• Title/Summary/Keyword: Mixture Behavior

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Effect of Solvent Mixture on the Properties of LTCC Slurry and Green Sheets (LTCC 슬러리 및 그린시트의 물성 변화에 미치는 혼합용매 조성의 영향)

  • Cho, Beom-Joon;Park, Eun-Tae
    • Korean Journal of Materials Research
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    • v.16 no.9
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    • pp.533-537
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    • 2006
  • The effects of binary solvent mixtures with various ratios of toluene and ethanol on the properties of slurries and green sheets were investigated. Viscosity of slurry was changed by varying the ratio of solvent mixture which affected the solubility of binder. The relative solvency behavior of a solvent mixture could be predicted with the Hildebrand solubility parameter(${\delta}$) and hydrogen bonding index( ${\gamma}$). The minimum viscosity, the best dispersion of binder, was reached at the composition of toluene:ethanol=4:6, which corresponded to our forecast. The mechanical properties of green sheets related to evaporation of solvents were influenced by the composition of the solvent mixture. At the azeotrope the skin was formed on a drying cast during the drying process because of fast evaporation. At a range of concentrations over 50wt% toluene, green sheets could not be fully dried at low temperature due to excessive toluene. The mechanical properties of green sheets were excellent at the azeotrope-like composition of toluene:ethanol=4:6 which has a little excess of toluene over the azeotrope.

EXPERIMENTAL STUDY ON THE FLOW AND MIXTURE DISTIBUTION IN A VISUALIZATION ENGINE USING DIGITAL PARTICLE IMAGE VELOCIMETRY AND ENTROPY ANALYSIS

  • Lee, K.H.;Lee, C.H.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.127-135
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    • 2007
  • The objective of this study is to analyze the effect of velocity and vorticity on stratified mixture formation in the visualization engine. In order to investigate spray behavior, the pray velocity is obtained through the cross-correlation PIV method, a useful optical diagnostics technology and the vorticity calculated from the spray velocity component. These results elucidated the relationship between vorticity and entropy, which play an important role in the diffusion process for the early injection case and the stratification process for the late injection case. In addition, we quantified the homogeneous diffusion ate of spray using entropy analysis based on Boltzmann's statistical thermodynamics. Using these methods, we discovered that the homogeneous mixture distribution is more effective as a momentum dissipation of surrounding air than that of the spray concentration with a change in the injection timing. We found that the homogenous diffusion rate increased as the injection timing moved to the early intake stroke process, and BTDC $60^{\circ}$ was the most efficient injection timing for the stratified mixture formation during the compression stroke.

Experiments and MAAP4 Assessment for Core Mixture Level Depletion After Safety Injection Failure During Long-Term Cooling of a Cold Leg LB-LOCA

  • Kim, Y. S.;B. U. Bae;Park, G. C.;K. Y. Sub;Lee, U. C .
    • Nuclear Engineering and Technology
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    • v.35 no.2
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    • pp.91-107
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    • 2003
  • Since DBA(Design Basis Accidents) has been studied rather separately from SA(Severe Accidents) in the conventional nuclear reactor safety analysis, the thermal hydraulics during transition between DBA and SA has not been identified so much as each accident itself. Thus, in this study, the thermal hydraulic behavior from DBA to the commencement of SA has been experimentally and analytically investigated for the long-term cooling phase of LB-LOCA(Large-Break Loss-of-Coolant Accident). Experiments were conducted for both cases of the loop seal open and closed in an integral test loop, named as SNUF (Seoul National University Facility), which was scaled down to l/6.4 in length and 1/178 in area of the APR1400 (Advanced Power Reactor 1400MWe). The core mixture level was a main measured value since it took major role in the fuel heat-up rate, the location of fuel melting initiation and the channel blockage by melting material during SA. Experimental results were compared to MAAP4.03 to assess its model of calculating the core mixture level. MAAP4.03 overestimates the core two- phase mixture level because sweep-out and spill-over and the measures to simulate the status of loop seal are not included, which is against the conservatism. Thus, it is recommended that MAAP4.03 should be improved to simulate the thermal hydraulic phenomena, such as sweep-out, spill-over and the status of loop seal.

Measurement of Autoignition Temperature of Propionic Acid and 3-Hexanone System (Propionic acid와 3-Hexanone 계의 최소자연발화온도의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.28 no.4
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    • pp.44-49
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    • 2014
  • The autoignition temperaturs (AIT) of solvent mixture is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AIT and ignition delay time for Propionic acid and 3-Hexanone system by using ASTM E659 apparatus. The AITs of Propionic acid and 3-Hexanone which constituted binary system were $511^{\circ}C$ and $425^{\circ}C$, respectively. The experimental AIT of Propionic acid and 3-Hexanone system were a good agreement with the calculated AIT by the proposed equations with a few average absolute deviation (A.A.D.). And Propionic acid and 3-Hexanone system was shown the minimum autoignition temperature behavior (MAITB).

