• Title/Summary/Keyword: Mixed Phase

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열분해법과 혼합가스 질화법으로 합성한 FePtN 나노 입자의 특성 (Characterization of FePtN Nano-particles Synthesized by Thermal Decomposition and Mixed-gas Nitrification)

  • 오영우
    • 한국자기학회지
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    • 제26권4호
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    • pp.129-132
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    • 2016
  • 열분해법으로 합성한 FePt 나노입자를 $NH_3+H_2$ 혼합가스 질화법으로 상변태와 동시에 질화시킨 FePtN 나노입자의 특성을 분석하였다. 초기 합성된 FePt 나노입자는 fcc 구조를 가졌으며, 보자력과 포화자화는 각각 247.34 Oe와 27.308 emu/g를 나타내었다. 혼합가스 질화법으로 열처리한 입자는 XRD 분석 결과 fcc 구조에서 fct 구조로 상변태가 진행되었으며, 열처리 온도의 증가에 따라 (111) 피크의 $2{\theta}$가 shift되는 특성을 나타내었다. fct 구조의 FePtN의 보자력과 포화자화는 각각 1058.2 Oe and 32.718 emu/g를 나타내었으며, 합성된 FePtN 나노자성입자는 고밀도 자기기록매체와 생체의료 분야에서의 응용이 기대 된다.

Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and

  • 강계홍;김홍운;임경희;정노희
    • Bulletin of the Korean Chemical Society
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    • 제22권9호
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    • pp.1009-1014
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    • 2001
  • In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $\beta$ of the regular solution model was estimated to be -5 and this negative value of $\beta$ indicated an overall attractive force in the mixed state.

Synthesis and Photocatalytic Properties of SnO2-Mixed and Sn-Doped TiO2 Nanoparticles

  • Choi, Hong-Goo;Yong, Seok-Min;Kim, Do-Kyung
    • 한국재료학회지
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    • 제22권7호
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    • pp.352-357
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    • 2012
  • $SnO_2$-mixed and Sn-doped $TiO_2$ nanoparticles were synthesized via a hydrothermal process. $SnO_2$-mixed $TiO_2$ nanoparticles prepared in a neutral condition consisted of anatase $TiO_2$ nanoparticles(diamond shape, ~25 nm) and cassiterite $SnO_2$ nanoparticles(spherical shape, ~10 nm). On the other hand, Sn-doped $TiO_2$ nanoparticles obtained under a high acidic condition showed a crystalline phase corresponding to rutile $TiO_2$. As the Sn content increased, the particle shape changed from rod-like(d~40 nm, 1~200 nm) to spherical(18 nm) with a decrease in the particle size. The peak shift in the XRD results and a change of the c-axis lattice parameter with the Sn content demonstrate that the $TiO_2$ in the rutile phase was doped with Sn. The photocatalytic activity of the $SnO_2$-mixed $TiO_2$ nanoparticles dramatically increased and then decreased when the $SnO_2$ content exceeded 4%. The increased photocatalytic activity is mainly attributed to the improved charge separation of the $TiO_2$ nanoparticles with the $SnO_2$. In the case of Sn-doped $TiO_2$ nanoparticles, the photocatalytic activity increased slightly with the Sn content due most likely to the larger energy bandgap caused by Sn-doping and the decrease in the particle size. The $SnO_2$-mixed $TiO_2$ nanoparticles generally exhibited higher photocatalytic activity than the Sn-doped $TiO_2$ nanoparticles. This was caused by the phase difference of $TiO_2$.

벽체 내·외부에 시공한 PCM혼입 도료의 열적성능 평가에 관한 실험적 연구 (An experimental study on thermal performance evaluation of PCM mixed coating material constructed in and out of the wall)

  • 주동욱;신상헌;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.216-217
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    • 2014
  • Optimum finishing position, thickness and phase change temperature of winter and summer season were selected and suitability of finishing materials was evaluated based on temperature measurement of specimens applying the coating material mixed phase change materials(PCM). As a result, when finishing position was interior and finishing thickness of coating material mixed n-Octadecane(28℃ PCM) was 4mm, thermal performance was effective. n-Octadecane in summer season and n-Hexadecane(18℃ PCM) in winter season are indicated effective on energy savings, respectively.

