• 제목/요약/키워드: Mo addition

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Ni-Cr-Mo-V 내열강의 마찰마모 특성 연구 (A Study on Tribological Characteristics for High Temperature Alloy Steel with Ni-Cr-Mo-V)

  • 임호기;배문기;김태규
    • 열처리공학회지
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    • 제29권6호
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    • pp.284-291
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    • 2016
  • High temperature alloy steel such as Ni-Cr-Mo-V material has excellent properties of high strength and high heating resistance. It has been used for several military weapon components such as gun barrel of a warship, turbine rotor and turbine disk for nuclear power plant. Being curious about this material required excellent wear resistance and durability in extreme environmental conditions. A dry wear test at the ambient air and Ar gas conditions in the room temperature were performed in this study. What's more a lubricant wear test at different temperature was conducted. In addition that DLC was coated on Ni-Cr-Mo-V alloy steel substrate with a thickness of $3{\mu}m$, a property of it was compare with lubricant conditions. All the coefficient of friction and wear volume, comparing with DLC coated specimens. The test parameters were selected as follows: 10 N for normal load; 80 rpm for sliding wear speed; and 300 m for the sliding wear distance.

오스테나이트계 내열 구상흑연주철의 고온 특성 (Elevated Temperature Properties of Austenitic Heat-resistant Ductile Irons)

  • 최경환;서정혁;김수황
    • 한국주조공학회지
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    • 제37권2호
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    • pp.31-37
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    • 2017
  • A new form of austenitic heat-resistant ductile iron was developed and its microstructures and elevated temperature properties were compared to those of Ductile Ni-Resist D5S. According to JMatPro calculations, it was predicted that Mo-rich carbides would be crystallized before the eutectic reaction starts in the developed alloy. At the austenite cell boundaries of the developed alloy, both Mo-rich carbides and Cr-rich carbides were found. In addition, Ni-silicides were found adjacent to Cr-rich carbides in D5S specimen and were identified as $Ni_2Si$. The developed alloy also had greater yield strength and lower tensile strength levels with less elongation due to the dissolution of Mo atoms into the austenite matrix and the precipitation of Mo-rich carbides. From the results of elevated temperature tensile tests and stress-rupture tests, it was found that the developed alloy had elevated temperature properties superior to those of D5S. This was due to the pinning effect of the dissolved Mo atoms in the austenite matrix.

In-Process합성에 의한 고기능 금속간화합물의 복합성형 (Complex Forming of the High-Functional Intermetallic Compound by the In Process Synthesis)

  • 한정현;박성갑;박용호
    • 한국분말재료학회지
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    • 제13권6호
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    • pp.408-414
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    • 2006
  • [ $MoSi_2$ ] alloys with Al, B or Nb were prepared by an advanced consolidation process that combined mechanical alloying with pulse discharge sintering (complex forming) to improve the mechanical properties. Their microstructure and mechanical properties were investigated. The $MoSi_2$ alloys fabricated by complex forming method showed very fine microstructure when compared with the sample sintered from commercial $MoSi_2$ powders. Alloys made from powders milled in Ar gas had fewer silica or alumina phases as compared to their counterparts sintered from powders milled in air. In densification of the sintered body, addition of B was more effective than Al or Nb. Both Victors hardness and tensile test indicated that the alloy fabricated by the complex forming method showed better properties than the sample sintered from commercial $MoSi_2$ powders. The Al added alloy sintered from the powders milled in air had the superior mechanical properties due to the suppression of $SiO_2$ and formation of fine $Al_2O_3$ particles.

