• Title/Summary/Keyword: Metals and alloys

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A Study on Stress Corrosion of Al-8ti-1B Alloys by Mechanical Alloying (기계적 합금화한 Al-8Ti-1B 합금의 응력부식에 관한 연구)

  • 김기주;강성군;백영남
    • Journal of Surface Science and Engineering
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    • v.27 no.4
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    • pp.215-222
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    • 1994
  • The role dispersoids has been studied in a number of researches as a key point for the high strength application of dispersion strengthened aluminum alloy. The mechanical alloying(MA) process with high mechanical properties of dispersion strengthened MA Al-8Ti-1B alloys were invested in order to evaluate their stress corrosion cracking(SCC) application. SCC properties of the mechanically alloyed Al-8Ti-1B were studied using slow strain rate test(SSRT). In this study Al-8Ti-1B alloy were more susceptible to SCC in solutions of pH=2.01 and 13.2 than pH=6.81 solution. In this study Al-8Ti-1B alloys by MA had more SCC resistance than Al-8Ti alloys or Al 7075-T73 alloys. So Al-8Ti-1B alloys by MA had more resistance in SSRT SCC susceptinility test than any other above alloying metals.

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Effect of Delayed Oxygen Evolution in Anodic Polarization on the Passive Film Characteristic and Localized Corrosion Resistance of Titanium Alloys (타이타늄 합금에서 산소발생전위 지연이 부동태 피막 특성과 국부부식 저항성에 미치는 영향)

  • Oh, Yu Soo;Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.19 no.3
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    • pp.156-162
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    • 2020
  • The objective of this study was to investigate delayed oxygen evolution and localized corrosion resistance of titanium alloys by performing potentiodynamic polarization, potentiostatic polarization, and Mott-Schottky measurements. Delayed oxygen evolution was compared among titanium alloys, 316 stainless steel, and platinum. Difference in delayed oxygen evolution between titanium alloys and other metals was attributed to specific surface characteristic of each metal. Delayed oxygen evolution of titanium alloys resulted from the predominant process of ionic conduction over electronic conduction. The effect of oxygen evolution on localized corrosion of titanium alloys was investigated using electrochemical critical localized corrosion temperature (E-CLCT) technique. Mott-Schottky measurement was performed to clarify the difference in film properties between titanium alloys and stainless steels. Titanium alloys were found to have much lower donor density than stainless steels by 1/28. These results indicate that delayed oxygen evolution has little influence on the concreteness of passive film and the resistance to localized corrosion of titanium alloys.

Corrosion Behaviour of Some Alloys in Tropical Urban and Marine Atmospheres

  • Dang, Vu Ngoan;Bui, Ba Xuan;Nguyen, Nhi Tru
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.125-129
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    • 2008
  • Results of corrosion testing for different grades of titanium, copper, zinc, alluminium alloys and steels after two years of outdoor exposure under humid tropical urban and marine conditions have been presented and discussed. Mass loss and corrosion product characteristics for the exposed specimens at Hanoi testing site with high humidity and Nhatrang marine stations (at 100 and 1,000 meters distances from sea) with different airborne salinities (35.9 and $90.0mg/m^2.d$ respectively) have been selected for investigation. From time dependence of the specimen mass loss and corrosion product characteristics, the strong influence of environmental parameters upon durability for the investigated metals and alloys has been demonstrated. Only titanium alloys show high resistance to the marine conditions. All the other specimens (copper, zinc, alluminium alloys and steels) have been underwent strong deterioration under influence of aerosol salinity. Results of corrosion products analysis have been also presented for characterization of environmental impact on the metal degradation processes.

Properties of the White 5K Au-Ag-In Alloys with Indium Contents (백색 5K Au-Ag-In 합금재의 인듐 첨가량에 따른 물성 변화)

  • Song, Jeongho;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.27 no.7
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    • pp.381-385
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    • 2017
  • In order to replace 14K white gold alloys, the properties of 5K white gold alloys (Au20-Ag80) were investigated by changing the contents of In (0.0-10.0 wt%). Energy dispersive X-ray spectroscopy (EDS) was used to determine the precise content of alloys. Properties of the alloys such as hardness, melting point, color difference, and corrosion resistance were determined using Vickers Hardness test, TGA-DTA, UV-VIS-NIR-colorimetry, and salt-spray tests, respectively. Wetting angle analysis was performed to determine the wettability of the alloys on plaster. The results of the EDS analysis confirmed that the Au-Ag-In alloys had been fabricated with the intended composition. The results of the Vickers hardness test revealed that each Au-Ag-In alloy had higher mechanical hardness than that of 14K white gold. TGA-DTA analysis showed that the melting point decreased with an increase in the In content. In particular, the alloy containing 10.0 wt% In showed a lower melting temperature (> $70^{\circ}C$) than the other alloys, which implied that alloys containing 10.0 wt% In can be used as soldering materials for Au-Ag-In alloys. Color difference analysis also revealed that all the Au-Ag-In alloys showed a color difference of less than 6.51 with respect to 14K white gold, which implied a white metallic color. A 72-h salt-spray test confirmed that the Au-AgIn alloys showed better corrosion resistance than 14K white gold alloys. All Au-Ag-In alloys showed wetting angle similar to that of 14K white gold alloys. It was observed that the 10.0 wt% In alloy had a very small wetting angle, further confirming it as a good soldering material for white metals. Our results show that white 5K Au-Ag-In alloys with appropriate properties might be successful substitutes for 14K white gold alloys.