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Smart Solid State Syntheses of Well-Crystallized Phase Pure Mixed Oxides for Electroceramics

  • Sennat, Mamoru
    • 한국세라믹학회지
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    • 제43권11호
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    • pp.680-687
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    • 2006
  • An overview is given to optimize the solid state processes toward phase pure and well-crystallized fine particulates of mixed oxides, serving as electroceramic materials in various genres. Elevation of the reactivity and preservation of stoichiometry of the starting mixture are of universal importance. Mechanical activation is versatile for these purposes, particularly when an oxygen atom as a hinge promotes formation of hetero-bridging bonds between dissimilar cationic species prior to calcination. Case studies carried out recently in the author's laboratory are displayed and compared for ferroelectric materials, i.e. $PbMg_{1/3}Nb_{2/3}O_3$ $xPbTiO_3$(PMN-PT), $(1-y)Pb(Zn_xMg{1-x})_{1/3}$ $yNb_{2/3}O_3$ (PZN-PMN), $BaBi_2Ta_2O_9$ (BBT), $Ba(Mg_{1/3}Ta_{2/3})O_3$ (BMT), and ferromagnetics, i.e. M-, Y-, and Z-phases of Ba-hexaferrites.

역변태 오스테나이트와 가공유기 마르텐사이트의 2상 혼합조직을 갖는 스테인리스강의 기계적 성질과 감쇠능 (Relationship Between Mechanical Properties and Damping Capacity in Stainless Steel with Two Phases of Reversed Austenite and Deformation Induced Martensite)

  • 남궁원;정목환;이향백;김재남;강창룡
    • 동력기계공학회지
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    • 제17권2호
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    • pp.114-120
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    • 2013
  • This study was carried out to investigate the relationship between mechanical properties and damping capacity in high manganese austenitic stainless steel with two phase mixed structure of reversed austenite and deformation induced martensite. Reversed austenite of ultra-fine grain size less than $0.3{\mu}m$ was obtained by reversion treatment. Two phase structure of deformation induced martensite and reversed austenite was obtained by annealing treatment at range of $500^{\circ}C{\sim}700^{\circ}C$ for various time in cold rolled high manganese austenite stainless steel. In stainless steel with two phase mixed structure of martensite and austenite, damping capacity decreased rapidly with the increasing hardness and strength. With the increasing elongation, damping capacity was increased rapidly and then, slowly increased.

폐기물을 포함한 이종혼합토의 강도·변형특성 (Strength and Deformation Characteristic of Two-Phase Mixture Soil)

  • 이기호
    • 한국지반환경공학회 논문집
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    • 제2권2호
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    • pp.33-39
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    • 2001
  • 굴패각을 혼합한 해성점토를 매립재료로 활용하기 위한 기초자료를 얻기 위해 삼축실험을 실시하여 혼합토의 전단 변형특성을 검토했다. 일련의 실험을 통해, 굴패각의 혼합율이 증가하면 이종혼합토의 강도가 증가한다는 것을 알 수 있었다. 그리고, 이러한 강도개선 효과는 순수점토와 같이 구속압에 기인한 마찰력뿐만 아니라, 굴패각의 골격 구조 및 형성과정에 의해서도 영향을 받고 있다는 것을 알 수 있었다. 또한, 혼합토의 할선탄성계수 및 다일러턴시 특성으로부터 굴패각 혼합에 의해 나타나는 영향을 파악하였고 보정계수의 개념을 도입해 전단과정의 굴패각 골격구조의 변화를 고찰했다.

