• Title/Summary/Keyword: Molecular thin film

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A Scope of Functional Molecular Materials (기능성 분자재료의 발전 방향)

  • Shin, Dong-Myung;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.136-138
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    • 1990
  • In developing, microscopic scale electrical and electronic devices, molecular level Insulators and functional electric conductors are fundamental. The properties of the electrical-insulating thin film materials are very much dependent on defects and electron transfer rate. There are number of companies which try to reduce defects and control electrical conductivity. Functional electrical conductors are more demanding subject in electrical fields. Reorganization energy around the sites that generate the electrons and holes are very important for the electron transfer in the organic thin layers.

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Lubrication Effect of Journal Bearing according to its Eccentricity and Attitude Angle (베어링 편심도와 자세각에 따른 저어널 베어링의 윤활효과)

  • Kim, Jong-Do;Wang, Yi-Jun;Yoon, Moon-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.5
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    • pp.88-95
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    • 2015
  • The thickness of adsorbed molecular layers is the most critical factor in studying thin-film lubrication, and it is the most essential parameter that distinguishes thin-film from thick-film lubrication analysis. The thin film between the shaft and bearing surface within a very narrow gap was considered. The general Reynolds equation has been derived for calculating thin-film lubrication parameters affecting the performance of the circular journal bearing. Investigation of the load-carrying capacity and pressure distribution for the journal bearing considering the adsorbed layer thickness has been carried out. A Reynolds equation appropriate for the journal bearing is used in this paper for the analysis, and it is discussed using the finite difference method of the central difference scheme. The parameters, such as eccentricity and attitude angle, are used for discussing the load-carrying capacity of the journal bearing. The results reported in this paper should be applied to analysis of the journal bearing with different lubrication factors. The steady-state analysis of the journal bearing is conducted using the Reynolds model under thin-film lubrication conditions. For a journal bearing, several parameters, such as a pressure, load capacity, and pressure components of the bearing can be obtained, and these results can be stored in a sequential data file for later analysis. Finally, their distribution can be displayed and analyzed easily by using the MATLAB GUI technique. The load-carrying capability of the journal bearing is observed for the specified operating conditions. This work could be helpful for the understanding and research of the mechanism of thin-film lubrication.

Additive Fabrication of Patterned Multi-Layered Thin Films of Ta2O5 and CdS on ITO Using Microcontact Printing Technique

  • Lee, Jong-Hyeon;Woo, Soo-Yeun;Kwon, Young-Uk;Jung, Duk-Young
    • Bulletin of the Korean Chemical Society
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    • v.24 no.2
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    • pp.183-188
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    • 2003
  • The micro-patterning of multi-layered thin films containing CdS and $Ta_2O_5$ layers on ITO substrate with various structures was successfully obtained by combining three different techniques: chemical solution depositions, sol-gel, and microcontact printing (μCP) methods using octadecyltrichlorosilane (OTS) as the organic thin layer template. $Ta_2O_5$ layer was prepared by sol-gel casting and CdS one obtained by chemical solution deposition, respectively. Parallel and cross patterns of multi-layers with $Ta_2O_5$ and CdS films were fabricated additively by successive removal of OTS layer pre-formed. This study presents the designed architectures consisting of the two types of feature having horizontal dimensions of 170 ㎛ and 340 ㎛ with constant thickness ca. 150 nm of each deposited materials. The thin film lay-out of the cross-patterning is composed of four regions with chemically different layer compositions, which are confirmed by Auger electron microanalysis.

A Study on the Molecular Orientation of Po1yamic Acid Alkylamine Salt Langmuir-Blodgett Films (Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구)

  • 정순욱;임현성
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.53.1-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle($\theta$) of the dipole moment is about 68$^{\circ}$and the tilting angle of the alkyl chain is about $11.5^{\circ}$ .

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A Study on the Molecular Orientation of Polyamic Acid Alkylamine Salt Langmuir-Blodgett Films (Polyamic Acid 알킬아민 염 랭뮤어-블로젯막의 분자 배향에 관한 연구)

  • 정순욱;임현성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.53-56
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    • 2000
  • Langmuir-Blodgett(LB) technique is the best candidate for the future molecular electronic devices. But, these molecular thin film devices require the bulk properties that are influenced by the molecular orientations. So, this is of current interest in molecular electronic device fabrications of new materials. In this study, quantitative evaluation of molecular orientation in LB films of PAAS was performed by comparing the absorption intensities of the FT-IR transmission and reflection-absorption spectra and the polarized UV/visible absorption spectra. It was found that the polar angle( $\theta$ ) of the dipole moment is about 68$^{\circ}$ and the tilting angle of the alkyl chain is about 11.5$^{\circ}$

