• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.189.1-189.1
• /
• 2013

Titanium dioxide (TiO2) is a wide bandgap semiconductor possessing photochemical stability and thus widely used for photocatalysis. However, enhancing photocatalytic efficiency is still a challenging issue. In general, the efficiency is affected by physio-chemical properties such as crystalline phase, crystallinity, exposed crystal facets, crystallite size, porosity, and surface/bulk defects. Here we propose an alternative approach to enhance the efficiency by studying interfaces between thin TiO2 layers to be stacked; that is, the interfacial phenomena influencing on the formation of porous structures, controlling crystallite sizes and crystallinity. To do so, multi-layered TiO2 thin films were fabricated by using a sol-gel method. Specifically, a single TiO2 thin layer with a thickness range of 20~40 nm was deposited on a silicon wafer and annealed at $600^{\circ}C$. The processing step was repeated up to 6 times. The resulting structures were characterized by conventional electron microscopes, and followed by carrying out photocatalytic performances. The multi-layered TiO2 thin films with enhancing photocatalytic efficiency can be readily applied for bio- and gas sensing devices.

• Transactions of the Korean hydrogen and new energy society
• /
• v.32 no.6
• /
• pp.442-454
• /
• 2021

The porous transport layer (PTL) is essential to effectively remove oxygen and hydrogen gas from the electrode surface at high current density operation conditions. In this study, the effect of PTL with different characteristics such as pore size, pore gradient, interfacial coating was investigated by multi-layered sintered mesh. A water electrolysis single cell of active area of the 34.56 cm² was constructed, and IV performance and impedance analysis were conducted in the range of 0 to 2.0 A/cm². It was confirmed that the multi-layered sintered mesh PTL, which have an average pore size of 25 to 57 ㎛ and a larger pore gradient, removed bubbles effectively and thus seemed to improve IV performance. Also, it was confirmed that the catalytic metals such as Ni, NiMo coating on the PTL reduced activation overpotential, but increased mass transport overpotential.

• The Journal of the Acoustical Society of Korea
• /
• v.41 no.4
• /
• pp.375-388
• /
• 2022

This paper deals with the process of obtaining sound transmission loss of a cylindrical silencer lined with multi-layered poroelastic sound absorbing materials. The Biot model and the Johnson-Champoux-Allard-Lafarge (JCAL) model were used to deal with waves propagating in multi-layered poroelastic materials. The boundary conditions required for analysis of the silencer were obtained and the numerical process of finding modes was explained. A numerical experiment was conducted on the 2-layered silencer using the modes and the transmission loss converged with the first 12 modes. Finally, the mode matching method proposed in this research was validated by being compared with the results calculated from Finite Element Method (FEM) about different kinds of sound absorbing materials.

• Macromolecular Research
• /
• v.14 no.4
• /
• pp.430-437
• /
• 2006

The ultra-drawing process of an ultra high molecular weight polyethylene (UHMWPE) gel film was examined by incorporating linear low-density polyethylene (LLDPE) and $BaTiO_3$ nanoparticles. The effects of LLDPE and the draw ratios on the morphological development and mechanical properties of the nanocomposite membrane systems were investigated. By incorporating $BaTiO_3$ nanoparticles in the UHMWPE/LLDPE blend systems, the ultra-drawing process provided a highly extended, fibril structure of UHMWPE chains to form highly porous, composite membranes with well-dispersed nanoparticles. The ultra-drawing process of UHMWPE/LLDPE dry-gel films desirably dispersed the highly loaded $BaTiO_3$ nanoparticles in the porous membrane, which could be used to form multi-layered structures for electronic applications in various embedded, printed circuit board (PCB) systems.

• Ecology and Resilient Infrastructure
• /
• v.9 no.4
• /
• pp.228-236
• /
• 2022

Riverbank revetments are installed to increase the stability, while preventing scouring, and utilize the rivers; their construction is prioritized to secure dimensional safety that can withstand flooding. Existing revetment technologies employ use of rocks, gabions, and concrete. However, stone and gabions are easily erosion and destroyed by extensive flooding. Though the materials used in concrete technology possess strength and stability, the strong base adversely affects the aquatic ecosystem as components leach and remain in water for a long time. This serves as an environmental and ecological issue as vegetation does not grow on the concrete surface. This study introduces multi-layer porous riverbank revetment technology using biopolymer materials extracted from castor oil. Results obtained from this study suggest that this technology provides greater dimensional stability as compared to existing technologies. Moreover. it does not release toxic substances into the rivers. Multiple experiments conducted to review the application of this technology to diverse river environments confirm that stability is achieved at a flow velocity of 8.0 m/s and maximum tractive force of 67.25 kg_f/m² (659.05 N/m²).

