• Title/Summary/Keyword: Methane rates

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Effects of Elevated Atmospheric $CO_2$ Concentrations on Soil Microorganisms

  • Freeman Chris;Kim Seon-Young;Lee Seung-Hoon;Kang Hojeong
    • Journal of Microbiology
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    • v.42 no.4
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    • pp.267-277
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    • 2004
  • Effects of elevated $CO_2$ on soil microorganisms are known to be mediated by various interactions with plants, for which such effects are relatively poorly documented. In this review, we summarize and syn­thesize results from studies assessing impacts of elevated $CO_2$ on soil ecosystems, focusing primarily on plants and a variety the of microbial processes. The processes considered include changes in microbial biomass of C and N, microbial number, respiration rates, organic matter decomposition, soil enzyme activities, microbial community composition, and functional groups of bacteria mediating trace gas emission such as methane and nitrous oxide. Elevated $CO_2$ in atmosphere may enhance certain micro­bial processes such as $CH_4$ emission from wetlands due to enhanced carbon supply from plants. How­ever, responses of extracellular enzyme activities and microbial community structure are still controversy, because interferences with other factors such as the types of plants, nutrient availabilitial in soil, soil types, analysis methods, and types of $CO_2$ fumigation systems are not fully understood.

The extinction of unsteady counterflow diffusion flame without the retardation effect of a mixing layer (혼합층의 지연효과를 배제한 비정상 대향류 확산 화염의 소화)

  • Lee, Uen-Do;Oh, Kwang-Chul;Lee, Ki-Ho;Lee, Chun-Bum;Lee, Eui-Ju;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.93-101
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    • 2003
  • The extinction of unsteady diffusion flame was experimentally studied in an opposing jet counterflow burner using diluted methane. The stabilized flame was perturbed by linearly varying velocity change that was generated by pistons installed on both sides of the air and fuel stream. As the results, the extinction of unsteady flame is dependent not only on the history of unsteadiness, but also on the initial condition. We found that there are several unsteady effects on the flame extinction. First, the extinction strain rates of unsteady cases are extended well beyond steady state extinction limits. Second, as the slope of the strain rate change increases, the unsteady extinction strain rate becomes larger. Third, the extension of unsteady extinction strain rate becomes smaller as the initial strain rate increases. We also found that the extension of the extinction limit mainly results from the unsteady response of the reaction zone because there is no retardation effect of a mixing layer for our experimental condition.

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Dynamic Behaviors of Oscillating Edge-Flame in Low Strain Rate Counterflow Diffusion Flames (저신장율 대향류확산화염에서 진동불안정성을 갖는 에지화염의 동적거동)

  • Park, June-Sung;Kim, Hyun-Pyo;Park, Jeong;Kim, Jeong-Soo;Keel, Sang-In
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.65-72
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    • 2006
  • Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified.

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Denitrification of Anaerobic Sludge in Hybrid type Anaerobic Reactor(I): Acetate as Substrate (Hybrid type 반응조에서의 혐기성 슬러지의 탈질(I): 초산을 기질로 사용한 경우)

  • Shin, Hang-Sik;Kim, Ku-Yong;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.4
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    • pp.35-44
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    • 1999
  • In this study, it was attempted to remove nitrate and carbon in a single-stage reactor using acetate as substrate. Hybrid type upflow sludge baffled filter reactor was adopted using anaerobic sludge. Sludge bed in the bottom of reactor was intended to remove carbon and nitrate by denitrification and methanogenesis. And floating media in the upper part of reactor were intended to remove remaining carbon which was not removed due to the inhibition of nitrogen oxide on methane producing bacteria. The reactor removed over 96% of COD and most of nitrate with volumetric loading rate of $4.0kgCOD/m^3{\cdot}day$, hydraulic retention time of 24hr, 4,000mgCOD/L, and $266mgNO_3-N/L$. Nitrate in anaerobic sludge was converted to nitrogen gas(denitrification) or ammonia (ammonification) according to pH of influent, COD removal efficiency was easily affected by the change of volumetric loading rates and nitrate concentration. And when influent pH was about 4.7, most nitrate changed to ammonia while when influent pH was about 6.8~7.0, most nitrate denitrified independent of $COD/NO_3-N$ ratio. Most granules were gray and a few were black. In gray-colored granule, black inner side was covered with gray substance and SEM illustrated Methanoccoci type microorganisms which were compact spherical shape. Anaerobic filter removed residual COD effectively which was left in sludge bed due to the inhibition of nitrogen oxide.

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Behavior of the Edge Flame on Flame Extinction in Buoyancy minimized Methane-Air Non-premixed Counter Triple Co-flow Flames (부력을 최소화한 대향류 삼축 메탄-공기 비예혼합 화염 소화에서 에지화염의 거동)

  • Park, Jin Wook;Park, Jeong;Yun, Jin-Han;Keel, Sang-In
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.81-84
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    • 2014
  • A Experimental study on flame extinction behavior was investigated using He curtain flow with counter triple co-flow burner. Buoyancy force was suppressed up to a microgravity level of $10^{-2}-10^{-3}g$ by using He curtain flow. The stability maps were provided with a functional dependency of diluent mole fraction and global strain rate to clarify the differences in flame extinction behavior. The flame extinction curves had C-shapes at various global strain rates. The oscillation and extinction modes were different each other in terms of the global strain rate, and the flames extinction modes could be classified into five modes such as (I) and (II): an extinction through the shrinkage of the outmost edge flame forward the flame center after self-excitation and without self-excitation, respectively, (III): an extinction through rapid advancement of a flame hole while the outmost edge flame is stationary, (IV): self-excitation occurs in the outermost edge flame and the center edge flame and then a donut shaped flame is formed and/or the flame is entirely extinguished, (V): shrinkage of the outermost edge flame without self-excitation followed by shrinkage or survival of the center flame. These oscillation and extinction modes could be identified well to the behavior of edge flame. The result also showed that the edge flame was influenced significantly by the conductive heat losses to the flame center or ambient He curtain flow.

