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Ethanol Gas Sensing Properties of NiO-based Composite Oxide Semiconductor with Co3O4 Nanoparticles

산화코발트 나노입자의 첨가에 따른 산화니켈 기반 반도체 산화물의 에탄올 가스 검출 특성 향상

  • Kang, Wooseung (Department of Metallurgical & Materials Engineering, Inha Technical College)
  • 강우승 (인하공업전문대학 금속재료과)
  • Received : 2016.08.16
  • Accepted : 2016.08.30
  • Published : 2016.08.31

Abstract

NiO nanoparticles were synthesized by hydrothermal method for the application to ethanol gas sensor. They were composited with $Co_3O_4$ nanoparticles to improve the sensitivity to ethanol gas. Scanning electron microscopy revealed that the synthesized NiO nanoparticles were plate-shaped with the approximate size and thickness of 60 - 120 nm and 20 nm, respectively. On the other hand, $Co_3O_4$ nanoparticles mixed with NiO was observed to be spherical with the size range of 30 - 50 nm. The sensitivities of NiO sensors composited with $Co_3O_4$ nanoparticles at an optimal ratio of 8 : 2 were enhanced to approximately 1.44 - 1.79 times as high as those of as-synthesized NiO sensors for the ethanol concentration of 10 - 200 ppm at $200^{\circ}C$. The mechanism of the improved ethanol gas sensing of the NiO sensors composited with $Co_3O_4$ nanoparticles was discussed.

