• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.100-101
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• 2004

Many researches in Korea have been performed to understand the pollution of stream waters by acid mine drainage. However, few studies have been conducted regarding the effect of particulate and colloidal fractions on the transport of trace metals. To estimate harmful effects of trace metals, it is important to evaluate the particulate and colloidal metals as well as dissolved metals, because particulate and colloidal fractions of trace metals play an important role in transport of trace metals and may adversely affect habitats and organisms in riverine system. Colloids are solids with effective diameters in size range from 0.001 $\mu$m to 1 $\mu$m. According to Jone et al. (1974), metals in surface water, like Al, Fe, and Mn, require filtration with pore-size membranes smaller than 0.45 $\mu$m to define dissolved concentrations. The main objective of this study is to understand the effects of particulate, colloidal, and truly dissolved fractions on the transport and fate of trace metals in acid mine drainage. This study was conducted for the Onjeong creek in the Uljin mine area. Sampling was carried out in 13 sites, spatially covering the area from mine dumps to the downstream Onjeong reservoir. To examine the metal partitioning between particulate, colloidal, and truly dissolved fraction, we used successive filtration techniques consisting of conventional method (using 0.45 $\mu$m membranes) and tangential-flow ultrafiltration (using 0.001 $\mu$mm membranes). Ultrafiltration may seperate much smaller particles from aqueous phase (Josephson, 1984; Hernandez and Stallard, 1988). The analysis of metals were performed by inductively coupled plasma - atomic emission spectrometer (ICP-AES: model Perkin Elmer OPTIMA3000XL). Anions such as SO$_4$, Cl and NO$_3$ were measured with ion chromatograph (IC: model Dionex 120). Sample analysis is still in progress. The preliminary data show that the studied creek is severely polluted by Al, Fe, Mn, Pb and Zn. Toward upstream sites with relatively lower pH, less than 50% of Al and Fe occur in the sorbed form on particles or colloids, whereas more than 80% of Al and Fe occur in the sorbed form in downstream sites or tributaries with relatively higher pH. Less than 30% of Zn is present in particle or colloidal forms in the whole range of creek. Truly dissolved fraction of trace metals is negatively correlated with pH. The Kd values for Al, Fe and Zn consistently increase with increasing pH and decrease with increasing particle concentration.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.651-656
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• 2005

Toluene, which is emitted from textile process, is considered as an important hazardous air pollutant. In this study, the catalytic activity of transition metal oxides(Cu, Mn, V, Cr, Co, Ni, Ce, Sn, Fe, Sr, Cs, Mo, La, W, Zn)/${\gamma}-Al_2O_3$ catalysts was investigated to carry out the complete oxidation of toluene. The metal catalysts were characterized by XRD-ray diffraction), FE-SEM(Field Emission Scanning Electron Micrograph), BET(Brunauer Emmett Teller) method and TPR(Temperature Programmed Reduction). Among the catalysts, Cu/${\gamma}-Al_2O_3$ was highly promising catalyst for the oxidation of toluene. From the BET results, it seems that the catalytic activity is not correlated to the specific surface area. XRD results indicated that most of catalysts exist as amorphous phase. From the FE-SEM results, it was observed that copper on ${\gamma}-Al_2O_3$ surface was well dispersed among catalysts. The catalytic activity for the toluene oxidation could be explained with that metal oxide catalyst was dispersed well over supports and was attributed to reduction activity in surface of catalysts.

