• Title/Summary/Keyword: Mg particles

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The Decarbonization of Sea Water by LD Slag

  • Han, Ki-Hyun;Kim, Hyung-Suek;M. S. Oh;Byeon, Tae-Bong
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.532-536
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    • 2001
  • LD slag, that is, a by-product of steel making process, has been mainly used as land construction materials. Recently, the seashore application of LD slag was tried in Japan and Korea but the reaction between LD slag and seawater was not studied yet. We tried to clarify the leaching reaction and/or mechanism of LD slag and the reaction between seawater and LD slag. We tried to apply these results to the decarbonization of seawater for seawater magnesia process. The high pH solution(over 12) was injected into the sea water and the pH of mixed liquid was adjusted to 9.8. This mixed solution was aged for 8 hours and the 104ppm of CO$_3$$^{-2}$ in the sea water was decreased to 23ppm with the negligible loss of $Mg^2$$^{+}$. The slag particle was directly inserted into the seawater fur practical application. The 0.5~1mm particles were suitable for decarbonization when 5 grade slags mentioned above were reacted with sea water. In this case, the content of CO$_3$$^{-2}$ in the sea water was 53 ppm with the negligible loss of $Mg^2$$^{+}$ after 8 hours aging. The direct application of slag particle fur the decarbonization of seawater takes more reaction time.ime.

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A study for the Effects of Sb Addition on the properties of Cast Iron (I) (주철(鑄鐵)의 성질(性質)에 미치는 Sb 첨가(添加)의 효과(效果)에 관(關)한 연구(硏究)(I);기계적(機械的) 성질(性質)과 Pearlite의 안정화효과(安定化效果)를 중심(中心)으로)

  • Lee, Byeong-Yehp;Lee, Kye-Wan
    • Journal of Korea Foundry Society
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    • v.4 no.4
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    • pp.20-29
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    • 1984
  • It is very important to obtain gray and ductile cast irons with completely pearlitic structure by addition more economical alloying elements. In this study, 9 melts of gray iron and 5 melts of Mg-treated ductile cast iron were made according to Sb content (0-0.08% Sb). Each melt were casted to ${\phi}20mm$ test bars in sand mold under the same condition and inspected microstructure, mechanical and thermal properties. The results obtained from this study are as follows: 1. It is confirmed that Sb should be an economical, simple and useful additive for avoiding ferrite in gray and even in ductile cast irons. 2. For gray cast iron, the recommended ladle addition of metallic Sb amounts to 0.05%. At these levels, Sb has no detrimental influence on the mechanical properties of gray cast irons, which are normally modified according to their pearlite content without increasing the chilling tendency. 3. Despite its adverse influence on graphite shape in ductile iron, Sb can be used as a pearlite stabilizing alloying element even in the case of Mg - treated iron. The quantity to be added does not exceed 0.04% in the case of thinwalled castings. 4. The nodule count is increased very much and the shape of graphite particles become remarkably spheroidal. The matrix may be fully pearlitized, except for thin - walled castings, because the high nodule count results inevitably in some ferrite. 5. The $Ac_1$ and pearlite decomposition temperature are rised in accordance with increasing of additive Sb amount.

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Analyzing the Effect of an Extreme Turbidity Flow Event on the Dam Reservoirs in North Han River Basin (북한강 수계 대규모 탁수사상 발생에 의한 댐 저수지의 탁수 영향 분석)

  • Park, Hyung-Seok;Chung, Se-Woong;Choung, Sun-a
    • Journal of Korean Society on Water Environment
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    • v.33 no.3
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    • pp.282-290
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    • 2017
  • A long-term resuspension of small particles, called persistent turbidity, is one of the most important water quality concerns in the dam reservoirs system located in North Han River. Persistent turbidity may incur aesthetic nuisance and harmful effect on the ecosystem health, in addition to elevated water treatment costs for the drinking water supply to the Seoul metropolitan area. These sufferings have been more intensified as the strength and frequency of rainfall events increase by climate change in the basin. This study was to analyze the effect of an extreme turbidity flow event that occurred in 2006 on the serial reservoirs system (Soyang-Uiam-Cheongpyung-Paldang) in North Han River. The CE-QUAL-W2 model was set up and calibrated for the river and reservoirs system using the field data obtained in 2006 and 2007. The results showed that Soyang Reservoir released turbid water, which was classified as the TSS concentration is greater than 25 mg/L, for 334 days with peak TSS of 264.1 mg/L after the extreme flood event (592.7 mm) occurred between July 10 and 18 of 2006. The turbid water departed from Soyang Reservoir reached at the most downstream Paldang Reservoir after about 20 days and sustained for 41 days, which was validated with water treatment plant data. Since the released water from Soyang Reservoir had low water temperature and high TSS, an underflow formed in the downstream reservoirs and vertically mixed at Paldang Reservoir due to dilution by the sufficient inflow from South Han River.