Keywords

References

  1. Miao Zhang, Moreno de Respinis, Heinz Frei, Time-Resolved Observations of Water Oxidation Intermediates on a Cobalt Oxide Nanoparticle Catalyst, Nat. Chem., 6 (2014) 362-367. https://doi.org/10.1038/nchem.1874
  2. Ngai Yui Chan, Meng Zhao, JianXing Huang, Kit Au, Man Hon Wong, Hei Man Yao, Wei Lu, Yan Chen, Chung Wo Ong, Helen Lai Wa Chan, Jiyan Dai, Highly Sensitive Gas Sensor by the $LaAlO_3/SrTiO_3$ Heterostruxcture with Pd Nanoparticle Surface Modulation, Adv. Mater., 26 (2014) 5962- 5968. https://doi.org/10.1002/adma.201401597
  3. Jin Wu, Xiaoli Zan, Shaozhou Li, Yayuan Liu, Chenlong Cui, Binghua Zou, Weina Zhang, Hongbo Xu, Hongwei Duan, Danbi Tian, Wei Huang, Fengwei Huo, In Situ Synthesis of Large- Area Single Sub-10 nm Nanoparticle Array by Polymer Pen Lithography, Nanoscale, 6 (2014) 749-752. https://doi.org/10.1039/C3NR05033E
  4. Hiroaki Yoshida, Naoaki Yabuuchi, Kei Kubota, Issei Ikeuchi, Arnd Garsuch, Martin Schulz- Dobrick, Shinichi Komaba, P2-Type $Na_{2/3}Ni_{1/3}Mn_{2/3-x}TixO_2$ as a New Positive Electrode for Higher Energy Na-Ion Batteries, Chem. Commun. 50 (2014) 3677-3680. https://doi.org/10.1039/c3cc49856e
  5. Peimei Da, Wenjie Li, Xuan Lin, Yongcheng Wang, Jing Tang, Gengfeng Zheng, Surface Plasmon Resonance Elnhanced Real-Time Photoelectrochemical Protein Sensing by Gold Nanoparticle- Decorated $TiO_2$ Nanowires, Anal. Chem. 86 (2014) 6633-6639. https://doi.org/10.1021/ac501406x
  6. Wenjin Yang, Baodan Liu, Bing Yang, Jianyu Wang, Takashi Sekiguchi, Staedler Thorsten, Xin Jiang, Psudobinary Solid-Solution: An Alternative Way for the Bandgap Engineering of Semiconductor Nanowires in the Case of GaPZnSe, Adv. Funct. Mater., 25 (2015) 2543-2551. https://doi.org/10.1002/adfm.201404523
  7. Pengfei Qiang, Zhongwei Chen, Peihua Yang, Xiang Cai, Shozao Tan, Pengyi Liu, Wenjie Mai, $TiO_2$ Nanowires for Potential Facile Integration of Solar Cells and Electrochromic Devices, Nanotechnol., 24 (2013) 435403-7. https://doi.org/10.1088/0957-4484/24/43/435403
  8. M. Fickenscher, T. Shi,H.E. Jackson, L.M. Smith, J.M. Yarrison-Rice, C. Zheng, P. Miller, J. Etheridge, B.M. Wong, Q. Gao, S. Deshpande, H.H. Tan, and C. Jagadish, Optical, Structural, and Numerical Investigations of GaAs/AlGaAs Core-Multishell Nanowire Quantum Well Tubes, Nano Lett., 13 (2013) 1016-1022. https://doi.org/10.1021/nl304182j
  9. Emily P. Thi, Chad E. Mire, Amy C.H. Lee, Joan B. Ceisbert, Joy Z. Zhou, Krystle N. Agans, Nicholas M. Snead, Daniel J. Deer, Trisha R. Barnard, Karla A. Fenton, Ian MacLachlan, Thomas W. Geisbert, Lipid Nanoparticle siRNA Treatment of Ebola-Virus-Makona-Infected Nonhuman Primates, Nature, 521 (2015) 362-365. https://doi.org/10.1038/nature14442
  10. Heng Chen, Liuyang Zhang, Matthew Becton, Hong Nie, Jinbao Chen, Xianqiao Wang, Molecular Dynamics Study of a CNT-Buckyball-Enabled Energy Absorption System, Phys. Chem. Chem. Phys., 17 (2015) 17311-17321. https://doi.org/10.1039/C5CP01969A
  11. Chunyan Zhang, Jiasheng Lai, Juncheng Hu, Hydrothermal Synthesis of Mn-Doped CdS Hollow Sphere Nanocomposites as Efficient Visible-Light Driven Photocatalysts, RSC Adv., 5 (2015) 15110-15117. https://doi.org/10.1039/C4RA16995F
  12. Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Hiroko Ariga, Nobuhiro Yasuda, Norihito Sakaguchi, Kiyotaka Asakura, Wataru Ueda, Ultrathin Inorganic Molecular Nanowire Based on Polyoxometalates, Nat. Commun., 6 (2015) 7731-7740. https://doi.org/10.1038/ncomms8731
  13. Iskandar N. Kholmanov, Carl W. Magnuson, Richard Piner, Jin-Young Kim, Ali E. Aliev, Cheng Tan, Tae Young Kim, Anvar A. Zakhidov, Giorgio Sberveglieri, Ray H. Baughman, Rodney S. Ruoff, Optical, Electrical, and Electromechanical Properties of Hybrid Graphene/Carbon Nanotube Films, Adv. Mater., 27 (2015) 3053-3059. https://doi.org/10.1002/adma.201500785
  14. Josephine Socratous, Kulbinder K. Banger, Yana Vaynzof, Aditya Sadhanala, Adam D. Brown, Alessandro Sepe, Ullrich Steiner, Henning Sirringhaus, Electronic Structure of Low- Temperature Solution-Processed Amorphous Metal Oxide Semiconductors for Thin-Film Transistor Applications, Adv. Funct. Mater., 25 (2015) 1873- 1885. https://doi.org/10.1002/adfm.201404375
  15. Songyue Chen, Albert van den Berg, Edwin T. Carlen, Sensitivity and Detection Limit Analysis of Silicon Nanowire Bio (Chemical) Sensors, Sens. Actuators B, 209 (2015) 486-489. https://doi.org/10.1016/j.snb.2014.12.007
  16. Xiaohong Sun, Xudong Hu, Yongchao Wang, Rui Xiong, Xin Li, Jing Liu, Huiming Ji, Xiaolei Li, Shu Cai, Chunming Zheng, Enhanced Gas-Sensing Performance of Fe-Doped Ordered Mesoporous NiO with Long-Range Periodicity, J. Phys. Chem. C, 119 (2015) 3228-3237. https://doi.org/10.1021/jp5124585
  17. Jinwei Li, Xin Liu, Jiashan Cui, Jianbo Sun, Hydrothermal Synthesis of Self-Assembled Hierarchical Tungsten Oxides Hollow Spheres and Their Gas Sensing Properties, ACS Appl. Mater. Interfaces, 7 (2015) 10108-10114. https://doi.org/10.1021/am508121p
  18. Liqiang Zhang, Zhenfei Gao, Chao Liu, Yunhan Zhang, Zhiqiang Tu, Xiaopeng Yang, Fan Yang, Zhen Wen, Liping Zhu, Rui Liu, Yongfeng Li, Lishan Cui, Synthesis of $TiO_2$ Decorated $Co_3O_4$ Acicular Nanowire Arrays and Their Application as an Ethanol Sensor, J. Mater. Chem. A 3 (2015) 2794-2801. https://doi.org/10.1039/C4TA06440B
  19. Chen Wang, Jiangyang Liu, Qiuyue Yang, Peng Sung, Yuan Gao, Fengmin Liu, Jie Zheng, Geyu Lu, Ultrasensitive and Low Detection Limit of Acetone Gas Sensor Based on W-Doped NiO Hierarchical Nanostructure, Sens. Actuators B, 220 (2015) 59-67. https://doi.org/10.1016/j.snb.2015.05.037
  20. Chengjun Dong, Xuechun Xiao, Gang Chen, Hongtao Guan, Yude Wang, Igor Djerdj, Porous NiO Nanosheets Self-Grown on Alumina Tube Using a Novel Flash SYnthesis and Their Gas Sensing Properties, RSC Adv. 5 (2015) 4880-4885. https://doi.org/10.1039/C4RA13025A
  21. Changhui Zhao, Jiecai Fu, Zhenxing Zhang, Erqing Xie, Enhanced Ethanol Sensing Performance of Porous Ultrathin NiO Nanosheets with Neck- Connected Networks, RSC Adv., 3 (2013) 4018-4023. https://doi.org/10.1039/c3ra23182h
  22. Cheng-Liang Hsu, Kuan-Chao Chen, Tsung-Ying Tsai, Ting-Jen Hsueh, Fabrication of Gas Sensor Based on p-Type ZnO Nanoparticles and n-Type ZnO Nanowires, Sens. Actuators B: Chem., 182 (2013) 190-196. https://doi.org/10.1016/j.snb.2013.03.002
  23. Sahar Hemmati, Azam Anaraki Firooz, Abbas Ali Khodadadi, Yadollah Mortazavi, Nanostructured $SnO_2$-ZnO Sensors: Highly Sensitive and Selective to Ethanol, Sens. Actuators B: Chem., 160 (2011) 1298-1303. https://doi.org/10.1016/j.snb.2011.09.065
  24. Davide Barreca, Giorgio Carraro, Elisabetta Comini, Alberto Gasparotto, Chirara Maccato, Cinzia Sada, Giorgio Sbervglieri, Eugenio Tondello, Novel Synthesis and Gas Sensing Performances of CuO-$TiO_2$ Nanocomposites Functionalized with Au Nanoparticles, J. Phys. Chem. C, 115 (2011) 10510-10517. https://doi.org/10.1021/jp202449k