• The Journal of the Petrological Society of Korea
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• v.23 no.2
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• pp.31-43
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• 2014

The Yeongdeok granite emplaced in the eastern Yeongyang subbasin is typically a medium- to coarse-grained massive biotite granite. It intruded into Precambrian schist & gneiss complex and is unconformably overlain by Cretaceous sedimentary rocks. In this study, we attempt to investigate the magma type which formed Yeongdeok granite and estimate the emplacement depth using Al-in-hornblende geobarometer to mineral composition. According to the magma fractionation, $TiO_2$, $Al_2O_3$, $Fe_2O_3{^*}$, FeO, $Fe_2O_3$, MnO, MgO, CaO, $Na_2O$ and $P_2O_5$ show positive trend but $K_2O$ indicate negative trend with $SiO_2$ contents. Those are identified as calc-alkaline series in AFM diagram and show the chemical characteristics of the I-type magma through the oxidation tendency of the iron ion and the portion of the alkaline composition. When calculated using the equation of Hollister et al. (1987), the emplacement depths of the Yeongdeok granite range from 8.98 to 17.19 km and average depth was estimated 13.03 km approximately.

• Journal of Korean Society of Forest Science
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• v.89 no.3
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• pp.422-430
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• 2000

Three-year-old Pinus koraiensis seedlings, transplanted in brown forest soils originating from granite were treated with simulated acid rain of pH concentrations 5.6(control), 4.0, 3.0, 2.5 and 2.0 for 210 days from April 21 to November 17, 1999. Visible injury of the seedlings were observed at the pH 2.0 and pH 2.5 treatments. The total dry weight of the seedlings decreased at pH 2.0 treatment compared with that of the control, and T/R ratio increased at pH 2.0 treatment compared with others. The elements in each part of the seedlings, concentrations of Ca, P and content of chlorophyll in needles increased at the pH 2.0 treatment compared with the control. The concentration of N in the needles of the seedlings increased as the soil pH decreased. As the treated pH was lowered, soil pH has decreased, and concentrations of Ca, Mg, Al, and Mn increased, especially at pH 4.4. In addition, there was a strong correlation(r=0.90, p<0.05 ; r=-0.94, p<0.01) between the dry weight of the seedlings and the pH and Al concentration of the soils. Therefore, the pH and Al concentration in the soil may be useful indicator for assessing the effect of acid rain on the growth of woody plants.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.367-376
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• 2007

Aenigmatite, $Na_4(Fe^{2+},Ti,Fe^{3+}){_{12}}(Fe^{3+},Si){_{12}}O_{40}$, is a common constituent of sodium-rich alkaline igneous rocks and is classified a an open-branched single-chain silicate. $M\ddot{o}ssbauer$ spectroscopy of three natural aenigmatite specimens were done and the detailed crystal chemistry was obtained. Fitting of $M\ddot{o}ssbauer$ spectra led to the resolution of nine peaks. They consist of three doublets of $Fe^{2+}/oct$ and one merged peak at low velocity matching to two small peaks at high velocity which were assigned to $Fe^{3+}/tet\;and\;Fe^{2+}/oct$, respectively. Using the peak area for $Fe^{2+}\;and\;Fe^{3+}$ peaks, analytical data were recalculated. Precise assignment of $Fe^{2+}\;and\;Fe^{3+}$ ions in tetrahderal and octahedral sites revealed detailed crystal chemistry of aenigmatite. The existence of significant amounts of $Fe^{3+}/tet$ indicates that $Fe^{3+}$ has preference over $Al^{3+}$ for the tetrahedral sites. Crystal chemistry of aenigmatite (AEN1) yields the formula of $(Na_{3.97}Ca_{0.03})(Ca_{0.11}Mn_{0.59}Fe^{2+}{_{8.07}}Ti_{2.07}Mg_{0.70}Fe^{3+}{_{0.43}}Al_{0.04})(Fe^{3+}{_{0.56}}Al_{0.18}Si_{11.26})O_{40}$.

• Analytical Science and Technology
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• v.21 no.4
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• pp.332-337
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• 2008

Purification of silica mineral was compared with various leaching methods such as shaking, stirring, ultrasonic with 2.5% HF/HCl solution. Among them, ultrasonic method showed a best leaching effect. From the leaching experiment, Na, K, Fe, Al exist as the major impurity elements. The removal rate of Al, Fe showed little difference with various leaching methods but Ca, Mn, Na were very different. Four kinds of silica mineral (>99% purity) after physical purification treatment were used for ultrasonic leaching experiment. Among them IN-Si had a highest impurity removal rate. Ca, Cr, K, Zn were removed above 80% using ultrasonic leaching method and Fe was also removed above 60%. But Al showed 10~60% removal rate with different samples.

