• 제목/요약/키워드: Modified materials

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RF-magnetron Sputtering Process를 이용한 a-축 우선 배향된 PLZT(x/0/100)박막의 제조 (Characterization and Preparation of a-axis Preferred Oriented PLZT(x/0/100) Thin Films Deposited by RF-magnetron Sputtering Process)

  • 박명식;강승국;노광수;김동범;조상희
    • 한국재료학회지
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    • 제7권6호
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    • pp.522-528
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    • 1997
  • RF-magnetron Sputtering Process를 이용하여 Pt/Ti/Si(100)기판위에 lanthanum-modified lead titanate 박막을 제작하였다. 기판온도와 증착시간이 증가함에 따라 증착율은 감소하였다. 기판온도가 증가함에 따라 fine grain들은 large grain으로 변화하였다. Perovskite구조는 기판온도 54$0^{\circ}C$, gas pressure 30mtorr에서 나타나기 시작하였다. 본 실험에서 perovskite 박막제작에 대한 조건은 기판온도 58$0^{\circ}C$, gas pressure 30mtorr였다. Pt/Ti/Si(100) 우선 배향된 박막을 얻었다. La양이 증가함에 따라 유전율, 항전계, 잔류분극량은 증가하였다. 중심주파수가 44.7MHz, 전파속도는 2680m/sec를 가지는 SAW filter 특성을 얻었다.

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Application of Modified Rapid Thermal Annealing to Doped Polycrystalline Si Thin Films Towards Low Temperature Si Transistors

  • So, Byung-Soo;Kim, Hyeong-June;Kim, Young-Hwan;Hwang, Jin-Ha
    • 한국재료학회지
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    • 제18권10호
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    • pp.552-556
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    • 2008
  • Modified thermal annealing was applied to the activation of the polycrystalline silicon films doped as p-type through implantation of $B_2H_6$. The statistical design of experiments was successfully employed to investigate the effect of rapid thermal annealing on activation of polycrystalline Si doped as p-type. In this design, the input variables are furnace temperature, power of halogen lamps, and alternating magnetic field. The degree of ion activation was evaluated as a function of processing variables, using Hall effect measurements and Raman spectroscopy. The main effects were estimated to be furnace temperature and RTA power in increasing conductivity, explained by recrystallization of doped ions and change of an amorphous Si into a crystalline Si lattice. The ion activation using rapid thermal annealing is proven to be a highly efficient process in low temperature polycrystalline Si technology.

산성비 및 배연탈황설비 환경에서 Ni 첨가에 따른 저합금강의 내식성 비교연구 (Comparative Study of Ni effect on the Corrosion Behavior of Low Alloy Steels in FGD and Acid Rain Environments)

  • 한준희;;장영욱;김정구
    • 대한금속재료학회지
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    • 제47권9호
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    • pp.558-566
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    • 2009
  • The alloying effect of a small amount of nickel on low alloy steel for application to flue gas desulfurization(FGD) systems was studied. The structural characteristics of the rust layer were investigated by scanning electron microscopy(SEM). The electrochemical properties were examined by means of potentiostatic polarization test, potentiodynamic polarization test, and electrochemical impedance spectroscopy(EIS) in a modified green death solution of 16.9 vol.% $H_2SO_4$+0.35 vol.% HCl at $60^{\circ}C$ and an acid rain solution of $6.25{\times}10^{-5}M\;H_2SO_4+5.5{\times}10^{-3}M\;NaCl$ at room temperature. It was found that as the amount of nickel increased, the corrosion rate increased in the modified green death solution, which seemed to result from micro-galvanic corrosion between NiS and alloy matrix. In acid rain solution, the corrosion rate decreased as the amount of nickel increased due to the repulsive force of $NiFe_2O_4$ rust against $Cl^-$ ions by electronegativity.