Nutritional Factors Affecting Efficiency of a Bioremediation Process for Diesel-Contaminated Soil (경유오염 토양의 생물정화공정에 대한 영양인자의 영향 분석)

  • No, Sang-Cheol;Lee, Cheol-Hyo;Jang, Deok-Jin
    • KSBB Journal
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    • v.14 no.4
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    • pp.503-510
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    • 1999
  • In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

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Micromorphometric change of implant surface conditioned with Tetracycline-HCl : HA and Etched surface (염산테트라싸이클린의 적용시간에 따른 특수 가공된 임프란트 표면 변화)

  • Han, Ju-Young;Park, Joon-Bong;Kwon, Young-Hyuk;Herr, Yeek;Chung, Jong-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.36 no.3
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    • pp.731-744
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    • 2006
  • The present study was performed to evaluate the effect of tetracycline-HCl on the change of implant surface microstructure according to application time. Implant with pure titanium machined surface, HA-coated surface and dual acid etched surface were utilized. Implant surface was rubbed with $50mg/m{\ell}$ tetracycline-HCL solution for ${\frac{1}{2}}$min., 1min., $1{\frac{1}{2}}$min., 2min., and $2{\frac{1}{2}}$min. respectively in the test group. Then, specimens were processed for scanning electron microscopic observation. The results of this study were as follows. 1. Both test and control group showed a few shallow grooves and ridges in pure titanium machined surface implants. There were not significant differences between two groups. 2. In HA-coated surfaces, round particles were deposited irregularly. The roughness of surfaces conditioned with tetracycline-HCL was lessened and the cracks were increased relative to the application time. 3. The etched surfaces showed the honey comb structures. The surface conditioning with tetracycline-HCI didn't influence on its micro-morphology. In conclusion, the detoxification with $50mg/m{\ell}$ tetracycline-HCI must be applied respectively with different time according to various implant surfaces.

Laser Cladding with Al-36%Si Powder Paste on A319 Al Alloy Surface to Improve Wear Resistance (A319 알루미늄 합금 표면에 Al-36%Si 합금분말의 레이저 클래딩에 의한 내마모성 향상)

  • Lee, Hyoung-Keun
    • Journal of Welding and Joining
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    • v.35 no.2
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    • pp.58-62
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    • 2017
  • A319 aluminum alloy containing 6.5% Si and 3.5% Cu as major alloying elements has been widely used in machinery parts because of its excellent castability and crack resistance. However it needs more wear resistance to extend its usage to the severe wear environments. It has been known that hyper-eutectic Al-Si alloy having more than 12.6% Si contains pro-eutectic Si particles, which give better wear resistance and lubrication characteristics than hypo-eutectic Al-Si alloy like A319 alloy. In this study, it was tried to clad hyper-eutectic Al-Si alloy on the surface of A319 alloy. In the experiments, Al-36%Si alloy powder was mixed with organic binder to make a fluidic paste. The paste was screen-printed on the A319 alloy surface, melted by pulsed Nd:YAG laser and alloyed with the A319 base alloy. As experimental parameters, the average laser power was changed to 111 W, 202 W and 280 W. With increasing the average laser power, the melting depth was changed to $142{\mu}m$, $205{\mu}m$ and $245{\mu}m$, and the dilution rate to 67.2 %, 72.4 % and 75.7 %, and the Si content in the cladding layer to 16.2 %, 14.6 % and 13.7 %, respectively. The cross-section of the cladding layer showed very fine eutectic microstructure even though it was hyper-eutectic Al-Si alloy. This seems to be due to the rapid solidification of the melted spot by single laser pulse. The average hardness for the three cladding layers was HV175, which was much higher than HV96 of A319 base alloy. From the block-on-roll wear tests, A319 alloy had a wear loss of 5.8 mg, but the three cladding layers had an average wear loss of 3.5 mg, which meant that an increase of 40 % in wear resistance was obtained by laser cladding.

