• Journal of Microbiology and Biotechnology
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• v.23 no.7
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• pp.942-952
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• 2013

Monoliths are functional porous materials with a three-dimensional continuous interconnected pore structure in a single piece. A monolith with uniform shape based on poly(${\gamma}$-glutamic acid) (PGA) has been prepared via a thermally induced phase separation technique using a mixture of dimethyl sulfoxide, water, and ethanol as solvent. The morphology of the obtained monolith was observed by scanning electron microscopy and the surface area of the monolith was evaluated by the Brunauer Emmett Teller method. The effects of fabrication parameters such as the concentration and molecular mass of PGA and the solvent composition have been systematically investigated. The PGA monolith was cross-linked with hexamethylene diisocyanate to produce the water-insoluble monolith. The addition of sodium chloride to the phase separation solvent affected the properties of the cross-linked monolith. The swelling ratio of the cross-linked monolith toward aqueous solutions depended on the buffer pH as well as the monolith fabrication condition. Copper(II) ion was efficiently adsorbed on the cross-linked PGA monolith, and the obtained copper-immobilized monolith showed strong antibacterial activity for Escherichia coli. By combination of the characteristic properties of PGA (e.g., high biocompatibility and biodegradability) and the unique features of monoliths (e.g., through-pore structure, large surface area, and high porosity with small pore size), the PGA monolith possesses large potentials for various industrial applications in the biomedical, environmental, analytical, and separation fields.

• Transactions of the Korean Society of Automotive Engineers
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• v.2 no.5
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• pp.58-65
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• 1994

In order to reduce particulate emissions from diesel vehicles, mathematical model is established and analyzed on ceramic wall-flow monolith filter. A wall-flow monolith filter placed in the exhaust stream of a diesel engine can effectively limit the emission of diesel particulates through the monolith. The accumulated particulates can then be periodically combusted inside the monolith by directing hot gas to the monolith while normal engine exhaust is routed around the monolith system. The resulting low flow rates through the monolith require consideration of gas dynamics through the channels as well as particulate combustion to analyze this regeneration process. A mathematical model of the regeneration is formulated as a system of nonlinear partial differential equations describing the conservation of mass, momentum and energy. Numerical solutions are obtained by using a finite difference techniques for the spatial discretization. So we can use filter simulation program for the purpose of filter design and actual filter regeneration

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.6
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• pp.500-506
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• 2010

The metal monolith catalyst coated with 15wt% Ni/$MgAl_2O_4$ is applied to the natural gas steam reforming for hydrogen production. To address the improvement of adherence between metal monolith and catalyst coating layer, the pre-calcination temperature as well as the coating conditions of $Al_2O_3$ sol are optimized. When the Fe-Cr alloy monolith is pre-calcined at $900^{\circ}C$ for 6 h, $Al_2O_3$ layer was formed uniformly on the entire surface of the metal substrate. It is seen that the formation of $Al_2O_3$ layer on the monolith surface is essential for the uniform coating of $Al_2O_3$ sol onto the monolith substrate. The monolith catalyst coated with 10wt% $Al_2O_3$ sol shows high $CH_4$ conversion and good thermal stability as compared with the monolith catalyst without $Al_2O_3$ sol coating under severe reaction conditions with high GHSV of 30,000 $h^{-1}$ at $700^{\circ}C$. In addition, the metal monolith catalyst shows higher catalytic activity and better thermal conductivity than 15wt% Ni/$MgAl_2O_4$ pellet catalyst.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.2
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• pp.48-54
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• 2002

Since photocatalysts are activated by lights of UV wavelengths, plasma is alternatively used as a light source for a photocatalytic reactor. Light intensity generated by plasma is proportional to the surface area of catalytic material, and this, in many practical applications, is prescribed by the geometry of a plasma generator. Thus, it is crucial to increase the surface area far sufficient light intensity for photocatalytic reaction. For example, in a pack-bed type reactor, multitudes of beads are used as a substrate in order to increase the surface area. Honeycomb monolith type substrate, which has very good surface area to volume ratio, has been difficult to apply plasma as a light source due to the fact that light penetration depth through the honeycomb monolith was too short to cover sufficient area, thus resulting in poor intensity for photocatalytic reaction. In this study, nonthermal plasma generation through a photocatalytic reactor of honeycomb monolith substrate is investigated to lengthen this short penetration depth. The ceramic honeycomb monolith substrate used in this study has the same length as a three way catalyst used fur automotive applications, and it is shown that sufficient light intensity for photocatalytic reaction can also be obtained with honeycomb monolith type reactor.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.5
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• pp.55-65
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• 1998

