• Title/Summary/Keyword: Mixed surfactant

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The Study of Application of Bio-Surfactant Producing Bacteria for Growing Crop in Oil Spilled Soil (기름으로 오염된 토양에서 작물생육을 위한 계면활성제 생산 Bacteria의 활용에 관한 연구)

  • Hwang, Cher-Won;Chang, Hae-Won;Choe, Yong-Rak
    • Journal of Life Science
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    • v.17 no.7 s.87
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    • pp.944-947
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    • 2007
  • Bacillus sp.LPO3 (producing emulsifying substances such as bio-surfactant) was used as a bio-control agent to degrade hydrocarbon (gasoline in oil spilled crop soil). The soil (brought from fertilizer store)was mixed with gasoline-spilled soil (made with Diatomaceous Earth, Sigma.U.S.A). The study was conducted for a period of 13 days, 13 days during which bacterial growth, hydrocarbon degradation and growth parameters of Bacillus sp.LP03 including shoot and root length were studied. We found that the effective of bacterial producing substance might bio-surfactants let the plants survive even more promote the growth of shoot and root length and showed antifungal activity against gray mold. Without the bacteria, they couldn't grow in oil-spilled soil not even survive. According to the results of the above experiments, we can see with following results, hydrocarbon in gasoline was reduced, day by day, then RNA dot blotting was done and it fit the results we had done. Finally, this Bacteria(producing bio-surfactant) were found to have effective bio-control agent for cropping in oil spilled soil and infected by gray mold.

Effects of Butanol Isomers on the Mixed Micellization of TTAB/Brij 35 Mixed Surfactant Systems (TTAB/Brij 35 혼합계면활성제의 미셀화에 미치는 부탄올 이성질체들의 효과)

  • Gil, Han-Nae;Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.111-117
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    • 2008
  • critical micelle concentration (CMC) and the counter ion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at 25oC in water and in aqueous solutions of butanol isomers were determined as a function of 1 (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The results say that the effects of butanol isomers on the micellization of TTAB/Brij 35 mixtures have been in the order of n-butanol>iso-butanol>t-butanol> water.

Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems (DBS/Brij 35 혼합계면활성제의 미셀화에 미치는 n-부탄올 효과)

  • Lee, Byeong-Hwan;Park, In-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.5
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    • pp.355-361
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    • 2006
  • The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

Effect of n-Butanol on the Mixed Micellar Properties of Sodium Dodecylsulfate(SDS) with Sodium Dodecylbenzenesulfonate(DBS) (Sodium Dodecylsulfate(SDS)와 Sodium Dodecylbenzenesulfonate(DBS)의 혼합미셀화에 미치는 n-Butanol의 효과)

  • 이병환
    • Journal of the Korean Chemical Society
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    • v.41 no.1
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    • pp.12-17
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    • 1997
  • The critical micelle concentrations(CMC*) and the counterion binding constants(B) in a micellar state of the mixed surfactant systems of sodium dodecylsulfate(SDS) with sodium dodecylbenzenesulfonate(DBS) at 25℃ in pure water and in aqueous solutions of n-butanol were determined as a function of α1 (the overall mole fraction of SDS) by the use of electric conductivity method. Various thermodynamic parameters(Xi, γi, Ci, aiM, β, ΔHmix and ΔGm0 for the micellization of SDS/DBS mixtures were calculated and analyzed by means of the equations derived from the nonideal mixed micelle model. The effect of n-butanol on the mixed micellization of SDS/DBS mixtures have been measured and analyzed by comparing the values of the thermodynamic parameters in pure water with those in aqueous solutions of n-butanol(0.1 M, 0.2 M, and 0.3 M).

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Injection moldable material utilizing shell waste and recycled polyethylene (貝角 廢棄物과 混合 廢플라스틱을 이용한 射出用 素材에 대한 硏究)

  • Chong, Mie-Hwa;Chung, Yong-Chan;Chun, Byoung-Chul;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.14 no.3
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    • pp.55-62
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    • 2005
  • Mechanical properties of shell powder containing mixed recycled plastics were investigated depending on the shell content and surface modification. First, shell powder and LDPE were compounded using the twin screw extruder to manufacture 40 wt% master batch(M/B), and the M/B was blended with LDPE to produce bulk specimens with 10, 20, 30 and 40 wt% shell content. To improve the compatibility of shell powder with mixed recycled plastics matrix, surface of shell powder was chemically modified with cations or cationic surfactant. Surface modified shell was also used to prepare bulk specimens with the same shell content. Mechanical property analysis showed obvious improvement for the surface modified shell containing bulk specimens compared to unmodified ones. These results can lead to the development of new applications for the mixed recycled plastics.

