• Title/Summary/Keyword: Mixture layer

Search Result 764, Processing Time 0.031 seconds

HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate (고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층)

  • Nam, Dae-Geun
    • New & Renewable Energy
    • /
    • v.4 no.1
    • /
    • pp.31-36
    • /
    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

  • PDF

Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.1-5
    • /
    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

  • PDF

A Study on the Manufacturing of Porous Membrane for Separation of Gas Mixture by Al Anodizing Method (Al장극산화법에 의한 반휴분이용 다공성 격영의 제조에 관한 연구)

  • 윤은열;라경용
    • Journal of Surface Science and Engineering
    • /
    • v.15 no.2
    • /
    • pp.69-76
    • /
    • 1982
  • With a view to manufacturing membranes for separation of gas mixtures, Al foils were anodized in a 2% oxalic-acid electrolyte at 40V and 80V. When anodizing was completed and Barrier layer existed at the extreme back site of the foil, the anodized foil was made to react with only electrolyte, with switching off the electric power. When the size and density of pores were changed through voltage change, the membr-anes did not show large difference in the permeability. Reacting with electrolyte, the existing Barrier layer turns into porous layer. During this process, several small pores grow from one relatively large pore, getting to the back site. The number and size of the small pores getting to the back surface increase as time passing. This change of Barrier layer into porous layer is thought to be directly related to the permeability change of the membranes. The selectivity of an anodized Al membrane was not related to the voltage change, and was high, being similar to the theoretical selctivity of metallic membranes, according to my observation.

  • PDF

Characterization of the Barrier Layers Comprised of Inorganic Compound for Organic Light Emitting Device Applications

  • Kim, Na-Rae;Lee, Yang-Doo;Kim, Jai-Kyeong;Hwang, Sung-Woo;Ju, Byeong-Kwon
    • Journal of Information Display
    • /
    • v.7 no.3
    • /
    • pp.13-18
    • /
    • 2006
  • Currently, the flexible organic light emitting devices (OLEDs) are investigated. They are very vulnerable to moisture, and thus have been found to show some problems. Thus, an effective barrier layer is needed to protect from moisture in air. We deposited thin films with magnesium oxide (MgO) and silicon oxide $(SiO_{2})$ compounds mixed at various mixture ratios on flexible polyether sulfone (PES) substrates by an electron-beam evaporator to investigate their applizability for transparent barrier applications. In this study, we found that as the MgO fraction increased, thin films comprised of MgO and $(SiO_{2})$ compounds became more amorphous and their surface morphologies become smoother and denser. In addition, zirconium oxide $(ZrO_{2})$ was added to the above-mentioned compound mixtures. $ZrO_{2}$ made thin mixture films more amorphous and made the surface morphology denser and more uniform. The water vapor transmission rates (WVTRs) of the whole films decreased rapidly. The best WVTR was obtained by depositing thin films of Mg-Si-Zr-O compound among the whole thin films. As the thin mixture films became more amorphous, and the surface morphology become denser and more uniform, the WVTRs decreased. Therefore, the thin mixture films became more suitable for flexible OLED applications as transparent passivation layers against moisture in air.

Growth Characteristics of Kentucky Bluegrass on Different Rootzone Foundations (지반 유형에 따른 켄터키 블루그래스의 생육특성)

  • 이혜원;정대영;심상렬
    • Journal of the Korean Institute of Landscape Architecture
    • /
    • v.31 no.6
    • /
    • pp.95-103
    • /
    • 2004
  • A turfgrass rootzone foundation is one of the important iufluences on the growth of cool-season turfgrass such as Kentucky bluegrass, which is usually grown on korean golf courses and athletic fields in Korea. This study was carried out to evaluate the growth of Kentucky bluegrass on 4 types of turfgrass root-zone foundations: a 2cm thickness of Sand 90%+Peat humus 8%+Zeolite 2% mixture on a subsoil base (C), a 20cm thickness of Sand 90%+Peat humus 8%+Zeolite 2% mixture (S), a 20cm thickness of Sand 45%+fine sand(a sort of Bomyungsa) 45%+Peat humus 8%+Zeolite 2% mixture (S+F), and a 20cm thickness of Sand 45%+fine sand(a sort of Bomyungsa) 45%+Peat humus 8%+Zeolite 2% mixture on a 20cm thick drainage layer (S+F(G)). Visual ratings of Kentucky bluegrass on the C foundation were low throughout the experiment when compared to S, S+F, and S+F(G) foundations, which contained high contents of sand with a high water infiltration rate. However, poor growth of Kentucky bluegrass in the summer of 1991 on the S foundation was likely to be caused by a too high water infiltration rate (185.8cm/hr). The growth of Kentucky bluegrass on the S+F(G) was good while the growth was a little weak at the developing stage on the S +F foundation. If the cost had to be considered when constructing golf courses and athletic fields, The S+F foundation without the drainage layer would be the best choice in terms of low cost and good quality of Kentucky bluegrass compared to the S+F(G). In this result, the infiltration rate was regarded as the most influential factor to the growth of Kentucky bluegrass on rootzone foundations.