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Concentration Interaction of Premixed and Triple-layer Flames in Lean Burn with Methane Fuel (희박연소에서 발생하는 메탄의 농도 상호작용과 삼중화염에 대한 연구)

  • Oh, Tae-Kyun;Chung, Suk-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.171-178
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    • 2006
  • The performance in the practical combustion system including reciprocating engines and gas turbine combustors is being much governed by turbulent reacting flow that is often analyzed by both a laminar flamelets concept and flame interaction. The characteristics of laminar flame interaction have been investigated numerically to provide basic understanding of wrinkled turbulent flames under concentration interaction resulting from inhomogeneity in fuel-air mixing, especially focused on the transition of flame characteristics such as diffusion flame, partially premixed diffusion flame, and triple-layer flame by the variation in the degree of premixedness. The extinction stretch rates to the premixedness have also been obtained in this paper. The boundary defining the regime of the existence of triple-layer flames as functions of both stretch rate and premixedness has been determined which agrees well with previously reported experiment measuring OH radical concentration peaks based on PLIF.

A Study on the Treatment of Phenol Wastewater in an Anaerobic Fluidized-Bed Reactor (혐기성 유동층 반응기에서 페놀 폐수 처리에 관한 연구)

  • 박동일;안재동;신승훈;장인용
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.96-103
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    • 1996
  • The objectives of this study were to examine the biodegradation of phenol using the anaerobic fluidized bed reactor(AFBR). Mixed microorganisms were selected from the anaerobic digestion tank, and could be adapted to high concentration of phenol by increasing the phenol concentration 600-3600 mg/l step by step. The results were summarized as follows: 1. The average removal efficiency of phenol was 90%, decreased by increasing concentration of phenol, and then a shock range was 1200~2400 ppm. 2. The production rate of biogas in overall limits was proportional to the concentration of influent phenol. 3. At steady state, compositions of gases were $CH_4$ 55~60%, $C0_2$ 34~43%, respectively. These were similar to that of the theoretical estimates. 4. The production rates of biogas and methane per the molarity of phenol removed were linearly increased, 56.45 l gas/mol-phenol and 29.20 l $CH_4/mol$-phenol. Using this biogas, the recoverable energy was 269.1 kcal/mol phenol. It was 120.2 kcal/g-COD, transforming into the chemical oxygen demand. 5. The bulk of microorganisms existed in suspended section of fluidized bed with type of biofilm and its concentration was 340 mg/g-media. In conclusion, the anaerobic treatment of pure phenol was possible and its removal efficiency, introducing the AFBR, was successful. Also toxic organic compound such as phenol was biodegradable and was recoverable as resource of energy.

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High-Speed Deposition of Diamond Films by DC Plasma Jet (직류 플라즈마 제트를 이용한 고속 다이아몬드 막 증착기술)

  • Kim, Won-Kyu;Whang, Ki-Woong
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.949-951
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    • 1992
  • A low pressure DC plasma jet has been used to obtain diamond films from a mixture of $CH_4$ and $H_2$ with high deposition rate (>1$\mu\textrm{m}$/min). The effects of the deposition conditions such as torch geometry, substrate temperature, gas mixing ratio, chamber pressure, axial magnetic field on the diamond film properties such as morphology, purity, uniformity of the film and deposition rate, etc. have been examined with the aid of Scanning Electron Microscopy, X-Ray Diffraction, and Raman Spectroscopy. Both the growth rate and particle size increased rapidly for low methane concentrations but saturated and the morphology changed from octahedral to cubic structure when the concentration exceeded 1.0 %. Higher growth rates (>1.5${\mu}m$/min) can be obtained by applying an axial magnetic field to the DC plasma jet. Diamond obtained from the magnetized plasma jet also shows a sharp peak at 1332.5$cm^{-1}$ in the Raman Spectra and this result implies that higher growth rate with a good quality diamond films can he obtained by applying an external magnetic field to the plasma jet.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Yoon, Yong-Hee;Lee, Seung-Chul;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.81-85
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    • 2007
  • A fluidized bed reactor is made with quartz. The size of FBR is 0.055 m I.D. and 1.0 m in height. The FBR was employed for the thermocatalytic decomposition of propane to produce hydrogen without $CO_{2}$. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. Carbon black DCC-N330 is used to decompose the propane gas. The propane decomposition reaction over carbon black catalyst in a fluidized bed reactor was carried out the temperature range of 600 ${\sim}$ 800 $^{\circ}C$, propane gas velocity of 1.0 ${\sim}$ 4.0$U_{mf}$($1U_{mf}$ = 0.61cm/s) and the catalyst loading of 100 ${\sim}$ 200g. Production of $H_{2}$ such as other reaction temperature, gas velocity, catalytic loading on the reaction rates was investigated. The carbon depositied on the catalyst surface was observed by FE-SEM. The particle size of the carbon black was observed by Particle size analyzer. Resulting production in the experiment was not only hydrogen but also several by-products such as methane, ethylene, ethane, and propylene.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Nam, Woo-Seok;Jung, Jae-Uk;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.388-391
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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