A Study on the Application of Soil Washing Technology for HOCs-Contaminated Soil Using Mixed Surfactants (소수성 유기오염물질로 오염된 토양에 대한 혼합 계면활성제를 이용한 토양세척기법의 적용성 연구)

  • Choi, Sang-Il;Lee, Jai-Young;Jang, Min
    • Journal of the Korean Society of Groundwater Environment
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    • v.4 no.2
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    • pp.103-108
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    • 1997
  • A series of batch tests were conducted to evaluate the design parameters for the application of soil washing techniques to the hydrophobic organic compounds (HOCs)-contaminated soil using mixed surfactants. Because the mixed surfactants form different structures of molecular aggregates from single surfactant, they were applied to improve the washing efficiency. Kinds of surfactants added, mixing ratio, and total concentration of mixed surfactants were evaluated. The uncontaminated soil was obtained from a country hill near Nock-Chun Station in Seoul. The portion of soil passing #4 (4.75 mm) sieve was used. The pH, organic contents and cation exchange capacity were 4.4, 1.6% and 4.08 meq/100 g, respectively The soil was artificially contaminated by n-dodecane. The 5% solution of OA-5 and OA-14 (1:1) showed 86% washing efficency. The 4% solution of SDS and OA-5 (1:1) showed 95% washing efficiency.

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Self-Diffusion Coefficients of Colloidal Association Structures in ADS/OTAC Mixed Aqueous Solutions by Pulsed (Field) Gradient Spin Echo-NMR (Pulsed (Field) Gradient Spin Echo (PGSE) NMR에 의한 ADS/OTAC 혼합 수용액에서의 콜로이드 회합체의 자가 확산 계수)

  • Kim, Hong-Un;Lim, Kyung-Hee;Kim, Eun-Hee;Cheong, Chae-Joon
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.339-348
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    • 2002
  • Self-diffusion coefficients of colloidal ass9Ciation structures in the aqueous solutions of anionic ammonium dodecyl sulfate (ADS) and cationic octadecyltrimethylammonium chloride (OTAC) surfactants were measured by pulsed-gradient spin echo NMR. The results were interpreted on the basis of the ADS/OTAC/water phase diagram. Crossing the phase boundaries, significant changes in self diffusion coefficients were observed and well correlated to the phase diagram. For the micelles their apparent radii were obtained from Stokes-Einstein equation. Their values were 15 for the ADS micelles and 54 ${{\AA}}$ for the OTAC micelles, respectively. For vesicles which were formed spontaneously at different relative amounts of the surfactants and total surfactant concentrations, the radius was measured as 50 to 200 nm. This result is in fair agreement with those by TEM and light scattering.

Characteristics of Kapok Fibers by Treatment with Sodium Oleate and Xanthan Gum (Sodium Oleate와 Xanthan Gum 처리에 의한 카폭 섬유의 특성)

  • Koo, Hyein;Park, Youngmi
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.44-50
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    • 2020
  • In this study, pre-treatment was performed on kapok, a hydrophobic fiber, to compare dyeability by hydrophilization. The pretreatment conditions of kapok fiber were used with different amounts of sodium oleate(NaO), a fatty acid-based anionic surfactant, and xanthan gum(XG) as a natural thickener. At this time, NaO and XG were separately or mixed treated with 0.01%, 0.1%, 1% aqueous solution at 80℃ for 30 min. Hydrophilicity through dyeing was confirmed using Sappan wood extract. Therefore, SEM observation was performed to investigate the surface change of kapok fiber according to the conditions. The surface color difference was also analyzed. Pretreated kapok fibers were made from nonwoven fabrics and the contact angles were measured to determine their hydrophilization. The surface of the fiber after pretreatment was found to be cracked when NaO and NaO were mixed with XG. The surface color was the highest in a and K/S values after the simultaneous treatment of NaO and XG, followed by NaO pretreatment and XG pretreatment. The contact angle of kapok fiber made of nonwoven fabric was slightly lower at 300g/㎡ than the fabric weight of 150g/㎡. Such hydrophilized nonwoven kapok fiber are expected to be used in various fields.

Preparation and Characterization of Mesoporous Ceramic Materials (메조기공 세라믹 소재의 형성과 특성 분석)

  • Ha, Tae-Jung;Park, Hyung-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.8
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    • pp.593-601
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    • 2012
  • Ordered mesoporous oxide films have been focused because of their low density, high interior specific surface area, and high thermal insulation. Specially, the ordered mesoporous oxide films prepared by self-assembly has many advantages due to easy process and high reproducibility. In this work, ordered mesoporous $SiO_2$, $Al_2O_3$, and $TiO_2$ films were synthesized by control of composition and processing parameter. Also, their structural, thermal, and mechanical properties were characterized variously. In conclusion, ordered mesoporous oxides will be one of core materials in new technology due to their excellent and unique properties.

A Study on Characteristics of Emulsified Fuel (유화연료의 특성에 관한 연구)

  • Jung, J.S.;Kim, J.J.;Lee, K.B.
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.105-110
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    • 1999
  • The elementary experiment was performed to develop the emulsified fuel production system using pressure injection nozzle in this study. The stabilities and characteristics of emulsified fuel which is produced through direct spray of water via pressure injection nozzle into oil are examined. To understand performance of emulsion production, stabilities of emulsified fuel which is made by adding water to the mixed fuel of Bunker-C and 10 $^{\sim}$ 50 vol% of heating oil were investigated. According to volume ratios of surfactant in heating oil the stability and SMDs were measured

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