• Title/Summary/Keyword: N/S ratio

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Separation and Elution Behavior of Some Iron(Ⅲ)porphyrin Complexes by Reversed-Phase Liquid Chromatography (역상 액체 크로마토그래피에 의한 Iron(Ⅲ)porphyrin 착화합물들의 분리 및 용리거동에 관한 연구)

  • Chang Hee Kang;In Whan Kim;Won Lee
    • Journal of the Korean Chemical Society
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    • v.37 no.12
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    • pp.1035-1046
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    • 1993
  • Some iron(III)porphyrin complexes were prepared, and identified by the spectroscopic methods. Elution behavior of iron(III)porphyrin complexes was investigated by reversed-phase HPLC. The optimum conditions for the separation of iron(III)porphyrin complexes were examined with respect to flow rate and mobile phase strength. These complexes were successfully separated on NOVA-PAK $C_{18}$ column using methanol / water(95/5) for $[T_pCF_3PP)Fe(R)]$ and methanol / water (98/2) for $[(P)Fe(C_6F_5)]$ as a mobile phase. It was found that these complexes were largely eluted in an acceptable range of capacity factor value ($0{\leq}logk'{\leq}1$). The dependence of the capacity factor (k') on the volume fraction of water in the binary mobile phase as well as the dependence of k' on the liquid-liquid extraction distribution ratio$(D_c)$ in methanol-water / n-pentadecane extraction system showed a good linearity. It means that the retention of iron(III)porphyrin complexes on NOVA-PAK $C_{18}$ column is largely due to the solvophobic effect. Also, there was a good linear dependence of the capacity factor(k') on the column temperature and enthalpy calculated by van't Hoff plot. From these results, it was confirmed that the retention mechanism of iron(III)porphyrin complexes in reversed-phase liquid chromatography was invariant under the condition of various temperature, and the solvophobic binding process exhibited isoequilibrium behavior.

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Relationships between Obesity Types and Periodontitis according to Characteristics of Subjects (대상자 특성에 따른 비만유형과 치주질환의 관련성)

  • Kong, Young-Mi;Han, Gyeong-Soon
    • Journal of dental hygiene science
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    • v.12 no.3
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    • pp.279-286
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    • 2012
  • The aim of this study was to evaluation the association between obesity and periodontitis according to the characteristics of subjects. The subjects of this study was 429 subjects aged 19 years or older from March to May, 2010. Data were analyzed with chi-square test, Multivariable logistic regression and Statistics were analyzed linear regression analysis using SPSS 18.0. WHR had dose-effect relationship with the number of sextants with periodontitis. With regard to relationships between obesity type and periodontitis depending on characteristics of objects, the WHR obesity group showed results higher than the normal group, for twice(OR: 2.24; 95% CI: 1.17-4.28) and three times or more(OR: 3.34; 95% CI: 1.53-7.27) in frequency of daily teeth brushing, 0-3 points(OR: 2.47; 95% CI: 1.09-5.59) and 4-6 points(OR: 3.99; 95% CI: 1.75-9.08) in the self-perception of stress level, and the group with 8 hours or more(OR: 4.20; 95% CI: 2.11-8.34) in the sleeping time. If anyone is judged to have obesity by WHR, we can say that the risk to have periodontitis together with it is 2.56 times more likely(95% CI: 1.58-4.13).

Studies on the Main Factors Affecting the Mycelial Growth of Phellinus linteus (목질진흙버섯균 Phellinus linteus의 균사체 생육에 미치는 주요 인자에 관한 연구)

  • Chi, Jeong-Hyun;Ha, Tae-Moon;Kim, Young-Ho;Rho, Yeong-Dock
    • The Korean Journal of Mycology
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    • v.24 no.3 s.78
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    • pp.214-222
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    • 1996
  • This study was carried out to obtain the basic data on artificial culture of Phellinus linteus. The optimum condition for the mycelial growth was $25{\sim}30^{\circ}C$ and pH $6.0{\sim}7.0$. The carbon sources such as D-glucose, D-mannose and Dextrose were favorable to mycelial growth. As nitrogen sources, peptone, cassamino acid and glutamic acid appeared to be favorable. The optimum C/N ratio was about 20:1, when 2% of glucose was provided as a carbon source. The better organic acids and vitamin among tested ones were gallic, silicic acids and biotin. The mineral nutrients of $KH_2PO_4,\;FeSO_4{\cdot}7H_2O,\; MgSO_4{\cdot}7H_2O,\;ZnSO_4{\cdot}7H_2O$ were effective and the optimum concentrations were 0.05, 0.001, 0.02 and 0.003%, respectively.