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Electrical characteristics of Pentacene thin film (Pentacene 박막의 전기적 특성에 관한 연구)

  • Kim, Dae-Yop;Kang, Do-Yol;Choi, Jong-Sun;Kim, Young-Kwan;Shin, Dong-Myung;Choi, Don-Su
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1950-1952
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    • 1999
  • Pentacene thin films are a component for active layer of Organic thin film transistors. Pentacene film was deposited by Organic Molecular Beam Deposition(OMBD) and electrodes were deposoted by vacuum evaporation. Electrical characterization of Pentacene films were measured by two probe methods, as the results. The Au/Pentacene/Al contact is Ohimic contact. Band diagram of pentacene films were measured by UV-spectrum and Cyclic-Voltammetry method.

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A Study on Electroluminescence Device with Polymer (고분자를 이용한 전계발광소자에 관한 연구)

  • Lee, Jong-Chan;Lee, Cheong-Hak;Park, Su-Gil;Lim, Kee-Joe;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1219-1221
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    • 1997
  • Poly(1,4-phenylene(1-methoxyenthylene)), organic water soluble PPV precursor was synthesized for polymer electroluminescence(EL) device. To control the molecular array, deposition method of emitter was Langmuir-Blodgett(LB). PPV precursor layer was treated thermally to conversion of PPV. Optical, electrical and EL properties of PPV LB thin film was estimated. Homogeneous light emission of greenish-yellow in PPV LB thin film can be easily confirmed under normal lighting even at low driving voltage. Polymer EL device using PPV LB thin film as emitter materials had a possibility to apply to next generation display device.

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Resist characteristics and molecular structure control of polystyrene by plasma polymerization method (플라즈마중합법에 의한 폴리스티렌의 분자구조 제에 및 레지스트 특성 조사)

  • 박종관;김영봉;김보열;임응춘;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.438-443
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    • 1996
  • The effect of plasma polymerization conditions on the structure of the plasma polymerized styrene were investigated by using Fourier Transform Infrared Ray(FT-IR), Differential Scanning Calorimetry (DSC), Gel Permeation Chromatography(GPC). Plasma polymerized thin film was prepared using an interelectrode inductively coupled gas-flow-type reactor. We show that polymerization parameters of thin film affect sensitivity and etching resistance of plasma polymerized styrene is 1.41~3.93, and deposition rate of that are 32~383[.angs./min] with discharge power. Swelling and etching resistance becomes more improved with increasing discharge power during plasma polymerization. (author). 11 refs., 10 figs., 1 tab.

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Effects of the Deposition Rate of Pentacene Film on the Electrical Characteristics of Organic Thin-film Transistors

  • Park, Jae-Hoon;Lee, Yong-Soo;Kang, Chang-Heon;Kim, Yeon-Ju;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.649-652
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    • 2003
  • Organic thin-film transistors were fabricated using pentacene as an active electronic material. Device characteristics are improved with increasing the deposition rate of pentacene. It is observed that the deposition rate influences on the interface properties between pentacene and polystyrene, and the molecular ordering of pentacene film. In this paper, we report the effects of the deposition rate of pentacene film on the device performance.

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Growth of La0.35Pr0.35Ca0.3MnO3/LaAlO3 Thin Film using Laser Molecular-Beam Epitaxy and its Magnetic Properties (Laser Molecular-Beam Epitaxy를 이용한 La0.35Pr0.35Ca0.3MnO3/LaAlO3 초격자 박막의 합성과 그 자기적 특성의 연구)

  • Seung, S.K.;Song, J.H.
    • Journal of the Korean Magnetics Society
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    • v.21 no.3
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    • pp.93-98
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    • 2011
  • We successfully grew $La_{0.35}Pr_{0.35}Ca_{0.3}MnO_3$(LPCMO)/$LaAlO_3$(LAO) thin film using Laser Molecular-Beam Epitaxy and studied post-growth annealing effects ($750^{\circ}C$, 5 h) on its crystal structural and magnetic properties. Whereas the single-layered LPCMO and LPCMO/STO superlattice thin films show rough surface before and after the post-growth annealing, LPCMO/LAO superlattice shows a relatively very flat surface even after the post-growth annealing. The enhancement of ferromagnetism of LPCMO/LAO superlattice after the post-growth annealing was remarkable compared to the single-layered LPCMO thin film. The coercive and saturation magnetic field of the single-layed LPCMO thin film were decreased after the post-annealing. However, for LPCMO/LAO superlattice, a same coercive and increased saturation magnetic field were exhibited after post-growth annealing. We suggest that these peculiar observations are originate from the super-structure of LPCMO and LAO.