Thermodynamic Interactions Among Carbon, Silicon and Iron in Carbon Saturated Manganese Melts (탄소 포화 Mn 합금 용액내 C, Si 및 Fe 사이의 열역학적 상호작용)

  • Paek, Min-Kyu;Lee, Won-Kyu;Jin, Jinan;Jang, Jung-Mock;Pak, Jong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.45-51
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    • 2012
  • Thermodynamics of carbon in manganese alloy melts is important in manufacturing low carbon ferromanganese and silico-manganese alloys. In order to predict the carbon solubility in liquid $Mn-Si-Fe-C_{sat}$ alloys as a function of melt composition and temperature, thermodynamic interactions among carbon, silicon and iron in carbon saturated liquid manganese should be known. In the present study, the effects of silicon and iron on the carbon solubility in Mn-Si, Mn-Fe and Mn-Si-Fe melts were measured in the temperature range from 1673 to 1773 K. The carbon solubility decreases significantly as silicon and iron contents increase in liquid manganese alloy. The interaction parameters among carbon, silicon and iron in carbon saturated liquid manganese were determined from the carbon solubility data and the Lupis' relation for the interaction coefficient at constant activity.

Brazing Filler Metal and Process for Stainless Steel (스테인리스강용 브레이징 합금과 브레이징 공정)

  • Hong, Sung Chul;Park, Sang Yoon;Jung, Do Hyun;Oh, Joo Hee;Lee, Jae Hoon;Kim, Wonjoong;Jung, Jae Pil
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.15-20
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    • 2012
  • Brazing technology has been widely used among bonding technologies because it enables to bond various metals, even ceramics, dissimilar metals, and give higher bonding strength, cost down, automation, etc. However, there are many parameters to achieve optimal brazing joint such as brazing alloys, brazing atmospheres, designs and brazing methods, etc. The brazing parameters affect seriously on the characteristic of final brazing products. Stainless steel is broadly used in high temperature applications, chemical industry, heat exchangers, muffler of vehicles, and so on. Accordingly, in this article, brazing alloys, forms of brazing alloys, brazing methods and atmospheres for stainless steel were described.

Medium-range Orders in Amorphous Alloys and Their Role on the Plasticity: A Molecular Dynamics Viewpoint Study (비정질 합금의 중주기배열구조 및 이 구조가 소성에 미치는 역할: 분자동력학적 연구)

  • Lee, Chang-Myeon;Lee, Mirim;Lee, Kwang-Ryeol;Kang, Kyung-Han;Lee, Byeong-Joo;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.101-108
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    • 2010
  • The local structural states of amorphous alloys have been depicted previously via short-range orders (SROs). However, the concept of SROs alone is inadequate and sometimes insufficient to explain the structure-property relation of the amorphous alloys. In this study, we propose new types of medium-range building structures that affect the mechanical properties, plasticity in particular. Using a combination of molecular dynamics simulations and the Voronoi tessellation method, we demonstrate a three-dimensional configuration of icosahedral medium-range orders (I-MROs) and elucidate how these icosahedral orders evolve by the application of shear deformation. It was observed that the structural stability of the icosahedral orders relies largely on how they are linked via percolation and this linking is explained in detail.

Hydrogenation Properties of MgH2-CaO Composites Synthesized by Hydrogen-Induced Mechanical Alloying

  • Kim, Min Gyeom;Han, Jeong-Heum;Lee, Young-Hwan;Son, Jong-Tae;Hong, Tae Whan
    • Korean Journal of Metals and Materials
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    • v.56 no.11
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    • pp.829-834
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    • 2018
  • Although magnesium-based alloys are attractive materials for hydrogen storage applications, their activation properties, hydrogenation/dehydrogenation kinetics, thermodynamic equilibrium parameters, and degradation characteristics must be improved for practical applications. Further, magnesium poses several risks, including explosion hazard, environmental pollution, insufficient formability, and industrial damage. To overcome these problems, CaO-added Mg alloys, also called Eco-Mg (environment-conscious Mg) alloys, have been developed. In this study, $Eco-MgH_x$ composites were fabricated from Mg-CaO chips by hydrogen-induced mechanical alloying in a high-pressure atmosphere. The balls-to-chips mass ratio (BCR) was varied between a low and high value. The particles obtained were characterized by X-ray diffraction (XRD), and the absorbed hydrogen was quantified by thermogravimetric analysis. The XRD results revealed that the $MgH_2$ peaks broadened for the high BCR. Further, PSA results revealed particles size were decreased from $52{\mu}m$ to $15{\mu}m$.

Evaluation on Resistance to Pitting Corrosion of Fe-Cr Alloys via Measurement of the Critical Pitting Temperature (CPT) and Potentiodynamic Polarization According to KS D 0238 (wet, dry), ASTM G 61 and ISO 17475 Standards (Fe-Cr합금의 공식저항성 평가를 위하여 다양한 규격(KS D 0238, ASTM G 61, ISO 17475)에 따라 실시한 동전위 분극 시험과 임계공식온도 측정시험)

  • Kang, Su-Yeon;Lee, Jae-Bong;Kim, Yeong-Ho
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.635-643
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    • 2009
  • The resistance to pitting corrosion of Fe-Cr alloys was evaluated by performing potentiodynamic polarization and critical pitting temperature (CPT) tests. For the potentiodynamic polarization tests, various standards were applied, i.e., KS D 0238 (wet, dry), ASTM G 61, and ISO 17475, showing different potentiodynamic polarization results including pitting potentials. ASTM G 61 and ISO 17475 standards presented relatively higher pitting potential while KS D 0238 (dry) indicated lower values than the others. Effects of surface roughness, scan rates, and exposure time to air before tests were also investigated. CPT tests were performed under two different applied potentials, 300 m$V_{SCE}$ and 200 m$V_{SCE}$ in deaerated 1 M NaCl aqueous solution. CPT values and the polarization test results showed a linear relationship.