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Changes of Soil Properties and Evaluation of Plant Utilization According to the Application of Compost Used with Phyllite (Phyllite를 이용한 퇴비 시용에 따른 토양 특성 변화 및 작물에 대한 효용성 평가)

  • Park, Young-Hee;Chang, Ki-Woon;Hong, Jei-Gu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.92-99
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    • 2002
  • The study was conducted to investigate the changes of soil properties and evaluation of plant utilization according to the application of compost used with phyllite. At this experiment, the plant cultivation test(lettuce and radish plant) was carried out to know about physico-chemical properties of compost, humus degradarion and stabilization degree, and some effects among rhe treatments were best at 20Mg/ha in PSPC 10(Phyllite, Saw dust, Pig manure Compost) plots and ar 10Mg/ha in PSPC 20 treatments, respectively. The EC value was high in the compost. Therefore the EC was appeared more than 2ds/m at the applied 40Mg/ha with compost. And in case of lettuce, Avail.-$P_2O_5$ and EC were more increased than in the radish plots, highly. In contrast, in case of radish, Toral-N, Total-C, and EC contents were decreased after plant cultivation. That is, it could know that radish was fond of absorprion of nitrogen. Also, BD values of soil physical properties were decreased according to increasing of phyllite addition ratio, however water holding capacity(WHC) was increased. The plant test had not been darnaged through the application of compost used with phyllite in soil and there had not been worse on changing of soil physico-chemical properties. Consequently, phyllite composts have been thought on agricultural utilized possibility.

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Composting of Small Scale Static Pile by addition of Microorganism (미생물 첨가에 의한 소규모 정체식 퇴비화)

  • Chang, Ki-Woon;Yu, Young-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.1
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    • pp.149-153
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    • 2003
  • This study was conducted to survey the utilization possibility of composting system of small scale static pile with animal manure produced from cattle shed and the effect of addition of microorganism on the maturity of compost. Microorganisms added in composting substrate were bacteria+lactobacillus(BL)+photo.(BLP). The composting practiced was a windrow system without aeration equipment and turning was practiced periodically. The water content of substrate mixed with cow manure, rice husk, and sawdust was about 60%. The temperature during the composting process was increased at over $60^{\circ}C$ within 3 days after composting starting. Increase of temperature at the early stage of composting was fasten in BLP and BL than Control. Because the pH of the raw material was high, the changes of pH during composting was little and stabilized in weak alkaline condition. EC value was high for accumulation of manure and urine excreted continuously by animal and the changes of those during composting occurred in 5~10% increase. Reduction rates of C/N ratio were the largest as the 22.7% in BLP and 19.2and 17.5% in BL and Control respectively. In the evaluation of phytotoxicity, there was stabilized within the short time in BLP and not the difference between BL and Control. Treatment of animal manure produced from small scale cattle shed was possible by using the small scale static pile composting system with reasonable water content and turning and the addition of microorganism in composting substrate was effected on the temperature increase at the early stage of composting and reduction of plant toxicity compounds but little on the maturity of compost.

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Developmemt of Rice Husk Pellets as Bio-filter Media of Bio Scrubber Odor Removal System (왕겨펠렛 생물담체 개발 및 이를 이용한 bio scrubber형 악취제거 시스템 성능평가)

