• Title/Summary/Keyword: Mixed layer

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High Temperature Oxidation of Thermomechanically Treated Ti-45.4%Al-4.8%Nb Alloys (열기계적 처리한 Ti-45.4%Al-4.8%Nb 합금의 고온산화)

  • Kim Jae-Woon;Lee Dong-Bok
    • Korean Journal of Materials Research
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    • v.14 no.7
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    • pp.457-461
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    • 2004
  • The thermomechanically treated $Ti-45.4\%Al-4.8\%Nb(at\%)$ alloy was oxidized between 800 and $1000^{\circ}C$ in air, and the oxidation characteristics were studied. The dissolution of Nb in the oxide scale was observed from the TEM study. The Pt marker test revealed that the oxidation process was controlled by the outward diffusion of Ti ions and the inward diffusion of oxygen ions. During oxidation, the evaporation of Nb-oxides was found to occur to a small amount. Niobium tended to pile-up at the lower part of the oxide scale, which consisted primarily of an outer $TiO_2$ layer, and an intermediate $Al_{2}O_{3}-rich$ layer, and an inner mixed layer of ($TiO_{2}+Al_{2}O_{3}$).

NUMERICAL METHOD FOR SINGULAR PERTURBATION PROBLEMS ARISING IN CHEMICAL REACTOR THEORY

  • Andargie, Awoke
    • Journal of applied mathematics & informatics
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    • v.28 no.1_2
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    • pp.411-423
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    • 2010
  • In this paper, a numerical method for singular perturbation problems arising in chemical reactor theory for general singularly perturbed two point boundary value problems with boundary layer at one end(left or right) of the underlying interval is presented. The original second order differential equation is replaced by an approximate first order differential equation with a small deviating argument. By using the trapezoidal formula we obtain a three term recurrence relation, which is solved using Thomas Algorithm. To demonstrate the applicability of the method, we have solved four linear (two left and two right end boundary layer) and one nonlinear problems. From the results, it is observed that the present method approximates the exact or the asymptotic expansion solution very well.

Study on high efficient phosphor layer using conductive powder particle in field emission light source (전계방출광원에서 전도성 입자를 이용한 고효율 형광막 특성 연구)

  • Jeong, Se-Jeong;Kim, Gwang-Bok;Lee, Seon-Hui;Kim, Yong-Won
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.3-6
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    • 2007
  • The Light brightness is to enhance the luminescence efficiency of phosphor including conductive material. In preparing the anode layer, phosphors mixed with conductive material prepared with pastes of polymer resin using by screen printing method. When the prepared anode layer bombarded by cold electron from emitter of cathode, it give rise to form the secondary electron from those of conductive materials such as ITO powder. Furthermore, we are expect to enhance the luminescence efficiency more than without conductive material.

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High Temperature Oxidation of Ti-43%Al-2%W-0.1%Si Alloys (Ti-43%Al-2%W-0.1%Si 합금의 고온산화)

  • 심웅식;이동복
    • Journal of the Korean institute of surface engineering
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    • v.36 no.2
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    • pp.128-134
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    • 2003
  • Alloys of Ti-43%Al-2%W-0.1%Si were oxidized isothermally and cyclically between $900^{\circ}C$ and$ 1050^{\circ}C$, and their oxidation characteristics were studied. During isothermal tests, the alloys oxidized slowly up to 100$0^{\circ}C$, but fast at $1050^{\circ}C$. Though the scale adherence was not good above $900^{\circ}C$, the alloys displayed better oxidation behavior than unalloyed TiAl alloys. The oxide scales consisted primarily of an outer $TiO_2$ layer, intermediate $Al_2$$O_3$-rich layer, and an inner mixed layer of (TiO$_2$ $+Al_2$$O_3$). Tungsten was present mainly at the lower part of the oxide scale, while Si over the whole oxide scale.

Thermally Stable Antireflective Coatings based on Nanoporous Organosilicate

  • Kim, Su-Han;Cho, Jin-Han;Char, Kook-Heon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.282-282
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    • 2006
  • Nanoporous organosilicate thin films were realized by the microphase separation of pore generating components mixed with an organosilicate matrix. The refractive index of such nanoporous organosilicate films can be tuned in the range of $1.40{\sim}1.22$. With a nanoporous single layer with n ${\sim}1.225,\;99.85\;%$ transmittance in the visible range was achieved. In order to overcome the limitation on the narrow wavelength for high transmittance imposed by single nanoporous thin films, bilayer thin films with different reflectance for each layer were prepared by inserting high refractive index layer with a refractive index of 1.447. It is demonstrated that the novel broadband antireflection coating with improved transmittance can be easily achieved by the nanoporous bilayer thin films described in present study.