표면 개질된 나노피브릴화 셀룰로오스를 이용한 에멀젼 안정화 및 고분자 입자 제조 (Surface-modified Cellulose Nanofibril Surfactants for Stabilizing Oil-in-Water Emulsions and Producing Polymeric Particles)

  • 김보영;문지연;유명재;김선민;김정아;양현승
    • 공업화학
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    • 제32권1호
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    • pp.110-116
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    • 2021
  • In this work, the surface of hydrophilic cellulose nanofibrils (CNFs) was modified precisely by varying amounts of cetyltrimethylammonium bromide (CTAB) to produce CNF-based particle surfactants. We found that a critical CTAB density was required to generate amphiphilic CTAB-grafted CNF (CNF-CTAB). Compared to pristine CNF, CNF-CTAB was highly efficient at stabilizing oil-in-water Pickering emulsions. To evaluate their effectiveness as particle surfactants, the surface coverage of oil-in-water emulsion droplets was determined by changing the CNF-CTAB concentration in the aqueous phase. Furthermore, styrene-in-water stabilized by CNF-CTAB surfactants was thermally polymerized to produce CNF-stabilized polystyrene (PS) particles, offering a great potential for various applications including pharmaceuticals, cosmetics, and petrochemicals.

한약인성 간손상의 원인산정법으로 도입된 진단 척도(Modified RUCAM scale)에 대한 임상적 고찰 (A Clinical Study on the Modified RUCAM Application to Liver Injury Induced by Herbal Medicine)

  • 천진홍;민상연;김장현
    • 대한한방소아과학회지
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    • 제22권3호
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    • pp.83-94
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    • 2008
  • Objectives : The purpose of this study is to confirm severe problem caused by using a modified RUCAM scale than that officially recognized to diagnose liver injury induced by herbal medicine. Materials and Methods : Cases with liver injury induced by herbal medicine received to a related institute from January 2004 to December 2007 were collected and evaluated by the original scale and modified scale. Results : 1. Based on this study, we couldn't clinicaly confirm that the case was not excluded by the relieved first item basis of modified RUCAM scale which has to be excluded by the first item basis of orginal RUCAM scale. 2. By modified 6th item, one score was added to the total score. 3. By adding 8th item, it gaind one point to the whole the total score. Conclusions : In this study, we can clinically confirm that the modified RUCAM application to case with liver injury induced by herbal medicine is a severe problem.

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Resin-Modified Glass-Ionomer와 Compomer의 경화 반응 특성의 비교에 관한 연구 (A COMPARISON OF THE SETTING CHARACTERISTICS BETWEEN RESIN-MODIFIED GLASS-IONOMERS AND COMPOMERS)

  • 고용준;유현미;엄정문
    • Restorative Dentistry and Endodontics
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    • 제25권1호
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    • pp.123-132
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    • 2000
  • To overcome problems of conventional glass ionomers, resin components have been added to glass ionomers. On a continuum between glass ionomers and composites are a variety of blends, employing different proportions of acid-base and free radical reactions to bring about cure. Popular groups defined between the ends are resin-modified glass-ionomers(RMGIs), polyacid-modified composite resins(Compomers) and ionomer modified resins. These groups show different clinical properties, and in selecting these materials for a restoration, one should sufficiently understand these different setting properties. In this study, some difference in the setting characteristics of different groups of hybrid ionomers were examined. Two RMGIs (Fuji2 LC,GC / Vitremer, 3M), three Compomers (Dyract AP, Dentsply / F2000, 3M / Elan, Kerr) were involved in this study. The identification of the setting characteristics of different groups was achieved by a two-stage study. First, thermal analysis was performed by a differential scanning calorimeter, and then the hardness of each group at different depth and time were measured by a micro-hardness tester. Thermal analysis was performed to identify the inorganic filler content and to record the heat change during setting process. The setting process was progressed for each material by chemical set mode and light-cured mode. In the hardness test, samples of materials were prepared with a 6mm-diameter metal ring, and the hardness was measured at the top, and 1mm, 2.5mm, 4mm below at just after a 40 second-cure, and after 10 minutes, 24 hours, and 7 days. Statistical analysis was performed by Mann-Whitney rank sum test to assess significant differences between set modes and types of materials, and by ANOVA and T-test to evaluate the statistical meanings of data at different times and depths of each materials. Followings are findings and conclusions derived from this study. Thermal analysis; 1. Compomers show no evidence of chemical setting while RMGIs exhibit heat output during the process of chemical setting. 2. Heat of cure of RMGIs exceed Compomers. 3. The net heat output of RMGIs through light-cured mode is higher than through chemically set mode. Hardness test; 1. Initial hardness of RMGIs immediately after light cure is relatively low, but the hardness increases as time goes by. On the contrary, Comomers do not show evident increase of the hardness following time. 2. Compomers show a marked decrease of setting degree as the depth of the material increases. In RMGIs, the setting degree at different depths does not significantly differ.