  • Bae, Jiyeol;Han, Sangjong;Park, Ki Ho;Kim, Kwang-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.4
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    • pp.554-566
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    • 2018
  • The rice husk contains nutrients which can be easily utilized by microorganisms, and also has a water retaining ability, which played a crucial part in enabling it to become a biofilter media. In this study, we evaluated the applicability of rice husk pellet bio-scrubber as a microbiological carrier. The pelletization experiment of rice husk as a biological media was performed using PVA and EVA binder. Also, the feasibility tests of rice husk as a biological media for odor removal were carried out in order to know whether rice-husk contains useful components as a media for microbiological growth or not. Lastly, a combined test for odor gas absorption and biological oxidation was conducted using a lab scale bio-filter set-up packed with rice-husk pellets as wet-scrubber. The major components of the rice husk were carbon, hydrogen, nitrogen, and oxygen, while carbon acted as the main ingredient which comprised up to 23.00%. The C : N : P ratio was calculated as 45 : 1 : 2. Oxygen uptake rate, yield and decay rate of the rice husk eluent was calculated to be $0.0049mgO_2/L/sec$, 0.24 mgSS/mgCOD and 0.004 respectively. The most stable form of rice husk pellets was produced when the weight of the rice husk, EVAc, PVAc, and distilled water was 10 : 2 : 0.2 : 10. The prepared rice husk pellets had an apparent density of 368 g/L and a porosity of 59.00% upon filling. Dry rice husks showed high adsorption capacity for ammonia gas but low adsorption capacity for hydrogen sulfide. The bio-filter odor removal column filled with rice husk pellets showed more than 99.50% removal efficiency for NH3 and H2S gas. Through the analysis of circulation water, the prime removal mechanism is assumed to be the dissolution by water, microbial nitrification, and sulfation. Finally, it was confirmed that the microorganisms could survive well on the rice husk pellets, which provided them a stable supply of nutrients for their activity in this long-term experiment. This adequate supply of nutrients from the rice husk enabled high removal efficiency by the microorganisms.

Development of a Seismic Measurement System with a reference for the Reduction of Artificial Noise (인공잡음 제거를 위한 기준점 이용 탄성파 측정시스템 개발)

  • Hwang, Hak-Soo;Lee, Tai-Sup;Sung, Nak-Hoon
    • Geophysics and Geophysical Exploration
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    • v.2 no.4
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    • pp.180-183
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    • 1999
  • A proto-type seismic measurement system with a reference was developed to improve S/N (signal-to-noise ratio) of seismic data, especially in noisy urban areas. Two pairs of correlation measurements (the one for microphone and geophone, and another for electromagnetic (EM) loop and geophone) were carried out near Kimpo Airport and at Kimje. The spectrum analyses were also performed to investigate the correlation of two pairs of time series; one for microphone and geophone, and another for EM loop and geophone. The sound waves measured with the microphone and the geophone are highly correlated. However, differences in the reponses are readily identifiable across 200 Hz; in the vicinity of 100 Hz, the spectral energy for geophone is 20 dB higher than that for microphone, and at near 500 Hz, the spectral energy for microphone is 30 dB higher than that for geophone. Overall, the spectral energy appears concentrated on the frequency window below 600 Hz for geophone. It contrasts with the observation of dominant frequency at the range of above 200 Hz for microphone. The wave forms of EM noise (due to an ACDC inverter) measured with EM loop and geophone are consistently and highly correlated each other. The power spectrum of the EM noise for EM loop shows that the spectral energies at odd harmonic frequencies of 60 Hz are higher than those at even harmonic frequencies of 60 Hz. It is compared to the power spectrum for geophone; the spectral energies at odd harmonics are nearly same as those at even harmonic frequencies.

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Electric and Electromagnetic Surveys of the Hongseong Fault Zone (홍성 단층대에서의 전기, 전자 탐사 연구)

  • Kwon, Byung-Doo;Lee, Heui-Soon;Park, Gye-Soon;Oh, Seok-Hoon;Lee, Choon-Ki
    • Journal of the Korean earth science society
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    • v.24 no.4
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    • pp.361-368
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    • 2003
  • We have investigated the electric resistivity structure of the fault zone located in the Hongseong area where a big earthquake with M 5.0 occurred in 1978. Usually, Electric and Electromagnetic methods are broadly operated in the field of engineering works since these methods are effective to understand the distribution of geological weak zones - fault or fracture zones. We have conducted the dipole-dipole array resistivity method and MT(magnetotelluric) method and interpreted the resistivity distribution of the fault zone with the aid of various inversion methods. An MT survey was performed at 18 points along a 2.9 km survey line perpendicular to the fault line and a magnetic dipole source was used to enhance the S/N ratio in the high frequency. A Electric dipole-dipole array resistivity survey with the dipole length of 50 meters was carried out perpendicular to the fault. In view of two survey results, the fault marks the boundary between two opposite resistivity structures, especially the low resistivity zone is exhibited deeply through the prospective fault line. The result that the low resistivity zone is located at the center of the fault zone corresponds with the fact that the fault zone of the Hongseong area is active. We expect these results to provide basic information about the physical properties of fault zones in Korea.