Characteristics of Cyclone-Bag Filter with Bottom Inlet (하부유입식 원심 여과집진장치의 특성)

  • Yoa, Seok-Jun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.639-650
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    • 2000
  • The main object of this study was to investigate experimentally the characteristics of cyclone-bag filter with bottom inlet to decrease the high pressure drop which was one of main problems of fabric bag filter. The experiment was executed for the analysis of collection efficiency and pressure drop(specially, pressure drop of fabric filter) characteristics of the cyclone-bag filter in comparison with those of general fabric bag filter with various experimental parameters such as the inlet velocity, dust loading and variation of vortex region, etc. In the results, the tangential inlet type showed higher collection efficiency for submicron particles below $1{\mu}m$ in diameter than of center inlet, and over 99% for overall collection efficiency. For the inlet particle concentration $100mg/m^3$, pressure drop reduction ratios were shown as 15~38% with the inlet velocity in case of large bag, while 30~48% for small bag due to the increase of vortex region.

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Micromorphometric change of implant surface conditioned with tetracycline-HCI;HA and oxidized surface (표면처리 시간에 따른 임플란트 미세구조의 변화;HA와 양극산화 표면 임플란트)

  • An, Sang-Ho;Park, Joon-Bong;Kwon, Young-Hyuk;Herr, Yeek;Chung, Jong-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.35 no.4
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    • pp.891-905
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    • 2005
  • The present study was performed to evaluate the effect of tetracycline-HCL on the change of implant surface microstructure according to application time. Implant with pure titanium machined surface. HA-coated surface and TiUniteTM surface were utilized. Implant surface was rubbed with 50mg/ml tetracycline-HCL solution for $\frac{1}{2}min.$, 1min., $1\frac{1}{2}min.$, 2min., and $2\frac{1}{2}min.$ respectively in the test group. Then, specimens were processed for scanning electron microscopic observation. The results of this study were as follows. 1. Both test and control group showed a few shallow grooves and ridges in pure titanium machined surface implants. There were not significant differences between two groups. 2. In HA-coated surfaces, round particles were deposited irregularly. The roughness of surfaces conditioned with tetracycline-HCL was lessened and the cracks were increased relative to the application time. 3. The anodic oxidized surfaces showed the craterous structures. The surface conditioning with tetracycline-HCl didn't influence on its micro-morphology. In conclusion, the detoxification with 50mg/ml tetracycline-HCL must be applied respectively with different time according to various implant surfaces.

Sonochemical Synthesis of UiO-66 for CO2 Adsorption and Xylene Isomer Separation (초음파 합성법을 이용한 UiO-66의 합성 및 이산화탄소 흡착/자일렌 이성체 분리 연구)

  • Kim, Hee-Young;Kim, Se-Na;Kim, Jun;Ahn, Wha-Seung
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.470-475
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    • 2013
  • Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.

Optimal Production of N-acetyl-$\beta$-D-glucosamine Using Chitinolytic Enzyme (Chitinolytic Enzyme을 이용한 N-acetyl-$\beta$-D-glucosamine의 최적생산)

  • 이천우;이은영장상목김광
    • KSBB Journal
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    • v.11 no.6
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    • pp.696-703
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    • 1996
  • The bacterium Serratia marcescens QM Bl466 produces selectively large amount of chitinolytic enzymes(about 1mg/L medium). Enzymatic hydrolysis of chitin to N-acelyl-${\beta}$-D-glucosamine(NAG) is performed by a system consisting of two hydrolases : chitinase and chilobiase. Objectives of this study included optimization of a microbial host by using chitin particles for chitinase/chitobiase production and secretion and also development of batch fermentation system for high cell density cultivalion of S. marcescens QM B1466. Also, the influence of chitin source and carboxymethyl(CM) chitin on chitinase/chitobiase production and NAG production was investigated. When carboxymethyl chitin was substituted for colloidal and practical grade chitin, the chitinase activity was increased about 7∼10U/mL. In this case, the ratio of chitinase/chitobiase was 30.03U/3.44U(9:1). The highest amounts of NAG(3.0g/L) was obtained.

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