The Characteristics of Compound Layers Formed during Plasma Nitrocarburising in Pure Iron (플라즈마 침질탄화처리된 순철의 화합물층 특성)

  • Cho, H.S.;Lee, S.Y.;Bell, T.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.13 no.3
    • /
    • pp.143-150
    • /
    • 2000
  • Ferritic plasma nitrocarburising was performed on pure iron using a modified DC plasma unit. This investigation was carried out with various gas compositions which consisted of nitrogen, hydrogen and carbon monoxide gases, and various gas pressures for 3 hours at $570^{\circ}C$. After treatment, the different cooling rates(slow cooling and fast cooling) were used to investigate its effect on the structure of the compound layer. The ${\varepsilon}$ phase occupied the outer part of the compound layer and ${\gamma}^{\prime}$ phase existed between the ${\varepsilon}$ phase and the diffusion zone. The gas composition of the atmosphere influenced the constitution of the compound layer produced, i.e. high nitrogen contents were essential for the production of ${\varepsilon}$ phase compound layer. It was found that with increasing carbon content in the gas mixture the compound layer thickness increased up to 10%. In the gas pressure around 3 mbar, the compound layer characteristics were slightly effected by gas pressure. However, in the low gas pressure and high gas pressure, the compound layer characteristics were significantly changed. The constitution of the compound layer was altered by varying the cooling rate. A large amount of ${\gamma}^{\prime}$ phase was transformed from the ${\varepsilon}$ phase during slow cooling.

  • PDF

Heat Transfer Analysis for Asphalt Mixture Temperature Variation due to Wind Speed (풍속에 따른 포설 아스팔트 혼합물의 온도변화에 대한 열전달 해석)

  • Yun, Tae Young;Yoo, Pyeong Jun
    • International Journal of Highway Engineering
    • /
    • v.17 no.4
    • /
    • pp.33-40
    • /
    • 2015
  • PURPOSES: Evaluation of the wind speed effect on the temperature drop of an asphalt mixture during construction, by using the transient heat transfer theory and dominant convective heat transfer coefficient model. METHODS: Finite difference method (FDM) is used to solve the transient heat transfer difference equation numerically for various wind speeds and initial temperature conditions. The Blasius convective heat transfer coefficient model is adapted to account for the effect of wind speed in the temperature predictions of the asphalt mixture, and the Beaufort number is used to select a reasonable wind speed for the analysis. As a function of time and depth, the temperature of the pavement structure is predicted and analyzed for the given initial conditions. RESULTS : The effect of wind speed on the temperature drop of asphalt mixture is found to be significant. It seems that wind speed is another parameter to be accounted for in the construction specifications for obtaining a better quality of the asphalt mixture. CONCLUSIONS: It is concluded that wind speed has a significant effect on the temperature drop of the asphalt layer. Although additional field observations have to be made to reflect the effect of wind speed on the construction specifications, it appears that wind speed is a dominant variable to be considered, in addition to the atmospheric temperature.

Strength Characteristics of Soil-Bentonite Mixture (Soil-Bentonite 혼합토의 강도 특성)

  • Jin, Guang-Ri;Shin, Dong-Hoon;Im, Eun-Sang;Kim, Ki-Young
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2009.03a
    • /
    • pp.844-851
    • /
    • 2009
  • A soil mixture with low permeability and bentonite as an additive has been highly utilized as a cutoff material in landfills, banks, and dams. Even though it is anticipated that the water can seep through shear failures in the filter layer due to external loads and embankment loads during construction, usually only the coefficient of permeability of the soil mixture is considered rather than the changes of strength from the different amounts of additives. Therefore, the amount of bentonite was changed between 0%~4% in the soil mixture of the bed material to conduct a series of unconfined compressive strength, tensile strength, and shear strength tests on a specimen in order to study the characteristics of the strength. In the result, the unconfined compressive and tensile strength were increased along with the increased amount of bentonite in the low water content; however, the tensile strength in the consolidated-drained shear test generally showed similar values without significant changes.

  • PDF

Identification of shear layer at river confluence using (RGB) aerial imagery (RGB 항공 영상을 이용한 하천 합류부 전단층 추출법)

  • Noh, Hyoseob;Park, Yong Sung
    • Journal of Korea Water Resources Association
    • /
    • v.54 no.8
    • /
    • pp.553-566
    • /
    • 2021
  • River confluence is often characterized by shear layer and the associated strong mixing. In natural rivers, the main channel and its tributary can be separated by the shear layer using contrasting colors. The shear layer can be easily observed using aerial images from satellite or unmanned aerial vehicles. This study proposes a low-cost identification method extracting geographic features of the shear layer using RGB aerial image. The method consists of three stages. At first, in order to identify the shear layer, it performs image segmentation using a Gaussian mixture model and extracts the water bodies of the main channel and tributary. Next, the self-organizing map simplifies the flow line of the water bodies into the 1-dimensional curve grid. After that, the curvilinear coordinate transformation is performed using the water body pixels and the curve grid. As a result, the shear layer identification method was successfully applied to the confluence between Nakdong River and Nam River to extract geometric shear layer features (confluence angle, upstream- and downstream- channel widths, shear layer length, maximum shear layer thickness).

High-temperature oxidation of Ti3(Al,Si)C2 nano-laminated compounds in air

  • Lee, Hwa-Shin;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2007.11a
    • /
    • pp.147-148
    • /
    • 2007
  • The compound, Ti3(Al,Si)C2, was synthesized by hot pressing a powder mixture of TiCX, Al and Si. Its oxidation at 900 and 1000 oC in air for up to 50 h resulted in the formation of rutile-TiO2, -Al2O3 and amorphous SiO2. During oxidation, Ti diffused outwards to form the outer TiO2 layer, and oxygen was transported inwards to form the inner mixed layer.

  • PDF