• Title/Summary/Keyword: Mixed conductor

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Partial Conductivity of YSZ Doped with 10 mol% $TiO_2$

  • Kobayashi, Kiyoshi;Kai, Yukiharu;Yamaguchi, Shu;Kawashima, Tsuyoshi;Iguchi, Yoshiaki
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.114-121
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    • 1998
  • Using Hebb-Wagner's asymmetric cell, partial conductivities of holes and electrons in yttria stabilized zirconia doped with 10 mol% TiO2 have been estimated by a dc polarization measurement. The current interrruption method and ac impedance measurements have been also made to evaluate the ionic conductivity and to examine the consistency of the partial conductivities. Partial conductivities of electrons(σn) and holes (σp) were found to be pro-peortional to -1/4 and 1/4 power of partial pressure of oxygen gas, respectively, except for σn at reducing conditions. In comparison with 5 mol% doped YSZ, σn was found to increase with the increase of TiO2 concentration, but σp stayed at almost a constant value.

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A Study on the ZnO Supported Silica Gel (ZnO가 담지된 실리카 겔 연구)

  • Kim, S.Y.;Kim, M.Y.;Ju, C.S.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.75-78
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    • 2011
  • There are various types of materials used in electronic industry, such as electrode material, conductor, insulator, anode, cathode and semiconductor. Electrode material type is Cu, Ti, ZnO and so on. Especially if we use mixed ZnO in soil cement or silica gel, we can have advantages in ice road to prevent freezing. We have great impact if we use supported in inorganic substances like silica gel. In this paper we have studied that ZnO supported silica gel and its properties. Zinc acetate dissolved in distilled water were loaded on the silica gel by the reaction with ammonia at $80^{\circ}C$. And we investigated particle structures of ZnO by scanning electron microscopy(SEM) and X-ray diffraction(XRD).

Studies of Co-Fe based perovskite cathodes with fixed A-site cations (중 저온형 고체 산화물 연료전지를 Co-Mn 계열의 페로브스카이트 구조의 공기극에 관한 연구)

  • Park, Kwang-Jin;Kim, Jung-Hyun;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.364-367
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    • 2006
  • The decrease of polarization resistance in cathode is the key point for intermediate temperature SOFC(Solid Oxide Fuel Cell). In this study, the Influence of Co substitution in B-site at perovskite PSCM (Pr0.3Sr0.7CoxMn(1-x)) was investigated. The PSCM series exhibits excellent MIEC(Mixed ionic Electronic Conductor) properties. The ASR(Area Specific Resistance) of PSCM3773 was $0.174{\Omega}cm^2\;at\;700^{\circ}C$. The activation energy of PSCM3773 was also lower than other compositions of PSCM. The ASR values were increased gradually during the thermal cycling test of PSCM37773 due to the delamination between electrolyte and cathode materials.

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Fabrication and Test of a 1 MJ Superconducting Energy Storage System for the Sensitive Load (민감부하 보상용 1 MJ 초전도 에너지저장 시스템 제작 및 시험)

  • 성기철;유인근;한성룡;정희종
    • Progress in Superconductivity and Cryogenics
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    • v.3 no.2
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    • pp.39-43
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    • 2001
  • For several decades researches and development on superconducting magnetic energy storage(SMES) system have been done for efficient electric power management. Korea Electrotechnology Research Institute (KERI) have developed of a 1MJ , 300kVA SMES System for improving power quality in sensitive electric loads. It consists of an IGBT (Insulated Gate Bipolar Transistor) based power conversion module. NbTi mixed matrix conductor superconducting magnet and a cryostat with HTS current leads. We developed the code fro design of a SMES magnet. Which could find the parameters of the SMES magnet having minimum amount of superconductors for the same store denerby. and designed the 1 MJ SMES magnet by using it . And we have design and fabricated cryostat with kA class HTS current leads for a 1 MJ SMES System. This paper describes the design fabrication and test results for a 1MJ SMES System.

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Electrothermal Crack Analysis in a Finite Conductive Layer with Temperature-dependent Material Properties (온도 의존성 물성치를 가지는 유한한 전도층에서의 전기/열하중을 받는 균열의 해석)

  • Jang Yong-Hoon;Lee Sang-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.8 s.251
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    • pp.949-956
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    • 2006
  • The method of Greenwood and Williamson is extended to obtain a solution to the coupled non-linear problem of steady-state electrical and thermal conduction across a crack in a conductive layer, for which the electrical resistivity and thermal conductivity are functions of temperature. The problem can be decomposed into the solution of a pair of non-linear algebraic equations involving boundary values and material properties. The new mixed-boundary value problem given from the thermal and electrical boundary conditions for the crack in the conductive layer is reduced in order to solve a singular integral equation of the first kind, the solution of which can be expressed in terms of the product of a series of the Chebyshev polynomials and their weight function. The non-existence of the solution for an infinite conductor in electrical and thermal conduction is shown. Numerical results are given showing the temperature field around the crack.

