• Title/Summary/Keyword: Mn-Al

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Metals in Coastal Sediments Adjacent to the Youngkwang Nuclear Power Plant, West Coast of Korea

  • Cho, Yeong-Gil;Yang, Sung-Ryull;Park, kyung-Yang
    • Journal of the korean society of oceanography
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    • v.32 no.3
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    • pp.112-119
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    • 1997
  • Coastal sediments collected near the Youngkwang Nuclear Power Plant were analysed for major(Al$_2$O$^_3$, Fe$^_2$O$^_3$, MgO, CaO, Na$^_2$O, K$^_2$O, TiO$^_2$, MnO), trace (Ba, Sr, V, Co, Cr, Cu, Ni, Zn, Pb) metal, and P$^_2$O$^_5$ contents. The composition of bulk metals from most stations fits within the range as those in the average crustal and sedimentary rocks, suggesting that the anthropogenic perturbation of these components is insignificant. The abundance and distribution of total contents for the majority of metals in the surface sediment could be explained by the grain size and were associated with mud (<63 ${\mu}$m) contents. However, distributions of Ca, K, Sr and Ba did not have any significant association with the sediment grain size. This may be due to the geochemical coherence among these metals in certain minerals abundant in coarse grained fractions. The distribution of Pb appears to be partly affected by the contribution from aerosol fallout. Using the R'-mode factor analysis, we show that the variance of the metal contents could be explained by four factors which account for 93.7% of the total variance. It appears that texturally controlled and/or sorting factors influenced by fine fraction are the most dominant factors which determine the relative abundance and distribution of metals in the study area.

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Algae removal by Loess and coagulant (황토와 응집제에 의한 조류 제거)

  • 양상용;구연봉;최지혁;이인선;신찬기;유재근
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.127-130
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    • 1997
  • The removal of algae was conducted by loess, aluminum sulfate and PAC on a laboratory scale. The loess was consists of organic matter 1.4%, T-N $289{\mu}g/g$, T-P $17{\mu}g/g$, $Al841.2{\mu} g/g$, Fe $592.7{\mu}g/g$, Ca $10.6{\mu}g/g$, Mg $85.5{\mu}g/g$ and Mn $6.6{\mu}g/g$. Test water was dominated by Microcystis aeruginosa. When test water was mixed with 0.01, 0.05. and 0.1 g/$\ell$ of the loess in 5 minutes, after settled in 1 hour, the removal of chl-a was 2, 22, and 36% respectively. The removal of chl-a was 69%, 70% in pH 4.5 and 9.0 and above 92% between pH 5.0 and 8.0 after the $2mg/{\ell}$ of aluminum sulfate was added. When the $2mg/{\ell}$ of PAC and $0.05g/{\ell}$ of loess were added to test water together, the removal of chl-a was 95-99% in pH 4.0-8.0, 60% in pH 9.0, and 18% in pH 10.0. The removal of chl-a was higher when loess, aluminum sulfate and PAC was used together than used alone.

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A Study on the Potable Water Purification System with Pre-Ozone and Ultra Filtration Membrane of Hollow Fiber Type (전오존과 중공사형 한외여과막을 이용한 간이정수처리시스템에 관한 연구)

  • Kim, Min-Kuk;Chun, Yang-Kun
    • Journal of Korean Society on Water Environment
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    • v.21 no.2
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    • pp.196-204
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    • 2005
  • The objective of this study is to evaluate the possibility to apply pre-ozone and membrane system for drinking water. This system is improved in fouling control by pre-ozone system. It is composed of ultrafiltration hollow fiber type membrane and ozone reactor. The result of this study is that the flux is increased about 10.7% and decreased in TMP by the pre-ozone. Also, backwashing pressure decreased about 18%. The optimum concentration of residual ozone is 0.3~0.5 ppm. During the period, the recovery ratio of this system was turned out to be 90% as the flowrate of effluent is $67.1m^3/day$. When the TMP and backwashing pressure was $0.85kg/cm^2$ and $1.10kg/cm^2$, this system was stable without sudden fouling. Finally, the quality of effluent is satisfied the guidelines for potable water quality such as turbidity, color, E.coli, Mn, Al, Fe and so on.

