumes $\bar{V}^{\circ}$which varies considerably in accordance with the solvent composition. that is, mole fraction of methanol. The experimental results are discussed in terms of the varying size and charge effect, hydrophobic nature of the solute species, and also the additivity relationship between successive homologous and the structure of the binary solvent. The results indicate that at 0.1 mole fraction methanol the enhanced structuredness of water cause a minimum in the partial molal volumes of cations $\bar{V}^{\circ}_+$, while at 0.4 mole fraction the solvent structure is such that the free volume is a minimum but the effect of electrostriction is a maximum.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2003.10a
• /
• pp.89-94
• /
• 2003

Hard coatings are known to improve the performance of cutting tools in aggressive machining applications, such as high speed machining. New superhard Ti-Al-Si-W films, characterized by a nanocomposite nano-sized (Ti,Al,Si)N crystallites embedded in amorphous $Si_3 N_4$ matrix, could be successfully synthesized on WC-Co substrates by a hybrid coating system of arc ion plating(AIP) and sputtering method. The hardness of Ti-Al-Si-N film increased with incorporation of Si, and had the maximum value ~50 GPa at the Si content of 9 at.%, respectively. And the X-ray diffraction patterns of Ti-Al-Si-N films with various Si content is investigated. In this study, Ti-Al-Si-N coatings were applied to end-mill tools made of WC-Co material by a hybrid coating system. Cutting tests fir the high-hardened material (STD11,$H_R$)C62 and their performances in high speed cutting conditions were studied. Also, the tool wear and tool lift of Ti-Al-Si-N with various si(6, 9, 19) contents were measured.

• Journal of the Korean Institute of Gas
• /
• v.25 no.6
• /
• pp.53-65
• /
• 2021

While the hydrogen refueling station is rapidly expanded and installed, the safety inspection of the hydrogen pressure vessel in the station should be very important. Of these, according to ASME, hydrogen embrittlement tests must be performed for hydrogen vessel that store hydrogen above a certain pressure. The main test method for hydrogen embrittlement inspection is to carry out fracture tests and fatigue fracture tests in a high pressure hydrogen atmosphere, which allows the durability limit of the pressure vessel to be measured and the endurable limit to be determined in the hydrogen atmosphere. In detail, the critical crack depth can be calculated by the stress intensity factor(K), and the service life can be determined by da/dN (fatigue growth rate). API579-1/ ASME FFS-1 part 9 exemplifies the calculation method according to the mode of crack-like flaws, but for various shapes such as plates and cylinders, there are about 55 modes according to the shape and location of the crack. Due to the fairly complex formula, it is not easily accessible. In this study, we will show you how to calculate fracture mechanics numerically via Excel and VBA. In addition, this was applied to analyze the effects of the thickness and inner diameter of the pressure vessel on the service life.

• Journal of Information Technology and Architecture
• /
• v.10 no.1
• /
• pp.47-62
• /
• 2013

In this paper, we analyze the comparative advantage of industry innovation (R & D) activities. The method is that companies are classified suppliers dominated- industry, productionintensive industries and science-based industries, and data of Statistical analysis were collected HCCP (KRIVET). The result is that Tipping phenomena of science-based is apparent and suppliers dominated- industry is the lack of comparative advantage. The implications are as follows. suppliers dominated- industries that specialize in R & D capabilities, support R & D capability is required. Second, the policy in terms of support for R & BD (linking technology commercialization support innovation) should be strengthened. Third, SMEs in the leveling down of industry R & D capabilities should be supplemented.

• Structural Engineering and Mechanics
• /
• v.35 no.6
• /
• pp.735-758
• /
• 2010

The paper proposes two methodologies for damage identification from measured natural frequencies of a contiguously damaged reinforced concrete beam, idealised with distributed damage model. The first method identifies damage from Iso-Eigen-Value-Change contours, plotted between pairs of different frequencies. The performance of the method is checked for a wide variation of damage positions and extents. The method is also extended to a discrete structure in the form of a five-storied shear building and the simplicity of the method is demonstrated. The second method is through smeared damage model, where the damage is assumed constant for different segments of the beam and the lengths and centres of these segments are the known inputs. First-order perturbation method is used to derive the relevant expressions. Both these methods are based on distributed damage models and have been checked with experimental program on simply supported reinforced concrete beams, subjected to different stages of symmetric and un-symmetric damages. The results of the experiments are encouraging and show that both the methods can be adopted together in a damage identification scenario.

• Korean Chemical Engineering Research
• /
• v.57 no.2
• /
• pp.164-171
• /
• 2019

The protonation parameters, dissociation constants ($pK_{BH^+}$) of conjugate acid, slope values (m, ${\phi}$ and $m^*$) and correlation coefficients (r) of hydroxamic acids were determined by Hammett acidity function method, Bunnett-Olsen method and excess acidity method in hydrochloric and perchloric acid solutions. Effect of acid concentration on partition and percentage protonation was also studied. $pK_{BH^+}$ values show that hydroxamic acids do not behave as Hammett bases, but hydroxamic acids behave as weak bases in strong acidic solutions. The values of $pK_{BH^+}$ obtained through Bunnett-Olsen method and excess acidity method were compared with the Hammett acidity function. ChemAxon's MarvinSketch 6.1.5 software was also used for determining $pK_a$, pI and microspecies distribution (%) of hydroxamic acids with pH. Hydrogen donor and acceptor values and logD were also obtained. The results show that N-p-chlorophenyl-4-bromobenzohydroxamic acid has the highest $pK_a$ and lowest logD values. On the contrary, N-phenyl-3,5-dinitrobenzohydroxamic acid has lowest the $pK_a$ and highest logD values.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.6
• /
• pp.1771-1778
• /
• 2013

For the excited states of a hydrogen molecule up to n = 3 active spaces, potential energy curves (PECs) are obtained for values of the internuclear distance R in the interval [0.5, 10] a.u. within an accuracy of $1{\times}10^{-4}$ a.u. (Hartree) compared to the accurate PECs of Kolos, Wolniewicz, and their collaborators by using the multi-reference configuration-interaction method and Kaufmann's Rydberg basis functions. It is found that the accuracy of the PECs can be further improved beyond $1{\times}10^{-4}$ a.u. for that R interval by including the Rydberg basis functions with angular momentum quantum numbers higher than l = 4.

• Structural Engineering and Mechanics
• /
• v.53 no.3
• /
• pp.575-587
• /
• 2015

This paper focuses on vibration analysis of functionally graded cylindrical shell submerged in an incompressible fluid. The equation is established considering axial and lateral hydrostatic pressure based on first order shear deformation theory of shell motion using the wave propagation approach and classic Fl$\ddot{u}$gge shell equations. To study accuracy of the present analysis, a comparison carried out with a known data and the finite element package ABAQUS. With this method the effects of shell parameters, m, n, h/R, L/R, different boundary conditions and different power-law exponent of material of functionally graded cylindrical shells, on the frequencies are investigated. The results obtained from the present approach show good agreement with published results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1992.11a
• /
• pp.11-13
• /
• 1992

The dielectric reliability of the Thin $SiO_2$ films of wet oxidation on n-type Si substrates has been studied by using self-healing method of breakdown and according to injection time high frequence C-V tests. These experiments have been performed to investigate the dielectric breakdown mechanism of a thin film in which positive charge generation during high-field Fowler-Nordheim tunneling are considered. In addition, The weak spots and robust areas are distinguished so that the localized dielectric breakdown could be described.