Two new records of orb-weaving spiders with a new species (Araneae: Araneidae) from Korea

  • Lee, Sue Yeon;Yoo, Jung Sun;Kim, Seung Tae
    • Journal of Species Research
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    • v.10 no.4
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    • pp.387-391
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    • 2021
  • Araneidae Clerck, 1757 is one of the largest families within the order Araneae Clerck, 1757, comprising 3,065 species in 177 genera. To date, two species of the genus Mengora O. Pickard-Cambridge, 1889 and four species of the genus Araniella Chamberlin & Ivie, 1942 have been recorded in Korea. During a seasonal survey of the spider fauna in mountainous terrain conducted from 2018 to 2019, females of Mangora foliosa Zhu & Yin, 1998 and a male of Araniella robusta sp. nov. were collected with a sweep net between shrubs in mixed forests from Mt. Juwangsan National Park. In this paper, we provide a diagnosis of the new species and descriptions including measurements and morphological illustrations. The new species, Araniella robusta sp. nov., can be easily distinguished from other species in the genus Araniella Chamberlin & Ivie, 1942 by a branched conductor with two blunt tips and conjugation of the embolus tip and terminal apophysis.

Oxygen Permeation Properties of $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ Mixed-conducting Membrane (혼합전도성 $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ 분리막의 산소투과 특성)

  • Lim, Kyoung-Tae;Cho, Tong-Lae;Lee, Kee-Sung;Woo, Sang-Kuk;Park, Kee-Bae;Kim, Jong-Won
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.787-793
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    • 2001
  • $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ membranes were fabricated by solid-state reaction. We investigated sintering behavior and oxygen permeation flux as a function of time-on-stream, temperature and upstream oxygen partial pressure. The oxygen was permeated at temperatures form 750$^{\circ}$C to 950$^{\circ}$C by mixed conducting through oxygen vacancy diffusion in the dense membrane. The oxygen permeation flux through the membrane were about 0.1ml/$cm^3{\cdot}$min at 850$^{\circ}$C. A constant time was required for reaching stable oxygen flux, and oxygen partial pressure affected the oxygen permeation fluxes.

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Study of $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) as the cathode materials for intermediate temperature SOFC (${\cdot}$저온형 고체 산화물 연료전지의 공기극 물질로 사용되는 $Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3-\delta}$ (x=0, 0.3, 0.5, 0.7, 1) 에 관한 연구)

  • Park, Kwang-Jin;Kim, Jung-Hyun;Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.125-128
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    • 2007
  • The influence of Co substitution in B-site at perovskite PSCF($Pr_{0.3}Sr_{0.7}CO_{x}Fe_{(1-x)}O_{3}$) was investigated in this study. The PSCF series exhibits excellent MIEC(mixed ionic electronic conductor) properties. ASR(area specific resistance) of PSCF3737 was 0.137 ${\Omega}{\cdot}cm^{2}$ at $700^{\circ}C$. The activation energy of PSCF3737 was also lower than other compositions of PSCF. ASR of PSCF3737 was analysed as two parts at different part of frequency region. Responses at middle frequency part (${\sim}10^2$ Hz) were concerned with oxygen reduction reaction and those at low frequency part (${\sim}10^{-1}$ Hz) were related with oxygen diffusion.

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Cathode Properties of Sm-Sr-(Co,Fe,Ni)-O System with Perovskite and Spinel Structures for Solid Oxide Fuel Cell (고체산화물 연료전지의 페로브스카이트와 스피넬 구조를 갖는 Sm-Sr-(Co,Fe,Ni)-O 시스템의 공기극 특성)

  • Baek, Seung-Wook;Kim, Jung-Hyun;Baek, Seung-Whan;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.133-136
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    • 2007
  • Perovskite-structured samarium strontium cobaltite (SSC), which is mixed ionic electronic conductor (MIEC), is considered as a promising cathode material for intermediate temperature-operating solid oxide fuel cell (SOFC) due to its high electrocatalytic property. Cathode material containing cobalt (Co) is unstable at high temperature and has a relatively high thermal expansion property. In this paper, Sm-Sr-(Co,Fe,Ni)-O system with perovskite and spinel structures was investigated in terms of electrochemical property and thermal expansion property, respectively. Area specific resistance (ASR) was measured by ac impedance spectroscopy to investigate the electrochemical property of cathode, and thermal expansion coefficient (TEC) was measured by using dilatometer. Micro structure of cathode was observed by scanning electron microscopy. Perovskite-structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ showed the ASR of $0.87{\Omega}/cm^{2}$, and $Sm_{0.5}Sr_{0.5}NiO_{3-\delta}$, which actually has a spinel structure, showed the lowest TEC value of $13.3{\times}10^{-6}/K$.

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Electric Field Optimization using the NURB curve in a Gas-Insulated Switchgear (NURB 곡선을 이용한 가스절연 원통형 관로 내에서의 전계 최적화)

  • Han, In-Su;Kim, Eung-Sik;Min, Suk-Won;Lee, June-Ho;Park, Jong-Keun;Lee, Tae-Hyung;Park, Choon-Soo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.3
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    • pp.548-558
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    • 2009
  • This paper attempts to develop an algorithm which optimizes the electric field through the so-called NURB(Non-Uniform Rational B-spline) curve in order to improve the insulation capacity. In particular, the NURB curve is a kind of interpolation curve that can be expressed by a few variables. The electric field of a conductor is computed by Charge Simulation Method(CSM) while that of a spacer by Surface Charge Method(SCM); this mixed calculation method is adopted for the electric field optimization. For calculation of the initial and optimal shapes, the Gauss-Newton method, which is quite easy to formulate and has slightly faster convergence rate than other optimization techniques, was used. The tangential electric field, the total electric field, and the product of the tangential electric field and area (Area Effect) were chosen as the optimization objective function by the average value of electric field for the determined initial shape.