Characteristics of Sand-Rubber mixtures with Strain Level (모래-고무 혼합재의 변형율 크기에 따른 거동 특성)

  • Lee, Chang-Ho;Truong, Q. Hung;Eom, Yong-Hun;Lee, Jong-Sub
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.90-96
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    • 2008
  • Engineered mixtures composed of rigid sand particles and soft rubber particles are tested to investigate their behavior with strain level. Mixtures are prepared with different volumetric sand fractions (sf) to identify response using small strain resonant column, intermediate strain oedometer, and large strain direct shear tests. The small strain shear modulus and damping ratio are determined with volumetric sand fractions. The asymmetric frequency response curve increases with decreasing sand fraction. Linear responses of shear strain and damping ratio with shear strain are observed at the mixture of sf=0.2. Vertical strain increases with decreasing sand fraction. Mixtures with $04.{\leq}sf{\leq}0.6$ show the transitional stress-deformation behavior from rubber-like to sand-like behavior. The friction angle increases with the sand fraction and no apparent peak strength is observed in mixture without sf=1.0.

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Study on the Behavior Characteristics of Gasoline-Fuel Spray by Using a Numerical Analysis (수치해석을 이용한 가솔린연료 분무 거동특성 연구)

  • Yeom, Jeong-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.992-999
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    • 2009
  • The focus of this study is placed on the behavior characteristics of gasoline spray under condition field of room temperature and pressure. To analyze the behavior and flow characteristics of injected fuel spray is important in speculation of mixture formation process. Also the exhausted emissions from actual engines can be controlled by the analyzed results. The ${\varphi}$(degree of freedom) and K(energy ratio of particle motion) are selected as the simulation parameter. The factors affect characteristics of spray structure, and the factors are included in the sub-program of the KIVA-II code. In this study, the simulation study by modified KIVA-II code was conducted and the calculated results obtained by the modified KIVA-II code show good agreements with experimental results. As a result, applying the improved TAB model with ${\varphi}$=8 and K=2 to simulation analysis of the KIVA-II code is sufficiently useful for analyzing the macro characteristics in spray structure, such as the spray tip penetration of injected fuel spray.

DEHP Migration Behavior from Excessively Plasticized PVC Sheets

  • Kim, Jung-Hwan;Kim, Seong-Hun;Lee, Chang-Hyung;Nah, Jae-Woon;Hahn, Airan
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.345-349
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    • 2003
  • The quantity, process and kinetics of di-(2-ethylhexyl)phthalate (DEHP) migration in the 30/70 and 40/60 poly(vinylchloride) (PVC)/DEHP blends were investigated using gas chromatograph. A thin and flexible PVC sheet was soaked in surrounding medium (SM) of water/ethanol mixture and acetonitrile with constant stirring to release DEHP. By observed concentration of DEHP in the SM, it is found that acetonitrile is more intense in DEHP migration than water/ethanol mixture. In addition the amount of extracted DEHP is proportional to the leaching temperature and added ratio of DEHP. The behavior of DEHP migration from flexible PVC sheets was described by the Ficks's law with $2.72-10.1\;{times}\;10^{-10}$ cm²/s of the diffusion coefficients.

Effects of fines content on void ratio, compressibility, and static liquefaction of silty sand

  • Lade, Poul V.;Yamamuro, Jerry A.;Liggio, Carl D. Jr.
    • Geomechanics and Engineering
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    • v.1 no.1
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    • pp.1-15
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    • 2009
  • Many aspects of the behavior of sands are affected by the content of non-plastic fine particles and these various aspects should be included in a constitutive model for the soil behavior. The fines content affects maximum and minimum void ratios, compressibility, shear strength, and static liquefaction under undrained conditions. Twenty-eight undrained triaxial compression tests were performed on mixtures of sand and fine particles with fines contents of 0, 10, 20, 30, 50, 75, and 100% to study the effects of fines on void ratio, compressibility, and the occurrence of static liquefaction. The experiments were performed at low consolidation pressures at which liquefaction may occur in near-surface, natural deposits. The presence of fines creates a particle structure in the soil that is highly compressible, enhancing the potential for liquefaction, and the fines also alter the basic stress-strain and volume change behavior, which should be modeled to predict the occurrence of static liquefaction in the field. The void ratio at which liquefaction occurs for each sand/fines mixture was determined, and the variation of compressibility with void ratio was determined for each mixture. This allowed a relation to be determined between fines content, void ratio, compressibility, and the occurrence of static liquefaction. Such relations may vary from sand to sand, but the present results are believed to indicate the trend in such relations.