Fe-(Mo-Mn-P)-xSi계 합금의 성형밀도에 따른 소결거동 (Sintering behavior of Fe-(Mo-Mn-P)-xSi alloys according to the Green Density)

  • 정우영;옥진욱;박동규;안인섭
    • 한국분말재료학회지
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    • 제24권5호
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    • pp.400-405
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    • 2017
  • The addition of a large amount of alloying elements reduces the compactibility and increases the compacting pressure, thereby shortening the life of the compacting die and increasing the process cost of commercial PM steel. In this study, the characteristic changes of Fe-Mo-P, Fe-Mn-P, and Fe-Mo-Mn-P alloys are investigated according to the Si contents to replace the expensive elements, such as Ni. All compacts with different Si contents are fabricated with the same green densities of 7.0 and $7.2g/cm^3$. The transverse rupture strength (TRS) and sintered density are measured using the specimens obtained through the sintering process. The sintered density tends to decrease, whereas the TRS increases as the Si content increases. The TRS of the sintered specimen compacted with $7.2g/cm^3$ is twice as high as that compacted with $7.0g/cm^3$.

An Architecture Supporting Adaptation and Evolution in Fourth Generation Mobile Communication Systems

  • Prehofer, Christian;Kellerer, Wolfgang;Hirschfeld, Robert;Berndt, Hendrik;Kawamura, Katsuya
    • Journal of Communications and Networks
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    • 제4권4호
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    • pp.336-343
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    • 2002
  • A major challenge for next generation mobile communication is capturing the system architecture’s complexity with all its internal and external dependencies. Seamless integration of heterogeneous environments in all system parts is a key requirement. Moreover, future systems have to consider the different evolution cycles of individual system parts. Among those, services are expected to change the fastest. With respect to these considerations, we propose an overall architecture for next generation mobile communication systems. It covers all system parts from wireless transmission to applications including network and middleware platform. Our approach focuses on adaptability in terms of recon- figurability and programmability to support unanticipated system evolution. Therefore, we consider abstraction layers which consist of adaptable cooperating components grouped by open platforms rather than rigid system layers. In addition to that, we introduce cross-layer cooperation allowing an efficient use of the available resources. Specific scenarios illustrate the feasibility of our approach.

Mo:Na 두께에 따른 Cu(In,Ga)Se2 박막의 물성과 효율변화 (The Physical Properties and Efficiencies of Cu(In,Ga)Se2 Thin Films Depending on the Mo:Na Thickness)

  • 신윤학;김명한
    • 한국재료학회지
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    • 제24권3호
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    • pp.123-128
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    • 2014
  • To realize high-performance thin film solar cells, we prepared CIGS by the co-evaporation technique on both sodalime and Corning glass substrates. The structural and efficient properties were investigated by varying the thickness of the Mo:Na layer, where the total thickness of the back contact was fixed at 1${\mu}m$. As a result, when the Mo:Na thickness was 300 nm on soda-lime glass, the measured Na content was 0.28 %, the surface morphology was a plate-like compact structure, and the crystallinity by XRD showed a strong peak of (112) preferential orientation together with relatively intense (220) and (204) peaks as the secondary phases influenced crystal formation. In addition, the substrates on soda-lime glass effected the lowest surface roughness of 2.76 nm and the highest carrier density and short circuit current. Through the optimization of the Mo:Na layer, a solar conversion efficiency of 11.34% was achieved. When using the Corning glass, a rather low conversion efficiency of 9.59% was obtained. To determine the effects of the concentration of sodium and in order to develop a highefficiency solar cells, a very small amount of sodium was added to the soda lime glass substrate.

초고속화염용사법으로 제조된 Ni-Cr-W-Mo-B 합금 코팅의 미세조직과 특성에 미치는 열처리 효과 (Effect of Heat Treatment on the Microstructures and Properties of HVOF Sprayed Ni-Cr-W-Mo-B Alloy Coatings)

  • 민경오;이창희
    • Journal of Welding and Joining
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    • 제18권6호
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    • pp.48-54
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    • 2000
  • The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

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쥐의 치수자극에 의해 유발되는 자율신경 반응과 악안면 근육활동의 변화 (CHANGES IN AUTONOMIC RESPONSES AND JAW MUSCLE ACTIVITY INDUCED BY TOOTH PULP STIMULATION IN THE RAT)

