• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집B
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• pp.367-372
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• 2000

By the means of microcellular (earning, we can make polymers with $10{\mu}m$ sized gas bubbles. After the $CO_2$ gas bubbles solve, diffuse and leave the polymer matrix, the thermal properties of polymer matrix are changed. Expecially, thermal conductivity becomes low. So, the polymer matrixes with gas bubbles can be used as insulator In this paper, we make model after microcellular foamed polymer matrix to know the change of thermal properties. Most of all, the purpose of this paper is the mlcrocellular foamed polymer matrix's availability as a insulator Beside of thermal properties the surface of microcellular foamed polymer is polished and easy to be colored. Above all the mechanical properties are better than the other insulator. So, microcellular foamed polymer can be used as exterior of building or it can be replaced as a tile.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2004년도 추계학술대회 논문집
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• pp.491-495
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• 2004

The industries use polymer materials for many purposes for they have many merits. The costs of these materials take up too great a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2$, $N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This characteristic of microcellular foaming process has influenced by cell morphology. The cell morphology means cell size and cell density. The cell morphology has influenced by many factors. The examples of factor are pressure drop rate, foaming temperature, foaming time, saturation pressure, saturation time etc. Among their factors, pressure drop rate is the most important factor for cell morphology in microcellular foaming injection molding process. This paper describes about the cell morphology change in accordance with the pressure drop rate of microcellular foaming injection molding process.

• 한국정밀공학회지
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• 제22권6호
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• pp.168-174
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• 2005

Nowadays, the companies use polymer materials for many purposes fur they have many advantages. The costs of these materials take up too high a proportion of the overall cost of products that use these materials as their major material. It is advantage for polymer industries to reduce these costs. The microcellular foaming process was developed in the early 1980s to solve this problem and proved to be quite successful. Microcellular foaming process uses inert gases such as $CO_2,\;N_2$. As these gases solve into polymer matrices, many properties are changed. The microcellular foaming process makes the glass transition temperature of polymers to low, and diminish the residual stress of polymer matrices. Besides, the microcellular foaming process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. In previous research, many facts of microcellular foaming process are founded its characteristics. But previous researcher found the characteristics of microcellular foaming process with pure gas, for example $CO_2,\;N_2$ and so on, they did not found the characteristics of microcellular foaming process with one more gases. If one more gases inlet the resin, the characteristics of microcellular foaming process is changed very amazingly. In this paper, discuss on the characteristics of microcellular foaming process wi th gas cocktail about cell morphology.

• 한국기계가공학회지
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• 제12권6호
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• pp.17-22
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• 2013

Recently, microcellular polymer films have been widely used as absorbents, support cells, and sensors in the industrial fields of IT, NT, BT, and ST. The conventional fabrication methods of microcellular polymer films are not only more complicated than those of non-microcellular polymer films, but also require a longer production time. In this paper, we propose a new hybrid fabrication method for microcellular polymer films; films can be rapidly made using UV laser processing with chemical blowing agents. The experimental results show that the number of the micropores increased with respect to the laser fluence and the concentration of the chemical blowing agents.

• 대한기계학회논문집A
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• 제25권5호
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• pp.816-822
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• 2001

The thermoforming process is widely used in the plastics industry to produce articles for the packaging, automotive, domestic construction and leisure industries. The microcellular foaming process appeared at M.I.T. in 1980s to save a quantity of polymer materials and increase their mechanical properties. The glass transition temperature of polymer materials is one of many important process variables in appling the microcellular foaming process to the conventional thermoforming process. The goal of this research is to evaluate the relation between gas absorption and glass transition temperature in batch process using microcellular foaming process. The weight gain ratio of polymer materials has a conception of gas absorption. Polymers such as acrylonitrile-butadiene-styrene(ABS), polystyrene(PS) have been used in this experiment. According to conventional Chows model and Cha-Yoon model, it was estimated with real experimental result to predict a change of glass transition temperature as a function of the weight gain ratio of polymer materials in batch process to gain microcellular foamed plastic products.

• Macromolecular Research
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• 제11권2호
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• pp.104-109
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• 2003

A microcellular, which combines a rubber with the conventional formulation of styrene/divinylbenzene/sorbitan monooleate/water system, was prepared using high internal phase emulsion (HIPE) polymerization. Although the open microcellular foam with low density from the conventional HIPE polymerization shows highly porous characteristics with fine, regular and isotropic structure, the one having much smaller cell size is desirable for various applications. In this study, a polybutadiene was introduced to reduce the cell size with comparable properties. Major interests were focused on the effects of rubber concentration and agitation speed on the cell sizes and compression properties. Scanning electron microscopy was used to observe the microcellular morphology and compression tests were conducted to evaluate the stress-strain behaviors. It was found that the cell size decreased as rubber concentration increased, reflecting a competition between the higher viscosity of continuous phase and the lower viscosity ratio of dispersed to continuous phases due to the addition of high molecular weight rubber into the oil phase of emulsion. A correlation for the average cell size depending on agitation speed was attempted and the result was quite satisfactory.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1367-1370
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• 2005

Microcellular foam processing of polymers requires a nucleated cell density greater than $10^9\;cells/cm^3$ so that the fully grown cells are smaller than 10 mm. A microcellular foam can be developed by first saturating a polymer sample with a volatile blowing agent, followed by rapidly decreasing its solubility in the polymer. In general, the cellular structure of crystalline polymer foams is difficult to control, compared to that of amorphous polymer foams. Since the gas does not dissolved in the crystallites, the polymer/gas solution formed during the microcellular processing is nonuniform. Moreover, the bubble nucleation is nonhomogeneous because of the heterogeneous nature of the crystalline polymer. In this paper, the effects of the crystallinity and morphology of crystalline polymers on the microcellular foam processing and on reflectivity of products are investigated. First, polymer specimens with various morphology and amount of solved blowing agent were prepared by varying the saturation pressure, saturation time and foaming condition. Then, cell morphologies according to several conditions were studied. The specimens with differing gas amount of solved and morphologies were foamed and their cellular structures were compared. The experimental results of reflectivity are compared to raw specimen and another specimen of different experimental conditions. After the experiments, recognize whether how reflectivity changes according to solved gas amount. And the effect of cell density and cell size on reflectivity is studied

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2001년도 춘계학술대회 논문집
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• pp.335-340
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• 2001

We use so many plastic products in everyday. Because polymer materials have a lot of merits including low cost and easiness of forming, they are widely used in many manufacturing industries. Microcellular foaming process was developed at MIT in 1980's to save a quantity of materials and increase mechanical properties. The improvement of strength is very important factor in relation with the reduction of mass. So the first purpose of this research is to improve the strength of the microcellular foamed plastics as variation of glass-fiber's volume friction. Also the characteristic of filler such as glass-fiber was presented in a microcellular foaming process.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2013년도 춘계학술대회 논문집
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• pp.1233-1234
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• 2013

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2010년도 춘계학술대회 논문집
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• pp.1191-1192
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• 2010