Synthesis and Characterization of a Ceria Based Composite Electrolyte for Solid Oxide Fuel Cells by an Ultrasonic Spray Pyrolysis Process (초음파분무 열분해법을 이용한 고체산화물 연료전지용 세리아계 복합체 전해질의 제조 및 특성)

  • Lee, Young-In;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.222-228
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    • 2014
  • Much research into fuel cells operating at a temperature below $800^{\circ}C$. is being performed. There are significant efforts to replace the yttria-stabilized zirconia electrolyte with a doped ceria electrolyte that has high ionic conductivity even at a lower temperature. Even if the doped ceria electrolyte has high ionic conductivity, it also shows high electronic conductivity in a reducing environment, therefore, when used as a solid electrolyte of a fuel cell, the powergeneration efficiency and mechanical properties of the fuel cell may be degraded. In this study, gadolinium-doped ceria nanopowder with $Al_2O_3$ and $Mn_2O_3$ as a reinforcing and electron trapping agents were synthesized by ultrasonic pyrolysis process. After firing, their microstructure and mechanical and electrical properties were investigated and compared with those of pure gadolinium-doped ceria specimen.

Heavy and Trace Metal Analysis of River Otter (Lutra lutra) Spraints from the Geoje Island (우리나라 거제지역에 서식하는 수달의 식이물 중금속 및 미량원소 분석에 대한 연구)

  • Cho Heesun;Lee Sang-Don
    • Korean Journal of Environmental Biology
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    • v.23 no.3 s.59
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    • pp.315-321
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    • 2005
  • The population of river otter (Lutra lutra) has been declined most of the world due to hunting, habitat destruction and indirect or direct influences of eutrophication, acidification and toxic chemicals. This study is conducted to identify the population decline of river otter in Korea with relation to environmental pollution caused by accumulation of heavy and flared metals. The field survey was conducted during Jan~Dec, 2004 at a monthly basis by collecting spraints. A total of 228 spraints were collected and analysis was done by ICP-AES. The concentrations of fourteen metals (Cr, Zn, Cd, Pb, Ni, Fe, Co, Mn, Mg, Cu, Al, Ba Hg, As) have been determined. Annual concentrations of Cd $(1.38{\mu}g\;g^{-1}),\;Zn\;(599.06\;{\mu}g\;g^{-1}),\;Pb\;(5.54\;{\mu}g\;g^{-1})$ at Gucheon were higher than those of Yeonchocheon. Concentrations of $Cr\;(5.01{\mu}g\;g^{-1}),\;Ni\;(1.91{\mu}g\;g^{-1}),\;Co\;(0.25{\mu}g\;g^{-1})$ were higher at Yeonchocheon. Most metals in winter were significantly increased (P<0.05) as season progressed from spring to winter. $Pb\;(15.58{\mu}g\;g^{-1}),\;Cu\;(15.15{\mu}g\;g^{-1}),\;a;Guchoen\;and\;Cr\;(5.77{\mu}g\;g^{-1})$ at Yeonchocheon were high in the downstream of winter.

Mineral Contents of Edible Seaweeds Collected from Gijang and Wando in Korea (기장산과 완도산 식용해조류 중의 미네랄 함량)

  • Im, Yung-Geun;Choi, Jin-Seok;Kim, Dong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.1
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    • pp.16-22
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    • 2006
  • Mineral and heavy metal contents were determined in three brown edible seaweeds (sea mustard, Undaria pinnatifida; seaweed fusiforme, Hizikia fusiforme; sea tangle, Laminaria japonica) collected from Gijang and Wando in Korea, and two green seaweeds (sea lettuce, Enteromorpha prolifera; green laver, Monostroma nitidum) collected from Gijang. Seaweeds contained high proportions of ash (13.8-24.8%) and sulfate (1.08-3.25%). In brown seaweeds, ash contents (24.5-24.8%) were higher than in green seaweeds (13.8-15.2%). The differences of mineral contents were remarkable in both Gijang and Wando and in 5 various kinds of seaweeds. Brown seaweeds contained higher amounts of both macro-minerals (657-13,947 mg/100 g; Ca, Mg, Na, K) and trace elements (0.27-12.98 mg/100 g; Fe, Al, Zn, Mn, Cr, Cu, Ni), and green seaweeds also had relatively higher amounts of both macro-minerals (233-5,279 mg/100 g) and trace elements (0.26-10.61 mg/100 g).

