• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1995.11a
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• pp.113-117
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• 1995

The mechanism of the displacement current generation for stimulation transmit observed in the present displacement current measurement and theoretically analysed. The orientational change of molecules in monolayers was discussed on the basis of the Maxwell-displacement-current obtained. Maxwell displacement current was generated from monolayers on a water surface by monolayerr compression, and it measuring technique has been applied to the study of monolayers of Dipalmitoylphosphatidyl choline (L-${\alpha}$-DPPC). Finally, We measured that differential thermal analysis(DTA) of sample. Displacement current was generated when the area per molecule about 180${\AA}$$^2$in low pressure, and it was generated when the area per molecule about 110${\AA}$$^2$in high pressure. A result of DTA was showed that temperature at 124.6$^{\circ}C$.

• Tribology and Lubricants
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• v.19 no.6
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• pp.329-334
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• 2003

The antiwear properties of amphiphilic monolayers and composite multilayer on silicon surface were investigated using micro­tribometer and Auger Electron Spectroscopy. Langmuir­Blodgett (LB) monolayers from behenic acid, 2,4­heneicosanedione(HD) and its lopper complex((HD)$_2$Cu) were fabricated on silicon surface and the composite multilayer of 5­bilayer of (HD)$_2$Cu was fabricated on the surface of octadecyltrichlorosilane (OTS) self­assembled monolayer (SAM). We observed that LB monolayers and the composite multilayer exhibited a steady and excellent friction response when compared with the OTS SAM. These LB mono and multilayer also showed much higher wear­resistance than the OTS SAM.

• Bulletin of the Korean Chemical Society
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• v.26 no.4
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• pp.553-557
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• 2005

The formation of striped phases of unsymmetric hexyl octadecyl disulfide ($CH_3(CH_2)_5SS(CH_2)_{17}CH_3$, HOD) and 1-hydroxyundecyl octadecyl disulfide ($CH_3(CH_2)_{17}SS(CH_2)_{11}$OH, HUOD) on Au(111) and graphite has been investigated by scanning tunneling microscopy (STM) to understand the self-assembly processes of dialkyl disulfides. STM imaging clearly shows the formation of striped phases having corrugation periodicities that are nearly consistent with the molecular length of alkanethiolate moieties formed after the S-S bond cleavage of dialkyl disulfide on a gold surface. On the other hand, self-assembled monolayers (SAMs) of dialkyl disulfides on a graphite surface displayed long-range, well-ordered monolayers with one striped pattern that shows periodicity as a function of molecular length via nondissociative adsorption. From a nonoscopic viewpoint, we have clearly demonstrated that dialkyl disulfide SAMs on gold form via S-S bond cleavage of disulfide.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.822-825
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• 2003

Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time $\tau$ of floating monolayers on water surface is presented. WC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time $\tau$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.211-214
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• 2003

The tribological properties of amphiphilic monolayers and composite multilayer on silicon surface were investigated using micro-tribometer and Auger Electron Spectroscopy. Langmuir-Blodgett (LB) monolayers from behenic acid. 2.4-heneicosanedione(HD) and its copper complex((HD)$_2$Cu) were fabricated on silicon surface and the composite multilayer of 5-bilayer of (HD)$_2$Cu was fabricated on the surface of octadecyltrichlorsilane (OTS) self-assembled monolayer(SAM). We observed that LB monolayers and the composite multilayer exhibited a steady and excellent friction response when compared with the OTS SAM. These LB mono and multilayer also showed much higher wear-resistance than the OTS SAM.

• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.699-704
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• 2002

We characterized nanoelectrode arrays prepared from self-assembled monolayers (SAMs) by adsorption from a solution containing thiolated $\beta$-cyclodextrin ($\beta$-CD) and n-alkanethiol on the gold electrode surface, using electrochemical methods. While the framework, the n-hexadecanethiol SAM, effectively blocked electron transfer between the electrode surface and solution-phase redox probe molecules, the $\beta$-CD cavities isolated in the forests of n-hexadecanethiol molecules were shown to act as an ultramicroelectrode array. The shapes of cyclic voltammograms of probe molecules were related to the number densities of $\beta$-CD molecules within the monolayer films. Probe molecules that have the correct combination of physical and chemical characteristics were shown to effectively penetrate the framework through the $\beta$-CD pores and exchange electrons with the electrode surface.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.55 no.3
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• pp.107-110
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• 2006

We fabricated the monolayers onto QCM by self-assembly using viologen, which has been widely used as electron acceptor. A gold electrode of the QCM was cleaned by piranha solution and prepared the ethanol-acetonitrile(1:1) solution with 2 m mol/l viololgen compounding of pure hi gas. We determined the time dependence to resonant frequency shift during self-assembly process and the electrochemical behavior of the self-assembled viologen monolayers by cyclic voltammetry. With increasing scan rate, the redox peak current of the viologen increased linearly. This was signified that the redox reaction was reversible. The EQCM measurements revealed the anions transfer during redox reactions, respectively. From the EQCM data, the well-defined shape peaks were nearly equal charges by cyclic voltammetry.

• Bulletin of the Korean Chemical Society
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• v.26 no.1
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• pp.127-130
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• 2005

The early stage of the self assembly for octadecyltrichlorosilane (OTS)-based monolayers is investigated using atomic force microscopy (AFM). Height measurements using AFM prove that the island height of the monolayers gradually increases with increasing the island size, and is close to the limiting value (h = $\sim$25 $\AA$) after d = $\sim$600 nm in size. Since the theoretical length of a covalently bound OTS molecule is 26.2 Å, the limiting value of the island height means that the islands with d ${\geq}$ 600 nm consist of close-packed, fully extended chains. The heights for the islands with d < 600 nm are lower than the limiting value and decrease with decreasing the island sizes. This observation indicates that the OTS molecules in the small islands are less densely packed, and that the packing densities of the islands increase as the islands grow in size.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.283-286
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• 2000

In this paper, generation form of displacement current was compared and measured induce monolayers which 8A5H with Pure azobenzene. Light response of two monolayers which compared and measured though they are the same isomer. The experimental results are as following; In case of ultraviolet($\lambda_1$) and visible($\lambda_2$) irradiation on 8A5H induce monolayers depositioned on board the peak of current was detected about 10[fA]. but light irradiation on pure azobenzene any particular reaction for detailed. This is the reason of hydrophobicity construct in molecule structures its molecule dynamic behaviour in cis and trans was not due to activated.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1583-1585
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• 2003

Maxwell displacement current(MDC) measuring technique has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time ${\tau}$ of floating monolayers on the water surface is presented. MDC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time ${\tau}$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.