• 제목/요약/키워드: Mo addition

검색결과 1,356건 처리시간 0.024초

자동차배기관용 페라이트계 스테인레스강의 고온염부식에 미치는 Mo, Ti, Nb 원소의 영향 (Effect of Mo, Ti, Nb on the hot salt corrosion behavior of ferritic stainless steels for automotive exhaust system)

  • 김수정;안용식
    • 한국해양공학회지
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    • 제11권3호
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    • pp.48-55
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    • 1997
  • The steel for automotive exhaust system needs a good corrosion resistance at the atmosphere of high temperature NaCl. Effect of the alloying elements Me, Ti, Nb on the NaCl induced hot corrosion behavior was investigated at the temperatures between 55$0^{\circ}C$ and 75$0^{\circ}C$ for 18Cr ferritic stainless steels. The weight loss by corrosion has increased linearly with corrosion cycle time, and the corrosion rate has accelerated at higher temperature. The alloying of Mo significantly improved corrosion resistance of the steel and the effect was more pronounced at higher temperature. The addition of alloying elements Ti, Nb have also shown improved corrosion resistance by formation of Ti(C,N) or Nb(C, N) precipitates.

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$BaTiO_3$ 세라믹의 유전손실에 미치는 Mn 첨가의 영향 (Effect of Mn Addition on the Dielectric Loss characteristics of $BaTiO_3$ Ceramics)

  • 김태중;한주환;이재열;이희영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.436-439
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    • 2000
  • Change of dielectric loss of use in high relative permitivity capacitor BaTiO$_3$ ceramic depends on Mn doping have been investigated. The powders used in this study were commercial BaTiO$_3$, TiO$_2$and, MnCO$_3$. Sample was fabricated by conventional ceramic process. The quantity of Mn was changed gradually from 0.lmol% to 10mo1%. The sintering densities were reduced with increasing amount of MnCO$_3$. This result is because of increase of low density second phase BaMnO$_3$. When the samples were doped by over 0.2mol% of MnCO$_3$, average grain sizes were enlarge to several tens ${\mu}{\textrm}{m}$. The dielectric losses were reduced by Mn doping to lmol% but, increased from lmol% to 10mo1% gradually.

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주강계 저열팽창 주조합금의 열팽창 계수와 경도에 미치는 Mo, V 첨가의 영향 (Effects of Mo, V addition on Linear Thermal Expansion Coefficient and Hardness of Low Thermal Expansion Cast Steel)

  • 김영한;윤의박;문병문;홍영명
    • 한국주조공학회지
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    • 제18권5호
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    • pp.467-473
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    • 1998
  • For enhancing the mechanical properties of LTE (low thermal expansion) cast steel, systematic researches have been carried out. The effects of alloying elements such as vanadium, molybdenum and carbon on the hardness and linear thermal expansion coefficient were investigated. In the range of $0.5{\sim}2.3\;wt%$ carbon, addition of 1.73 wt% carbon caused hardness increase due to the formation of eutectic carbide having high hardness but over the range of 1.73 wt% carbon, hardness was decreased. Thermal expansion coefficient increases with carbon contents. In the LTE cast steel containing 0.6 wt% carbon, hardness increased up to 1.96 wt% vanadium addition. But over the range of 1.96 wt% vanadium hardness was decreased by coarse eutectic carbide. Thermal expansion coefficient of LTE cast steel containing 0.6 wt%carbon moderately increased with increasing vanadium contents. There was no significant variation of hardness and thermal expansion coefficient according to molybdenum content in LTE cast steel.

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Inulin의 산 가수분해 반응에 과산화수소가 미치는 영향 (Effect of Hydrogen Peroxide on the Acid Hydrolysis of Inulin)

  • 윤석준;김성배최주홍박영철
    • KSBB Journal
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    • 제10권3호
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    • pp.298-303
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    • 1995
  • 과산화수소는 유기물에 접촉시에 물과 산소로 급속하게 분해되어 탄수화물과 같은 고분자물질을 저 분자물질로 분해하는 특성을 지니고 였다. 이러한 특성이 inulin의 산 가수분해 반응에 미치는 영향을 초음파를 조사시키면서 연구하였다. 반응조건은 온도가 $50∼60^{\circ}C$ 엽산의 농도가 O.1~O.3%(w/w) 였고, 이 조건하에서 과산화수소 농도가 2.3% (w/v) 일 때 가수분해 효과가 최대로 나타났다. 과산화 수소의 첨가로 control 반응에 비해 9~43% 의 분 해속도 증가를 보였다. 과산화수소를 첨가했을 경우 와 첨가하지 않았을 경우에 활성화에너지는 각각 26kcal/mol과 25kcal/mol로 거의 통일하였다. 따라서 과산화수소에 의한 inulin 가수분해 속도의 상승 효과는 frequency factor의 증가로 해석되 었다.