• Corrosion Science and Technology
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• v.6 no.4
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• pp.193-197
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• 2007

It is well known that the development of Advanced High Strength Steels (AHSS) is very important for the automotive industry in order to improve fuel efficiency and the reduction of material costs. However, it is particularly difficult to improve the surface quality of AHSS because the high amount of Si, Al, Mn and Ti etc. in AHSS promote selective oxidation, resulting in surface defects. The reheating process in the hot strip mill would cause severe oxidation because it is carried out at elevated temperatures under aggressive environments. In this study a reheating furnace simulator was developed to investigate oxidation phenomena in the reheating process. The environmental gas for the reheating furnace was made by burning coke oven gas with air in the simulator. The air/fuel ratio is precisely controlled by MFC. Ti oxides are easily formed on grain boundaries and Mn and Si oxides are usually formed in inner grains near the steel surface with a small round shape.

• Applied Biological Chemistry
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• v.1
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• pp.37-40
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• 1960

(1) Inorganic paper chromatography를 삼근회분(蔘根灰分)의 계통분석(系統分析)에 응용(應用)했으며 소량(少量)의 회분(灰分)으로 일제분석(一齊分析)이 가능(可能)하였다. (2) 계통분석(系統分析)에는 6족법(族法)으로 하였으며, Hg, Pb, Cd, Cu, As, Sb, Al, Fe, Co, Mn, Zn, Ca, Na, K 등의 양(陽) ion이 삼근회분중(蔘根灰分中)에서 검출(檢出)되었다. ($Ba^{++}$는 시험불구득(試驗不求得)으로 불실시(不實施)) (3) 삼근회분(蔘根灰分)의 양(陽) ion중(中) Co, Zn, Mn 등은 그들의 식물영양학적(植物榮養學的) 면(面)에서 관심사(關心事)가 될 것이다. (귀금속(貴金屬)과 음(陰) ion에 대(對)해서는 차후(次後) 계속예정(繼續豫定)임)

• Transactions of the Korean hydrogen and new energy society
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• v.8 no.1
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• pp.31-41
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• 1997

In order to investigate the mechanism of electrochemical hydrogenation reaction on Zr-based Laves phase hydrogen storage alloy electrodes, electrochemical charge/discharge characteristics, potentiostatic/dynamic polarizations and electrocehmical impedance spectroscopy(EIS) of Zr-Ti-Mn-Ni and Zr-Ti-Mn-Ni-M(M=Fe, Co, Al) alloys were examined. Electrochemical discharge capacities of the alloys were quite different with gas charge capacities. Therefore, it was considered that discharge capacities of the alloys depend on electrochemical kinetic factors rather then thermodynamic ones. Discharge efficiencies were increased linearly with exchange current densities. The results of potentiostatic/dynamic polarization measurements showed that electrochemical charge and discharge reaction of Zr-based Laves phase hydrogen storage alloys is controlled by charge transfer process at the electrode surface. The EIS measurements also confirmed this result.

• Journal of the Korean Mathematical Society
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• v.42 no.4
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• pp.871-881
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• 2005

In 1977, Ganter and Teirlinck proved that any $2t\;\times\;2t$ matrix with 2t nonzero elements can be partitioned into four sub-matrices of order t of which at most two contain nonzero elements. In 1978, Kramer and Mesner conjectured that any $mt{\times}nt$ matrix with kt nonzero elements can be partitioned into mn submatrices of order t of which at most k contain nonzero elements. In 1995, Brualdi et al. showed that this conjecture is true if $m = 2,\;k\;\leq\;3\;or\;k\geq\;mn-2$. They also found a counterexample of this conjecture when m = 4, n = 4, k = 6 and t = 2. When t = 2, we show that this conjecture is true if $k{\leq}5$.