A numerical and experimental study of three-dimensional steady incompressible non-reacting flow inside various dual-monolith catalytic converters has been conducted for achievement of performance improvement, reduction of light-off time and longer service life by improving the flow uniformity within the monolith. In this study, the effects of curvature of inlet exhaust pipe and monolith brick length on the flow uniformity and pressure drop within monolith were numerically investigated. The computations are confirmed by measurements of steady flow. The agreement between computations and experiment was relatively good. The result of this study shows that curvature of inlet exhaust pipe and monolith brick length gave a great effect on the flow uniformity and the shorter the brick length, the lower flow uniformity and the less pressure drop.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2943-2948
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• 2010

Silica monolith powders were prepared by a new procedure where ground powders of proper size distribution were obtained without sieving. An initiator was attached to this ground monolith and polystyrene was bound by reversible addition-fragmentation chain transfer polymerization to give a new stationary phase. The separation efficiency of this phase was found better than that of the polystyrene bound phase based on conventional silica particles and that of the C18 bound silica monolith powders.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.5
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• pp.63-71
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• 2007

The conversion efficiency, durability and pressure drop of the automotive exhaust catalysts are dependent on the flow distribution within the substrate. Conventional porous medium approaches assuming monolith resistance based on the one-dimensional laminar flow for simulating the flow through the automotive exhaust catalysts over-predict the flow uniformity in the monolith. In this study, additional pressure loss is also considered by accounting for entrance effects due to the oblique flow incident on the front face of monolith as a consequence of flow separation and recirculation within the diffuser. The incorporation of an additional pressure loss improves the predictions for the maximum flow velocity within the substrate. An numerical study has also been conducted for the three-dimensional unsteady incompressible non-reacting flow inside various dual-monolith catalytic converters for the rapid acceleration/deceleration driving.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.39 no.8
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• pp.805-812
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• 1990

In this paper, a design on the superconducting monolith for superconducting pulse magnet is described. Both stability and AC loss parameters are used in the design process, which restricted various design parameters. Determined design parameters satisfy both stability and AC loss restrictions. Finally superconducting monolith is flattened, fitting for magnet and acquiring transposition effect.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.1
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• pp.63-72
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• 1998

Simultaneous CO and $C_3H_6$ oxidation was carried out over noble metal supported monolith catalysts in a flow thorugh type reactor at the temperature ranging from room temperature to $500^\circ$C. Pt and Pd were selected as major active species, 10wt% of Ce was impregnated as an additive and alumina and silica were used as supports. The reactant gases were simulated and the reaction products were analyzed by on-line G.C.. EDX, SEM, TGA, XRD and optical microscope were used to analyze the characteristics of the prepared catalysts. Under the given conditions in this study, the catalysts supported on alumina showed better activity for CO oxidation, while Pd catalysts showed better activity for $C_3H_6$ oxidation. The improvement of conversion due to increase in thermal stability possibily by Ce addition was observed only for Pt catalysts.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.2
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• pp.40-47
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• 2002

Because UV wavelength lights can activate photocatalysts, plasma is used as a light source of a photocatalytic reactor. Even though plasma has good intensity for photo reaction, substrate of catalyst coating was limited by the geometry of plasma generator. Usually bead type substrate was used for a pack bed type reactor. Honeycomb monolith type substrate was used with UV lamps instead plasma, due to the light penetration the honeycomb monolith length was too short to show good activity In this study a photocatalytic reactor, which is using a honeycomb monolith substrate, was investigated with plasma as an activation light source. As a parametric study the effects of 1311owing factors on plasma generation and power consumption are examined; supply voltage, substrate length, environment condition, catalyst loading and ratio. Using the test results, the practicability test was done with simulated synthetic gases representing bad smells and automotive exhaust gases.