DOI QR코드

DOI QR Code

Size Distribution of Ambient Aerosol Measured at a Coastal Site in Jeju Island

제주도 해안가에서 측정된 에어로졸의 성분별 입경분포 특성

  • 이기호 (제주대학교 해양과학부 토목환경공학전공) ;
  • 양희준 (제주대학교 해양과학부 토목환경공학전공) ;
  • 허철구 (제주대학교 해양과학부 토목환경공학전공)
  • Published : 2003.10.01

Abstract

During the period from April to September 2002, the size distributions of ambient aerosol were measured at the coastal site at Hamduk in Jeju Island. Na$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/and Cl$\^$-/ exhibited mostly a bimodal coarse mode size distribution, while ammonium and sulfate were mainly in the fine size range, with maximum at around 0.54$\mu\textrm{m}$. The average molar concentration ratio of ammonium to sulfate for fine particles was equal to 2.0${\pm}$0.9. Nitrate was evenly found in both the coarse and fine modes. Elements like Al, Fe, Cu, Mg, Na, Ti, Sr and Mn were dominant in coarse particles, with the maximum at around 5.25$\mu\textrm{m}$. S and Pb were mainly in the submicrometer size range. Other elements with a fine and coarse modes were V, Ni, Cu, Ba and Mo. The patterns of the size distributions of trace elements measured at the downtown in Jeju City were very similar to those at the coastal site in Hamduk. However, the amplitude of size fractional concentrations at Jeju City was narrower than that at Hamduk. While the mass median diameters for the chemical species originated from the natural origin such as marine and crust were relatively large, those for ammonium, sulfate, S and Pb were very small.

Keywords

References

  1. Kramm, G. and R. Dlugi, 1994, Modelling the vertical fluxes of nitric acid, ammonia and ammonium nitrate, Journal of Atmospheric Chemistry, 18, 319-357 https://doi.org/10.1007/BF00712450
  2. Pryor, S. C. and R. J. Barthelmie, 2000, Particle dry deposition to water surface: Processes and Consequences, Marine Pollution Bulletin, 41 (1-6), 220-231 https://doi.org/10.1016/S0025-326X(00)00112-0
  3. Paerl, H. W, 1995, Coastal eutrophication In relation to atmospheric nitrogen deposition to oligotrophic oceans, Nature, 357, 397-399 https://doi.org/10.1038/357397a0
  4. Asman, W. A. H., O. Hertel, R. Berkowicz, J. Christensen, E. H. Runge, L. L. Sorensen, K. Granby, H. Nielsen and B. Jensen, 1995, Atmospheric nitrogen input to the Kattegat, Ophelia, 42, 5-28 https://doi.org/10.1080/00785326.1995.10431495
  5. Wu, Z. Y., M. Han, Z. C. Lin and J. M. Ondov, 1994, Chesapeake Bay atmospheric deposition study, Year 1: Sources and dry deposition of selected elements in aerosol particles, Atmospheric Environment, 28(8), 1471-1486 https://doi.org/10.1016/1352-2310(94)90208-9
  6. Migon, c., B. Journel and E. Nicolas, 1997, Measurement of trace metal wet, Dry and total atmospheric fluxes over the Ligurian Sea, Atmospheric Environment, 31(6), 889-896 https://doi.org/10.1016/S1352-2310(96)00242-7
  7. Injuk, J., R. V. Grieken, and G. Leeuw, 1998, Deposition of atmospheric trace elements into the North sea: coastal, ship, platform measurements and model predictions, Atmospheric Environment, 32, 3011-3025 https://doi.org/10.1016/S1352-2310(97)00497-4
  8. 양수미, 2002, 주성분 분석과 CMB를 이용한 제주시 대기 중 PM10 오염원 규명, 제주대학교 대학원 석사학위논문, 54pp
  9. 양희준, 2002, 제주연안에서의 입자상 물질의 건성침적플럭스의 추정에 관한 연구, 제주대학교 대학원 석사학위논문, 60pp
  10. Zhuang, H., C. K. Chan, M. Fang and A. S. Wexler, 1999, Size distributions of paticulate sulfate, nitrate, and ammonium at a coastal site in Hong Kong, Atmospheric Environment, 33, 843-853 https://doi.org/10.1016/S1352-2310(98)00305-7
  11. 김용표, 배귀남, 지준호, 진현철, 문길주, 1999, 제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구, 한국대기환경학회지, 15(5), 677-685
  12. Pakkanen, T. A., V. M. Kerminen, R. E. Hillamo, M. Makinen, T. Makela and A Virkkula, 1996, Distribution of nitrate over sea salt and soil derived particles implications from a field study, Journal of Atmospheric Chemistry, 24, 189-205 https://doi.org/10.1007/BF00162410
  13. Savoie, D. L. and J. M. Prospero, 1982, Particle size distribution of nitrate and sulfate in the marine atmosphere, Geophysical Research Letters, 9, 1207-1210 https://doi.org/10.1029/GL009i010p01207
  14. Wolff, G. T., M. S. Ruthkosky, D. R. Stroup, P. E. Korsog, M. A. Ferman, G. R. Wendel and D. H. Stedman, 1986, Measurement of SOx, NOx, and aerosol species on Bermuda, Atmospheric Environment, 20, 1229-1239 https://doi.org/10.1016/0004-6981(86)90158-7
  15. Maenhaut, W., J Cafmeyer, S. Dubtsov and X. Chi, 2002, Detailed mass size distributions of elements and species, and aerosol chemical mass closure during fall 1999 at Gent, Belgium, Nuclear Instruments and Methods in Physics Research, B189, 238-242
  16. Mukai, H., Y. Ambe and K. Shibata, 1990, Longterm variation of chemical composition of atmospheric aerosol on the Oki Islands in the Sea of Japan, Atmospheric Environment, 24A, 1379-1390
  17. Yi, S. M., U. Shahin, J Sivadechathep, S. C. Sofuoglu and T. M. Holsen, 2001, Overall element dry deposition velocities measured around Lake Michigan, Atmospheric Environment, 35, 1133-1140 https://doi.org/10.1016/S1352-2310(00)00242-9
  18. Dulac, F., P. Buat-Menard, E. Ullah, M. Sami and B. Gilles, 1989, Atmospheric input of trace metals to the western Mediterranean: Uncertainties in modelling dry deposition from cascade Impactor data, Tellus, 41B, 362-378 https://doi.org/10.1111/j.1600-0889.1989.tb00315.x
  19. Arimoto, R. and R. A. Duce, 1986, Dry deposition models and the air/sea exchange of trace elements, Journal of Geophysical Research, 91(D2), 2787-2792 https://doi.org/10.1029/JD091iD02p02787

Cited by

  1. Mass Size Distribution of Atmospheric Aerosol Particles with Nanosampler Cascade Impactor in Jinju City vol.24, pp.5, 2015, https://doi.org/10.5322/JESI.2015.24.5.679
  2. Characteristics of Size Distribution and Fugitive Emissions of Particulate Matter in Foundries vol.26, pp.1, 2016, https://doi.org/10.15269/JKSOEH.2016.26.1.30