Studies on Adenosine Triphosphate - Creatine Phosphotransferase from Muscle of the Snake Bungarus fasciatus (뱀 근육(筋肉) Adenosine Triphosphate - Creatine Phosphotransferase에 관(關)한 연구(硏究))

  • Park, Chung-Ung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.9 no.1
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    • pp.59-73
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    • 1980
  • A detailed procedure was described for the isolation of cratine kinase (ATP-Creatine phosphotransferase, E. C. 2. 7. 3. 2.) from the muscle of the snake Bungarus fasciatus. The original isolation procedure of Kuby et al. for the rabbit muscle enzyme has been modified and extended to include a chromatographic step. The properties of the enzyme have been investigated and kinetic constants for the reverse reactions determined as the followings: 1) A molecular weight of the enzyme was determined by gel filteration on Sephadex G-100 and by electrophoresis on SDS-polyacrylamide was 86,000. 2) Two reactive sulphydryl groups were detected with dithiobis nitrobenzoic acid (DTNB). 3) The nucleotide substrate specificity in the reverse reaction was determined as ADP*2'-dADP>GDP>XDP>UDP with magnesium as the activating metal ion. 4) The order of the metal specificity in the reverse reaction Mg>Mn>$Ca{\sim}Co$ was determined with ADP as substrate. 5) A detailed kinetic analysis was carried out in the reverse direction with $MaADP^-$ as the nucleotide substrate. Initial velocity and product inhibition studies($MaADP^{2-}$ competitive with respect to MgADP- and noncompetitive with respect to $N-phosphorycreatine^{2-}$ ; Creatine competitive with respect to $N-phosphorycreatine^{2-}$ and noncompetitive with respect to Ma $ADP^-)$ indicated that the reaction obeyed a sequential mechanism of the rapid equilibrium random type.

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Effects of Alloying Element and Grain Refinement on the Tensile Properties of Mg-Alloy Casted with Sand Mold (사형 주조 마그네슘 합금의 인장 특성에 미치는 합금 원소와 결정립 미세화의 영향)

  • Han, Jae-Jun;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.31 no.4
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    • pp.212-217
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    • 2011
  • The effects of alloying element and grain refinement on the tensile properties of magnesium alloy poured into sand mold were investigated. The strength of magnesium alloy was greatly increased by the addition of aluminium and that was increased with the increased aluminum content added up to 8.10 wt% and decreased beyond that. Even though the strength of Mg-8.10 wt%Al alloy was rather decreased by the addition of zinc, that was increased with increased zinc content added up to 0.50 wt% and decreased with the increased one beyond that. The maximum tensile strength was obtained with 0.50 wt%Mn added. The strength and elongation were simultaneously increased with grain refinement and the optimum amount of strontium addition for this was 0.30 wt%. The optimum chemical composition was obtained and the yield strength, tensile strength and elongation of the alloy with this composition were 90.2, 176.3MPa and 4.43%, respectively.

Size Distribution of Ambient Aerosol Measured at a Coastal Site in Jeju Island (제주도 해안가에서 측정된 에어로졸의 성분별 입경분포 특성)

  • 이기호;양희준;허철구
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1043-1054
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    • 2003
  • During the period from April to September 2002, the size distributions of ambient aerosol were measured at the coastal site at Hamduk in Jeju Island. Na$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/and Cl$\^$-/ exhibited mostly a bimodal coarse mode size distribution, while ammonium and sulfate were mainly in the fine size range, with maximum at around 0.54$\mu\textrm{m}$. The average molar concentration ratio of ammonium to sulfate for fine particles was equal to 2.0${\pm}$0.9. Nitrate was evenly found in both the coarse and fine modes. Elements like Al, Fe, Cu, Mg, Na, Ti, Sr and Mn were dominant in coarse particles, with the maximum at around 5.25$\mu\textrm{m}$. S and Pb were mainly in the submicrometer size range. Other elements with a fine and coarse modes were V, Ni, Cu, Ba and Mo. The patterns of the size distributions of trace elements measured at the downtown in Jeju City were very similar to those at the coastal site in Hamduk. However, the amplitude of size fractional concentrations at Jeju City was narrower than that at Hamduk. While the mass median diameters for the chemical species originated from the natural origin such as marine and crust were relatively large, those for ammonium, sulfate, S and Pb were very small.

Preparation and Luminescene properties with invisible inoranic phosphors of nano size (나노크기의 비가시 무기형광체 제조와 발광특성)

  • Jeong, Jae-Hoon;Yun, Hyun;Jang, Gyu-Hwan;Shin, Sang-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.461-462
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    • 2008
  • $BaMgAl_{10}O_{17}$:Mn, $Eu^{2+}$ green phosphors has been synthesized by the solid state reaction. Green phosphors of nano-size were manufactured in short time by shake method. which were easily manufactured respectively general method. Green phosphors of nano size were control additive, size of $ZrO_3$ ball, shake time and weight of ball in toluene. In result that green phosphors were obtained particle size of 140nm~150nm. The characteristics of fired samples were obtained by 365nm and 380nm excitation source under ultraviolet. In result that the highest PL intensity were observed in wavelength of 365nm.

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