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Density Functional Theory Studies on the Electrophilic versus Electron Transfer Mechanisms of Aryl Vinyl Ethers

  • 김왕기;손창국;임선희;이순기;김창곤;이익춘
    • Bulletin of the Korean Chemical Society
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    • 제20권10호
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    • pp.1177-1180
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    • 1999
  • The ab initio SCF MO and density functional theory (DFT) studies are carried out on the electrophilic (1a) and electron transfer (1b) addition reactions to the vinyl double bond of aryl vinyl sulfides and ethers. In the electrophilic addition processes, a double bond shift from C3 = C4 to X = C3 occurs with occupation number (1.97) close to the normal two. Due to this shift direct conjugation between the cationic center, X = S or O, and the para electron-donor substituent becomes impossible so that the reaction energies (or log K) are correlated with σ rather than σ+. By contrast, radical cation formation leads to delocalization of the SOMO, a lone-pair πorbital on X, with four major resonance structures in which cationic charge as well as spin density is delocalized over C4 , X and C7 atoms. As a result, partial πbonds are formed over C1 -X and C3 - C4 with occupation numbers (0.82) lower than one. In two of the cannonical structures, III(Ⅹ) and III(X+), direct conjugation between the cationic center, X, and the para substituent is achieved so that a better correlation with σ+ rather than σis obtained. The SCF MO energies at the HF/3-21G* and HF/6-31G* levels lead to very much inferior Hammett correlations in the σ/ σ+ diagnostic criterion. In contrast, the ρvalues evaluated with the DFT energies can give reliable diagnostic distinction between the two addition mechanisms.

Polymorphism of Insulin-like Growth Factor 1 Receptor Gene in 12 Pig Breeds and Its Relationship with Pig Performance Traits

  • Wang, Wenjun;Ouyang, Kehui;Su, Xifan;Xu, Mingsheng;Shangguan, Xinchen
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권11호
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    • pp.1541-1545
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    • 2006
  • The polymorphism of insulin-like growth factor I receptor (IGFIR) gene in 12 pig breeds (total n = 593) was detected by PCR-SacII-restriction fragment length polymorphism and allele A (379 bp) or allele B (235 bp and 144 bp) observed. In the studied breeds, it was found that European pigs principally carried allele A, while Chinese native pig breeds principally carried allele B. In addition, the role of pig IGFIR was investigated in 156 Wanbai pigs and 212 Large Yorkshire pigs. Growth related variables including body weight at birth, 2-, 4- and 6-mo of age and backfat thickness and lean percentage estimated by ultrasonography at 6-mo of age were recorded in analyzing the association between IGFIR gene polymorphism and growth traits. AA-genotype pigs exhibited greater (p<0.05) body weights (BW) at birth, 2- and 6-mo of age, but not at 4-mo of age, than those of the BB-genotype in Wanbai and Yorkshire breeds. Moreover, in the Yorkshire breed, AA-genotype pigs had less backfat thickness (p<0.05) and greater lean percentage (p<0.01) than the BB genotype. Based on these results, it is necessary to do more studies on IGFIR before introducing the IGFIR locus into breeding programs.

Administration of red ginseng ameliorates memory decline in aged mice

  • Lee, Yeonju;Oh, Seikwan
    • Journal of Ginseng Research
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    • 제39권3호
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    • pp.250-256
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    • 2015
  • Background: It has been known that ginseng can be applied as a potential nutraceutical for memory impairment; however, experiments with animals of old age are few. Methods: To determine the memory enhancing effect of red ginseng, C57BL/6 mice (21 mo old) were given experimental diet pellets containing 0.12% red ginseng extract (approximately 200 mg/kg/d) for 3 mo. Young and old mice (4 mo and 21 mo old, respectively) were used as the control group. The effect of red ginseng, which ameliorated memory impairment in aged mice, was quantified using Y-maze test, novel objective test, and Morris water maze. Red ginseng ameliorated age-related declines in learning and memory in older mice. In addition, red ginseng's effect on the induction of inducible nitric oxide synthase and proinflammatory cytokines was investigated in the hippocampus of aged mice. Results: Red ginseng treatment suppressed the production of age-processed inducible nitric oxide synthase, cyclooxygenase-2, tumor necrosis factor-${\alpha}$, and interleukin-$1{\beta}$ expressions. Moreover, it was observed that red ginseng had an antioxidative effect on aged mice. The suppressed glutathione level in aged mice was restored with red ginseng treatment. The antioxidative-related enzymes Nrf2 and HO-1 were increased with red ginseng treatment. Conclusion: The results revealed that when red ginseng is administered over long periods, age-related decline of learning and memory is ameliorated through anti-inflammatory activity.