• Transactions of the Korean hydrogen and new energy society
• /
• v.27 no.6
• /
• pp.642-650
• /
• 2016

One of the most feasible solution for reducing the excessive energy consumption and carbon dioxide emission is usage of more efficient fuel such as hydrogen. As is well known, there are three viable technologies for storing hydrogen fuel: compressed gas, metal hydride absorption, and cryogenic liquid. In these technologies, the storage for liquid hydrogen has better energy density by weight than other storage methods. However, the cryogenic liquid storage has a significant disadvantage of boiling losses. That is, high performance of thermal insulation systems must be studied for reducing the boiling losses. This paper presents an experimental study on the effective thermal conductivities of the composite layered insulation with aerogel blankets($Cryogel^{(R)}$ Z and $Pyrogel^{(R)}$ XT-E) and Multi-layer insulation(MLI). The aerogel blankets are known as high porous materials and the good insulators within a soft vacuum range($10^{-3}{\sim}1$ Torr). Also, MLI is known as the best insulator within a high vacuum range(<$10^{-6}{\sim}10^{-3}$ Torr). A vertical axial cryogenic experimental apparatus was designed to investigate the thermal performance of the composite layered insulators under cryogenic conditions as well as consist of a cold mass tank, a heat absorber, annular vacuum space, and an insulators space. The composite insulators were laminated in the insulator space that height was 50 mm. In this study, the effective thermal conductivities of the materials were evaluated by measuring boil-off rate of liquid nitrogen and liquid argon in the cold mass tank.

• The Journal of the Acoustical Society of Korea
• /
• v.43 no.3
• /
• pp.261-269
• /
• 2024

In this paper, the acoustic performance of an absorptive silencer was enhanced by optimizing an arrangement of multi-layered absorbing materials. The acoustic performance of the silencer was evaluated through transmission loss, and finite element method-based numerical analysis program was employed to calculate the transmission loss. Polyurethane, a porous elastic material frequently used in absorptive silencers, was employed as the absorbing material. The Biot-Allard model was applied, assuming that air is filled inside the polyurethane. By setting the frequency range of interest up to the 2 kHz and the acoustic performance affecting properties of the absorbing materials were investigated when it was composed as a single layer. And the acoustic performance of the silencers with the single and multi-layered absorbing materials was compared with each other based on polyurethane material properties. Subsequently, the arrangement of the absorbing materials was optimized by applying the Nelder-Mead method. The results demonstrated that the average transmission loss improved compared to the single-layered absorptive silencer.

• Membrane Journal
• /
• v.27 no.2
• /
• pp.167-181
• /
• 2017

Graphene-based materials have been considered as a promising membrane material, due to its easy processability and atomic thickness. In this study, we studied on gas permeation behavior in few-layered GO membranes prepared by spin-coating method. The GO membrane structures were varied by using different GO flake sizes and GO solutions at various pH levels. The GO membranes prepared small flake size show more permeable and selective gas separation properties than large one due to shortening tortuosity. Also gas transport behaviors of the GO membranes are sensitive to slit width for gas diffusion because the pore size of GO membranes ranged from molecular sieving to Knudsen diffusion area. In particular, due to the narrow pore size of GO membranes and highly $CO_2$-philic properties of GO nanosheets, few-layered GO membranes exhibit ultrafast and $CO_2$ selective character in comparison with other gas molecules, which lead to outstanding $CO_2$ capture properties such as $CO_2/H_2$, $CO_2/CH_4$, and $CO_2/N_2$. This unusual gas transport through multi-layered GO nanosheets can explain a unique transport mechanism followed by an adsorption-facilitated diffusion behavior (i.e., surface diffusion mechanism). These findings provide the great insights for designing $CO_2$-selective membrane materials and the practical guidelines for gas transports through slit-like pores and lamellar structures.

• Polymer(Korea)
• /
• v.32 no.4
• /
• pp.322-327
• /
• 2008

In this study, a multi-layered pellet was composed of a seed layer including a water-swellable agent and a drug layer containing doxazosin as a model drug, a porous membrane and a castor oil layer to control drug release. The pellet is prepared by a fluidized bed coating method. To confirm drug release from polymer blending in multi-layered pellet system, it is prepared by containing different ratio such as hydroxypropylmethylcellulose (HPMC) : ethyl cellulose (EC) in drug layer and cellulose acetate(CA) : Eudragit RS in membrane. Also, to confirm the effect of oil in drug release, castor oil is coated. As a result, we observed regularly spherical pellet with diameter of $1500{\mu}m$. Release pattern of drug is confirmed by dissolution tester in aqueous media. The more the ratio of EC in drug layer, CA in membrane, and castor oil layer in pellet, the less the drug release is observed. Formation and the amount of pores in membrane is observed by SEM.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.9 no.4 s.44
• /
• pp.67-74
• /
• 2005

This paper presents a new infinite element for modeling far-field region in dynamic analysis of a fluid-saturated two-phase medium. The infinite element method combined to the infinite element method has been effectively applied to several engineering problems where the full space or half-space medium should be modeled. However, the currently available infinite element for dynamic analysis of two-phase porous medium has a limitation that Pl and P2 waves can only be Included in shape function expressing behavior ol the body. In this paper, the infinite element method is extended to simulate arbitrary number of multi-component waves. For this purpose, the far-field of the porous medium is assumed to be a layered half-space, while the near-field Includes structures as well as irregular soil medium. The accuracy and effectiveness of the proposed element have demonstrated using 1-D and 2-D wave propagation problems.