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하소 조건 변화에 따른 YbBaCuO 초전도체 의 특성 연구 (A study on Properties of YbBaCuO Superconductor with various calcination conditions)

  • 이영매;박정철;소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.68-72
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    • 1997
  • In this paper, to obtain the YbB $a_2$C $u_3$ $O_{x}$ superconductor, the mixed Powders of Y $b_2$ $O_3$, BaC $O_3$, CuO and Y $b_2$BaCu $O_{5}$, BaCu $O_2$ were used and the various calcining conditions were applied for the 123 phase of YbB $a_2$C $u_3$ $O_{x}$. Samples were prepared by the mixed oxide method and calcined with various temperatures of 88$0^{\circ}C$ ~91$0^{\circ}C$ . It was observed that the distribution of YbB $a_2$C $u_3$ $O_{x}$ phase which was calcined at 90$0^{\circ}C$ for 12 hours and 99 hours. But the result of long time calcination(99 hrs), the 123 phase of YbB $a_2$C $u_3$ $O_{x}$ was existed between 89$0^{\circ}C$ and 91$0^{\circ}C$ . And the best case could be obtained at the calcination temp. of 90$0^{\circ}C$ from the mixed Powder of YbB $a_2$C $u_3$ $O_{5}$ and Bacu $O_2$ which were prepared individually.idually.

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저전력 비동기식 시스템 설계를 위한 혼합형 dual-rail data encoding 방식 제안 및 검증 (Mixed Dual-rail Data Encoding Method Proposal and Verification for Low Power Asynchronous System Design)

  • 지화준;김상만;박주성
    • 전자공학회논문지
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    • 제51권7호
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    • pp.96-102
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    • 2014
  • 본 논문에서는 dual-rail data encoding방식을 적용하여 비동기식시스템을 설계할 때, 신호천이를 줄이고 소비전력을 줄이기 위하여 4-phase handshaking 프로토콜과 2-phase handshaking 프로토콜을 혼합한 dual-rail data encoding방식을 제안한다. 기존의 dual-rail data encoding 4-phase handshaking 프로토콜은 space state가 존재함으로 말미암아 신호 천이가 많이 발생하게 되고 많은 전력소비를 발생한다. 이론적으로 dual-rail data encoding 2-phase handshaking 프로토콜은 dual-rail data encoding 4-phase handshaking 프로토콜보다 빠르고 신호천이도 적지만 표준 라이브러리를 사용하여 설계할 수 없다. 제안하는 혼합형 dual-rail data encoding 방식의 성능을 평가하기 위하여 Adder블록, Multiplier블록, Latch를 포함한 benchmark회로를 설계를 설계하였다. Benchmark회로를 이용하여 시뮬레이션해본 결과, 제안하는 혼합형 dual-rail data encoding방식은 기존의 dual-rail data encoding 4-phase handshaking 프로토콜에 비해 35%이상 전력소비가 감소되는 결과를 얻었다.

A Mixed Nonlinear Filter for Image Restoration under AWGN and Impulse Noise Environment

  • Gao, Yinyu;Kim, Nam-Ho
    • Journal of information and communication convergence engineering
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    • 제9권5호
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    • pp.591-596
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    • 2011
  • Image denoising is a key issue in all image processing researches. Generally, the quality of an image could be corrupted by a lot of noise due to the undesired conditions of image acquisition phase or during the transmission. Many approaches to image restoration are aimed at removing either Gaussian or impulse noise. Nevertheless, it is possible to find them operating on the same image, which is called mixed noise and it produces a hard damage. In this paper, we proposed noise type classification method and a mixed nonlinear filter for mixed noise suppression. The proposed filtering scheme applies a modified adaptive switching median filter to impulse noise suppression and an efficient nonlinear filer was carried out to remove Gaussian noise. The simulation results based on Matlab show that the proposed method can remove mixed Gaussian and impulse noise efficiently and it can preserve the integrity of edge and keep the detailed information.