Competitive Extraction of Chlorinated Solvents by Headspace SPME GC/FID (Headspace SPME GC/FID를 이용한 Chlorinated Solvents의 경쟁적 추출효과에 관한 연구)

  • An, Sangwoo;Kim, Youngju;Chun, Sukyoung;Lee, Sijin;Park, Jaewoo;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.5
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    • pp.61-67
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    • 2010
  • In this study, Solid-phase microextraction (SPME) with GC/FID was studied as a possible alternative to liquid-liquid extraction for the analysis of chlorinated solvents (PCE and TCE) and these by-products (cis-DCE, VC, and Ethylene). Experimental parameters affecting the SPME process (such as kind of fibers, adsorption time, desorption time, volume ratio of sample to headspace, salt addition, and magnetic stirring) were optimized. Experimental parameters such as CAR/PDMS, adsorption time of 20 min, desorption time of 5 min at $250^{\circ}C$, headspace volume of 50mL, sodium chloride (NaCl) concentration of 25% combined with magnetic stirring were selected in optimal experimental conditions for analysis of chlorinated solvents and these by-products. The general affinity of analytes to CAR/PDMS fiber was high in the order PCE>TCE>cis-DCE>VC>Ethylene. The linearity of $R^2$ for chlorinated solvents and these by-products was from 0.912 to 0.999 when analyte concentrations range from $10{\mu}g/L$ to $500{\mu}g/L$, respectively. The relative standard deviation (% RSD) were from 2.1% to 3.6% for concentration of $500{\mu}g/L$ (n=5), respectively. Finally, the limited of detection (LOD) observed in our study for chlorinated solvents and these by-products were from $0.5{\mu}g/L$ to $10{\mu}g/L$, respectively.

A Retrospective Clinical View of Basal Cell Carcinoma and Squamous Cell Carcinoma in the Head and Neck Region: A Single Institution's Experience of 247 Cases over 19 Years

  • Kang, Kyung Won;Lee, Dong Lark;Shin, Hea Kyeong;Jung, Gyu Yong;Lee, Joon Ho;Jeon, Myeong Su
    • Archives of Craniofacial Surgery
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    • v.17 no.2
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    • pp.56-62
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    • 2016
  • Background: The two most common skin cancers are basal cell carcinoma (BCC) and squamous cell carcinoma (SCC). The purpose of this study was to describe the detailed clinical behavior of BCC and SCC in the head and neck region over 19 years at a single institution. Methods: A retrospective analysis was performed for all patients with non-melanoma skin cancer who had undergone surgical resection over an 18-year period. Patient charts were reviewed for demographic information, tumor size, onset-to-diagnosis, anatomic location, clinical subtype, histologic differentiation, method of surgical treatment, and recurrence. Results: The review identified 265 cases of either BCC or SCC in 226 patients. Of the 226 patients, 80 (35.4%) were men and 146 (64.6%) were women. BCC (n=138, 55.9%) was more frequent than SCC (109, 44.1%). The most frequent age group was 70-to-79 year olds (45 patients, 35.2%) for BCC and 80-to-89 year olds (41 patients, 41.8%) for SCC. By aesthetic units of the face, the most common location was the nasal unit (44 cases, 31.9%) for BCC and the buccal unit (23 cases, 21.1%) for SCC. The most common clinical subtype of BCC was the nodular type (80 cases, 58.0%). Local flaps were most commonly used to cover surgical defects (136 cases, 55.1%). Recurrent rates were 2.2% for BCC and 5.5% for SCC. Conclusion: In our study, many characteristics of BCC and SCC were compared to previously published reports were generally similar, except the ratio of BCC to SCC. Further study can help to establish the characteristics of BCC and SCC.