Si$_3$N$_4$/S. S316 접합에서 중간재가 접합강도 및 신회도에 미치는 영향 (Effect of Interlayer Materials on Bending Strength and Reliability of Si$_3$N$_4$/S. S316 Joint)

  • 윤호욱;박상환;최성민;임연수;정윤중
    • 한국세라믹학회지
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    • 제35권3호
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    • pp.219-230
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    • 1998
  • Various interlayer materials have been tested for active metal(Cusil ABA) brazing of Si3N4/S. S316 joint. In general multilayer joint had higher strength(80-150 MPa) and better reliability than monolayered one. The joint with Cu(0.2)/Mo(0.3)/Cu(0.2mm) interlayer showed the highest bending strength of abou 490 MPa and the joint with Cu(0.2)/Mo(0.3mm) interlayer the best reliability (14.6 Weibull modulus). The stresses distributed in joint materials during 4-point bending test were estimated by CAE von Mises analysis; the estimated stresses were In good agreement with the measured data. In multilayer joint Cu was though to reduce the residual stresses induced by the difference in thermal expansion coefficient between the ceramic Mo and metal It apperared that a Cu/Mo was optimum interlayer material for Si3N4/S. S316 joint with high bending strength (420 MPa) and reliability. In addition the various shapes and types of compound were examined by EPMA in joining interface.

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전기화학 커패시터 응용을 위한 용액기반의 2차원 소재 제조 (Solution-based Synthesis of Two-dimensional Materials for Electrochemical Capacitors)

  • 최봉길
    • 공업화학
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    • 제28권3호
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    • pp.272-278
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    • 2017
  • 2차원 소재인 그래핀과 이황화몰리브덴($MoS_2$)은 슈퍼커패시터 응용을 위한 많은 관심과 무한한 가능성을 보여주었다. 2차원 소재의 슈퍼커패시터 응용성을 높이기 위해서는 2차원 소재 제조를 위한 효율적이면서 친환경적인 저비용 합성법이 개발되어야 한다. 본 논문에서 우리는 최근 개발된 슈퍼커패시터용 용액기반 2차원 소재 제조 기술을 논하고자 한다. 화학적 박리-환원, 화학적 삽입, 액상 박리 기술법들을 소개하고자 한다. 또한 그래핀과 이황화몰리브덴의 전기화학적 특성들을 정리하였다. 용액기반 공정들과 함께 개선되어야 할 나노시트들의 조성, 크기 및 두께 조절 기술개발을 다룬다.

Extension of Shelf Life of Kimchi by Addition of Encapsulated Mustard Oil

  • Kim, Mi-Jeong;Ha, Jee-Yun;Yun, Ye-Rang;Noh, Jeong-Sook;Song, Yeong-Bok;Song, Yeong-Ok
    • Food Science and Biotechnology
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    • 제15권6호
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    • pp.884-888
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    • 2006
  • In this study, we have attempted to characterize the effects of encapsulated mustard oil with regard to the extension of the shelf life of kimchi. The quantity of mustard oil or encapsulated mustard oil added to the brined cabbage in this study was 0.05%(w/w). Overall, the fermentation processes in the encapsulated mustard oil-added kimchi (EMO) and mustard oil-added kimchi (MO) occurred at a slower rate than in the controls. The periods during which the MO and EMO kimchi samples were edible were prolonged for more than two weeks, according to measurements of pH, total acidity, and microbial changes. The overall acceptability of EMO was superior to MO throughout the entirety of the fermentation period. Sensory evaluation verified that EMO yielded a more favorable product than the MO and control varieties. Encapsulated mustard oil can be employed as a natural food additive to prolong the shelf life of kimchi, via an induced delay of the fermentation process.