• Title/Summary/Keyword: Mixed Gas

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Ethanol Gas Sensing Properties of NiO-based Composite Oxide Semiconductor with Co3O4 Nanoparticles (산화코발트 나노입자의 첨가에 따른 산화니켈 기반 반도체 산화물의 에탄올 가스 검출 특성 향상)

  • Kang, Wooseung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.382-388
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    • 2016
  • NiO nanoparticles were synthesized by hydrothermal method for the application to ethanol gas sensor. They were composited with $Co_3O_4$ nanoparticles to improve the sensitivity to ethanol gas. Scanning electron microscopy revealed that the synthesized NiO nanoparticles were plate-shaped with the approximate size and thickness of 60 - 120 nm and 20 nm, respectively. On the other hand, $Co_3O_4$ nanoparticles mixed with NiO was observed to be spherical with the size range of 30 - 50 nm. The sensitivities of NiO sensors composited with $Co_3O_4$ nanoparticles at an optimal ratio of 8 : 2 were enhanced to approximately 1.44 - 1.79 times as high as those of as-synthesized NiO sensors for the ethanol concentration of 10 - 200 ppm at $200^{\circ}C$. The mechanism of the improved ethanol gas sensing of the NiO sensors composited with $Co_3O_4$ nanoparticles was discussed.

Characteristics for Co-digestion of Food Waste and Night Soil using BMP Test (BMP실험을 이용한 음식물폐기물 및 분뇨의 병합소화 특성)

  • Cho, Jinkyu;Kim, Hyungjin;Oh, Daemin
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.9
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    • pp.13-18
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    • 2014
  • BMP test was carried out to evaluate the characteristics for co-digestion of night soil and food waste. 6 types of sludge were tested in 30 days which were raw, excess, digested, night soil/septic tank (1:1), food waste (food : dilution water = 1:1), and mixed sludge. Bio gas was produced actively after 2 days, and continued in 2 weeks. Gas generation amount was decreased rapidly after considerable space of time. Especially maximum productivity of gas was shown in 7~8 days. The ultimate methane yields of raw, excess, digested, night soil/septic tank, food waste, and mixed sludge were 64.63, 67.49, 66.45, 72.44, 107.85, and 46.71 mL $CH_4/g$ VS respectively from Modified Gompertz model. The lag growth phase time and maximum specific methane production rate of mixed sludge were 1.88 day and 80.4 mL/day respectively. The methane potential of mixed sludge was higher than individual sludge. So high methane potential was expected by controlling mixing ratio of food waste. Besides stable operation of digestion tank and the solution of oligotrophic problem were possible.

Highly-permeable SBS/UiO-66 Mixed Matrix Membranes for CO2/N2 Separation (CO2/N2 분리를 위한 SBS/UiO-66 기반의 고투과성 혼합 매질 분리막)

  • Kim, Young Jun;Moon, Seung Jae;Kim, Jong Hak
    • Membrane Journal
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    • v.30 no.5
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    • pp.319-325
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    • 2020
  • In this study, we developed mixed matrix membranes by blending thermoplastic elastomer, i.e. polystyreneblock-polybutadiene-block-polystyrene (SBS) block copolymer with the synthesized UiO-66 particles for CO2/N2 gas separation. To investigate the effect of UiO-66 particles in the SBS matrix, we prepared different mixed matrix membranes (MMMs) by varying the mass ratio of SBS and UiO-66 in the blend. To fabricate well-dispersed UiO-66, the SBS/UiO-66 mixture was sonicated and stirred thoroughly. The physico-chemical properties of prepared membranes were characterized by Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope (SEM). The gas separation performance was measured by time-lag method. The permeability of the MMMs increased significantly as the content of UiO-66 increased, but the CO2/N2 selectivity did not decrease significantly. The membranes containing 20% of UiO-66 particles showed the best performance with the CO2 permeability and CO2/N2 selectivity of 663.8 barrer and 13.3, respectively. This result showed performance closer to upper bound than pure SBS membrane in the Robeson plot, as the added UiO-66 particles did not significantly sacrifice selectivity and more than doubled gas permeability.

Fabrication and Gas Sensing Properties of WO$_3$Thick Film Gas Sensor Dependent on Heat-Treatment Condition (소성 조건에 따른 WO$_3$계 후막센서소자의 제조 및 응답특성)

  • 정용근;엄우식;이희수;최성철
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.2
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    • pp.63-68
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    • 1999
  • We have fabricated $WO_3$ thick film gas sensor under various firing conditions in order to study gas sensing properties in terms of the variation of microstructure and non-stoichiometric structure of gas sensing layer. $WO_3$ paste mixed homogeneously with organic vehicle was coated by screen printing method on alumina substrate composed of Au electrode and $RuO_2$heater on each side. To change filing condition, sensing materials were fared at 600-$800^{\circ}C$ for 1 hour and refired at $700^{\circ}C$ for 1 hour in the mixtures of $_Ar/O2$gas. In the result of heat-treatment, $WO_3$ gas sensor fared at $700^{\circ}C$ showed best gas sensing properties of 210 gas sensitivity and 2 second response time and the best firing environment was 40-50% of $Ar/O_2$gas.