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Uncertainty Analysis of Concrete Structures Using Modified Latin Hypercube Sampling Method

  • Yang, In-Hwan
    • International Journal of Concrete Structures and Materials
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    • 제18권2E호
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    • pp.89-95
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    • 2006
  • This paper proposes a modified method of Latin Hypercube sampling to reduce the variance of statistical parameters in uncertainty analysis of concrete structures. The proposed method is a modification of Latin Hypercube sampling method. This analysis method uses specifically modified tables of random permutations of ranked numbers. In addition, the Spearman coefficient is used to make modified tables. Numerical analysis is carried out to predict the uncertainty of axial shortening in prestressed concrete bridge. Statistical parameters obtained from modified Latin Hypercube sampling method and conventional Latin Hypercube sampling method are compared and evaluated by a numeric analysis. The results show that the proposed method results in a decrease in the variance of statistical parameters. This indicates the method is efficient and effective in the uncertainty analysis of complex structural system such as prestressed concrete bridges.

MMA/BA 합성 라텍스 혼입 폴리머 시멘트 모르타르의 세공성상 (Porosity of Polymer-Modified Mortars Using Methylmethacrylate-Butyl Acrylate Latexes with Various Monomer Ratios)

  • 형원길;송해룡;김완기;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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    • pp.87-92
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    • 2002
  • At present, the polymer-modified mortars are used as high-performance as well as multi-functional materials in the construction industry. The purpose of this study is to synthesize polymer to modify in cement mortars and make test samples to understand pore size distribution. This paper deals with the effect of monomer ratio on the typical properties of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate(MMA/BA) latexes synthesized through emulsion polymerization. From the results, we knew that the pore volume of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate latexes at bound MMA contents of 70 and 60 percent is 7.5-75cm$^3$/g and the fine pore volume is increased with an increase in the polymer-cement ratio. The total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio.

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Effects of Silica Fume Content and Polymer-Binder Ratio on Properties of Ultrarapid-Hardening Polymer-Modified Mortars

  • Choi, Jong Yun;Joo, Myung-Ki;Lho, Byeong Cheol
    • International Journal of Concrete Structures and Materials
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    • 제10권2호
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    • pp.249-256
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    • 2016
  • This paper deals with the effects of silica fume content and polymer-binder ratio on the properties of ultrarapid-hardening polymer-modified mortar using silica fume and ethylene-vinyl acetate redispersible polymer powder instead of styrene-butadiene rubber latex to shorten the hardening time. The ultrarapid-hardening polymer-modified mortar was prepared with various silica fume contents and polymer-binder ratios, and tested flexural strength, compressive strength, water absorption, carbonation depth and chloride ion penetration depth. As results, the flexural, compressive and adhesion strengths of the ultrarapid-hardening polymer-modified mortar tended to increase as increasing polymer-binder ratio, and reached the maximums at 4 % of silica fume content. The water absorption, carbonation and chloride ion penetration resistance were improved according to silica fume content and polymer-binder ratio.

가공된 석탄재를 사용한 석탄재혼합시멘트의 모르터 특성 (The Mortar Properties of Portland Cements Blended with Modified Coal Ashes)

  • 홍원표;노재성;조헌영;정수영;김무한
    • 한국세라믹학회지
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    • 제27권7호
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    • pp.833-840
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    • 1990
  • For the development of multi-functional materials which has water reducing power, air entraining power and waterproofing power as well as blending additive in cement mortar the coal ash was modified with asphalt-stearic acid or asphalt-boiled oil mixtures by mechanical treatment. And the physical properties of cement mortar blended with modified coal ashes were compared with those of the water-tightness-cement mortar and the ordinary-portland-cement mortar added with AE.water reducing agent. The mortar of coalash-blend-cement modified with asphalt-stearic mixture was increased acid about 20% in initial strengths and decreased about 20% in water absorption ratio than those of ordinary coalash-blend-cement. The mortar of coalash-blend-cement modified with asphalt-bolied oil mixture was similar to the cement mortar added with AE.water reducing agent in water reduction ratio, air entraining conents and the initial strengths, also was similar to the water-tightness-cement mortar in water absorption and water permeability ratios.

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