  • 유미경;박수정
    • Restorative Dentistry and Endodontics
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    • 제24권4호
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    • pp.657-665
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    • 1999
  • The effects of application of mustard oil (MO), a small-fiber excitant and inflammatory irritant into the rat maxillary molar tooth pulp on arterial blood pressure and heat race, and electromyographic (EMG) activity of the jaw muscles were assessed in the anesthetized rats. In addition, Evans blue extravasation following pulpal MO application was measured. Application of MO into the tooth pulp produced a significant increase in mean arterial pressure and heat rate which gradually returned to baseline level. Application of MO into the tooth pulp induced a significant and short-lasting increase in EMG activity of digastric masseter and tongue muscle. Application of MO into the tooth pulp significantly increased the plasma extravasation of Evans blue dye. However, Application of mineral oil into the tooth pulp did not produce any significant changes in EMG activity of the digastric, masseter and tongue muscles, mean arterial pressure and heart rate, and plasma extravasation of Evans blue dye. These findings indicate that changes in arterial blood pressure, heart rate, jaw muscle activity and plasma extravasation accompanying noxious tooth pulp stimulation call be utilized as indirect measure of orofacial pain and inflammation.

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Spectroscopic Studies on ZrO2 Modified with MoO3 and Activity for Acid Catalysis

  • Sohn, Jong-Rack;Chun, Eun-Woo;Pae, Young-Il
    • Bulletin of the Korean Chemical Society
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    • 제24권12호
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    • pp.1785-1792
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    • 2003
  • Zirconia modified with $MoO_3$ was prepared by impregnation of powdered $Zr(OH)_4$ with ammonium heptamolybdate aqueous solution followed by calcining in air at high temperature. Spectroscopic studies on prepared catalysts were performed by using FTIR, Raman, XRD, and DSC and by measuring surface area. Upon the addition of molybdenum oxide to zirconia up to 15 wt%, the specific surface area increased in proportion to the molybdate oxide content, while acidity measured by irreversible chemisorption of ammonia exhibited a maximum value at 3 wt% of $MoO_3$. Since the $ZrO_2$ stabilizes the molybdenum oxide species, for the samples equal to or less than 30 wt%, molybdenum oxide was well dispersed on the surface of zirconia and no phase of crystalline $MoO_3$ was observed at any calcination temperature above $400^{\circ}C$. The catalytic activities for cumene dealkylation were roughly correlated with the acidity of catalysts measured by ammonia chemisorption method, while the catalytic activities for 2-propanol dehydration were not correlated with the acidity because weak acid sites are necessary for the reaction.

전기방사방법에 의해 합성된 ZnO 중공 나노섬유의 trimethylamine 가스 감응 특성 (Trimethylamine Sensing Characteristics of Molybdenum doped ZnO Hollow Nanofibers Prepared by Electrospinning)

  • 김보영;윤지욱;이철순;박준식;이종흔
    • 센서학회지
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    • 제24권6호
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    • pp.419-422
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    • 2015
  • Pure and Mo-doped ZnO hollow nanofibers were prepared by single capillary electrospinning and their gas sensing characteristics toward 5 ppm ethanol, trimethylamine (TMA), CO and $H_2$ were investigated. The gas responses and responding kinetics were dependent upon sensing temperature and Mo doping. Mo-doped ZnO hollow nanofibers showed high response to 5 ppm TMA ($R_a/R_g=111.7$, $R_a$: resistance in air, $R_g$: resistance in gas) at $400^{\circ}C$, while the responses of pure ZnO hollow nanofibers was low ($R_a/R_g=47.1$). In addition, the doping of Mo enhanced selectivity toward TMA. The enhancement of gas response and selectivity to TMA by Mo doping to ZnO nanofibers was discussed in relation to the interaction between basic analyte gas and acidic additive materials.