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Behavior of Nitrogen in the Variation of Heat Treatment Conditions of Super Duplex Stainless Steel (수퍼 2상 스테인리스강의 열처리 조건변화에 따른 첨가원소 질소의 거동)

  • Joo, Dong Won;Sung, Jang Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.1
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    • pp.30-39
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    • 1997
  • After changing the heat treating atmosphere of nitrogen gas, argon gas and vacuum, the nitrogen contents, microstructural changes, hardness and corrosion resistance of 0.25wt.%N alloyed super duplex stainless steel have been investigated in the temperature range from $1050^{\circ}C$ to $1350^{\circ}C$. The nitrogen content showed to be increased up to 0.36wt.% after heat treating the specimen in nitrogen gas at $1200^{\circ}C$, while the decrement of nitrogen content in vacuum atmosphere was shown down to 0.03wt.% at $1350^{\circ}C$. After heat treating in the mixed gas atmosphere of argon and nitrogen at $1250^{\circ}C$, the surface ${\gamma}$ phase existed as ${\alpha}+{\gamma}$ phase increased with increasing nitrogen gas content. The ${\gamma}$ single phase appeared at the surface above $80%N_2$ gas, while the surface ${\alpha}$ single phase was shown below $20%N_2$ gas. When heat treating the specimen in nitrogen gas at $1050^{\circ}C$, the hardness of austenite phases increased above Hv 40 at the surface layer compared to the hardness of the core parts, while decrement of denitriding effect caused to the hardness nearly unchanged between surface and the core parts after heat treating in vacuum atmosphere. The surface ${\gamma}$ single phase specimen showed superior corrosion resistance than the surface ${\alpha}$ single phase specimen. The surface ${\alpha}$ phase existed in the ${\alpha}+{\gamma}$ microstructure showed higher corrosion resistance after heat treating in the nitrogen gas atmosphere than the ${\alpha}$ phase heat treated in the argon gas and vacuum atmosphere.

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Non-Steady State Gas Permeation Measurements of $TiO_2$-Doped YSZ

  • Kobayashi, Kiyoshi;Yamaguchi, Shu;Iguchi, Yoshiaki
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.150-154
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    • 2000
  • Mobilities of electrons ($\mu_p$) and holes ($\mu_p$) in 2, 5, and 10 mol% $TiO_2$-doped yttria stabilized zirconia (TD-YSZ) have been estimated by a non-steady state gas permeation method using models proposed by Weppner and Maruyama. Values of $\mu_n$ and $\mu_p$ were found to be closed to those in non-doped YSZ reported earlier. The concentration of electrons and holes were calculated from $\mu_n$ and $\mu_p$ values and the partial conductivities of electrons and holes measured by a dc-polarization method. The concentration of electrons at unit oxygen partial pressure increased with increasing $TiO_2$concentration, while the hole concentration was almost independent of $TiO_2$concentration.

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The ralationship between apex seal breakage and engine detonation in a wankel engine (Wankel 엔진의 에이펙스 시일 파손과 엔진 이상폭발과의 관계)

  • 김승수
    • Journal of the korean Society of Automotive Engineers
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    • v.7 no.1
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    • pp.48-54
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    • 1985
  • One of the most probable reason of the apex seal damage in IR-2500 industrial Wankel (rotary) engine was believed to be the engine detonation. Both analytical and experimental studies were made with a view th find out engine detonation pressure. The stagnation detonation pressure $p_{03}$' was estimated based on the data from IR-2500 engine detonation tests, such as engine firing pressure, state of fresh charge at BDC and polytropic compression exponent. The estimated stagnation detonation pressure for the natural gas fueled IR-2500 engine was in excess of 3,700 psia. With natural gas liquid added to the natural gas the octane value of the fuel was lowered, thus, making the engine more prone to detonate. The estimated detonation pressure for the case with the mixed fuel was about 3,400 psia which was sufficiently high to break the apex seal. The subsequent engine lab tests performed on two identical engines with sole difference in the apex seal thickness between the two engines proved that the engine knock, in fact, was the villain of the apex seal failure.ilure.

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The measurement of electron drift velocity and analysis of transport coefficients in SF$_6$+$N_2$ gas (SF$_6$+$N_2$혼합기체의 전자 이동속도 측정 및 수송계수 해석)

  • 하성철;하영선
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.462-472
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    • 1994
  • In this paper, electron drift velocity is experimentally measured in SF$_{6}$+N$_{2}$ Gas by induced cur-rent method and quantitaive production of electron transport coefficient is calculated by backward-prolongation of Boltzmann equation. Then electron energy distribution function and attachment coefficients are calculated. This paper can use the electron drift velocity by experimentally and the electron transport coefficient by calculated as a basic data of mixed Gas by comparing and investigating.g.

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A study of discharge characteristics by Xe content rates of AC PDP (Xe gas %에 따른 AC PDP의 방전특성 고찰)

  • Lee, Don-Kyu;Lee, Sun-Hong;Lee, Ho-Jun;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.148-150
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    • 2003
  • We investigated the discharge characteristics by adding a little $N_2$ to the mixed gas, Ne+Xe+He, as the working gas in AC PDP. In this study, it is founded that the luminance and efficiency of the panel included a little $N_2$ increased and the discharge firing voltage is reduced. In addition, the characteristics of jitter and delay time are investigated.

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The Experimental Study on Emission Reduction by Oxygenate Additive in D.I. Diesel Engine (직접분사식 디젤기관에서 함산소계 첨가에 의한 배출가스 저감에 관한 실험적 연구)

  • 최승훈;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.33-42
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    • 2002
  • Recently, our world is faced with very serious and hard problems related to the air pollution due to the exhaust emissions of the diesel engine. In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has three kinds of mixed ratio. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbon components from Cl to C6 in exhaust gas using gas chromatography to seek the reason far remarkable reduction of smoke emission. This study was carried out by comparing the chromatogram with diesel fuel and diesel feel blended DGM(diethylene glycol dimethyl ether) 5%. The results of this study show that individual hydrocarbon(C1∼C6) as well as total hydrocarbon of oxygenated fuel is reduced remarkably than that of diesel fuel.