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Effect of Structural Type of Clay Minerals on Physical Properties of Mountainous Grassland Soils

  • Choi, Seyeong;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.807-812
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    • 2016
  • Soil amendment, especially addition of clay minerals, has been widely conducted to improve the physical and chemical properties of cultivated soils. However, there are no systematic studies on the effects of the structural type of clay minerals added. This study was conducted to investigate the effects of structural type of clay minerals on physical properties of soils. Two experimental soils, layer-dominant and granule-dominant ones, were mixed with either a layer-type smectite or a granule-type zeolite at a level of 2.0 wt%. It was observed that water permeability of soils was decreased by smectite whereas not significantly changed by zeolite. This effect was much greater in layered clay-dominant soil than in granular clay-dominant soil. Our results clearly indicated that the relationship of structural type between a soil and an amendment plays a decisive role in the soil properties. Therefore, it is highly recommended that the structural types of both soil and amendment be taken into consideration for soil amendment by clay minerals.

Effects of the Gas Atmosphere of ZnO Buffer Layers in the ZnO films grown on Si Substrates by RF Magnetron Sputtering (RF 스퍼터링으로 Si 기판위에 제작된 ZnO 박막에서 ZnO 버퍼층의 가스분위기 영향)

  • Park, Tae-Eun;Cho, Hyung-Koun;Kong, Bo-Hyun;Hong, Soon-Ku
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.656-661
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    • 2005
  • The effects of gas atmosphere and in-situ thermal annealing in buffet layers on the characteristic of the ZnO grown by RF magnetron sputtering have been investigated. It was shown that the introduction of buffer layers grown at the gas atmospheres of the mixed $Ar/O_2$ and the in-situ thermal treatment of the ZnO buffer layer improved the structural and optical properties. In addition, the ZnO films on the buffer layer thermal-annealed at $N_2$ gas ambience showed the strong emission of the near band gap exciton with narrow linewidth by combining the high-temperature growth of the ZnO film.

Electrothermal Crack Analysis in a Finite Conductive Layer with Temperature-dependent Material Properties (온도 의존성 물성치를 가지는 유한한 전도층에서의 전기/열하중을 받는 균열의 해석)

  • Jang Yong-Hoon;Lee Sang-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.8 s.251
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    • pp.949-956
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    • 2006
  • The method of Greenwood and Williamson is extended to obtain a solution to the coupled non-linear problem of steady-state electrical and thermal conduction across a crack in a conductive layer, for which the electrical resistivity and thermal conductivity are functions of temperature. The problem can be decomposed into the solution of a pair of non-linear algebraic equations involving boundary values and material properties. The new mixed-boundary value problem given from the thermal and electrical boundary conditions for the crack in the conductive layer is reduced in order to solve a singular integral equation of the first kind, the solution of which can be expressed in terms of the product of a series of the Chebyshev polynomials and their weight function. The non-existence of the solution for an infinite conductor in electrical and thermal conduction is shown. Numerical results are given showing the temperature field around the crack.

Characteristics of Oceanographic Conditions in an Area Suitable for the Construction of Artificial Upwelling (인공 용승 구조물 설치에 적합한 해역의 해양환경 특성)

  • Cho Kyu-Dae;KIM Dong-Sun;PARK Sung-Eun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.2
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    • pp.187-192
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    • 2003
  • To evaluate the oceanographic conditions for the artificial upwelling we measured vertical stratification coefficients, current speed distribution and grain size distribution of bottom sediment in the vicinity of Gukdo and Somaemuldo near Geojedo. There were a strong stratification between surface and bottom layers in summer, the stratification was weak from autumn to winter, and the water was well mixed during winter. In summer nutrient concentration of the bottom layer was 4 times higher than that of the surface layer. Underwater currents were strong in the bottom layer. We conclude that the oceanographic conditions in the area will meet the basic requirement for the construction of artificial upwelling.

Effects of Cr and Nb on the nigh Temperature Oxidation of TiAl

  • D.B. Lee;K.B. Park;M. Nakamura
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.319-319
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    • 1999
  • From isothermal and cyclic oxidation tests on thermomechanically treated Ti-5%Al, Ti47%Al-4%Cr, and Ti-48%Al-2%Cr-2%Nb alloys at 800, 900, 1000℃ in air, it was found that Ti-48%Al-2%Cr-2%Nb and Ti-47%Al-4%Cr had the best and the worst oxidation resistance, respectively. The oxide scales consisted primarily of TiO₂and Al₂O₃, with and without a small amount of dissolved Cr and 7b ions, depending on the alloy composition. These ions were slightly enriched inside the inner oxide layer, and strongly enriched around the scale-matrix interface. The outer TiO₂-rich layer was formed by the outward diffusion of Ti ions, while the inner (TiO₂+A1₂O₃,) mixed layer was formed by the inward transport of oxygen. The outward movement of Al ions farmed the intermediate Al₂O₃-rich Iayer, above talc prepared alloys.