• 제목/요약/키워드: Metal composite

검색결과 1,297건 처리시간 0.028초

PVdF-HFP/TiO2 나노복합체 보호층을 통한 리튬금속전지 음극의 전기화학적 성능 향상 (Nanostructured PVdF-HFP/TiO2 Composite as Protective Layer on Lithium Metal Battery Anode with Enhanced Electrochemical Performance)

  • 이상현;최상석;김동언;현준혁;박용욱;유진성;전소윤;박중원;신원호;손희상
    • 멤브레인
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    • 제31권6호
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    • pp.417-425
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    • 2021
  • 고용량 배터리에 대한 요구가 증가에 따라 기존 음극재보다 높은 용량(3,860 mAh/g)과 낮은 전기화학적 전위(-3.040 V)를 갖는 리튬 금속 기반 음극재에 대한 연구가 활발하게 이루어지고 있다. 본 연구에서는 수열 합성을 통해 제작된 아나타제(anatase) 타입의 TiO2 나노 입자 기반한 PVdF-HFP/TiO2 복합체를 리튬 금속 음극의 계면 보호층으로 적용하였다. 결정구조 및 형상 분석을 통해 유/무기-리튬 나노복합체 박막의 형성을 확인하였다. 또한, 전지화학 테스트(사이클 테스트 및 전압 프로파일)를 통해 리튬 금속 음극의 전기화학 성능 은 복합체 보호막이 TiO2 10 wt%, 코팅 두께 1.1 ㎛의 조건에서 가장 개선된 전기화학적 성능(콜롱 효율 유지: 77 사이클 동안 90% 이상) 발현을 확인하였다. 이를 통해, 처리하지 않은 리튬 전극 대비 본 보호층에 의한 리튬 금속 음극의 성능 안정화/개선 효과가 검증되었다.

Development of Porous Metal Materials and Applications

  • Fang, Y.;Wang, H.;Zhou, Y.;Kuang, C.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.599-600
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    • 2006
  • This paper described the state of art of porous metal materials, the typical manufacturing technologies and performances of sintered metal porous materials, with emphasis on the recent research achievements of CISRI in development of porous metal materials. High performance porous metal materials, such as metallic membrane, sub-micron asymmetric composite porous metal, large dimensional and structure complicated porous metal aeration cones and tube, metallic catalytic filter elements, lotus-type porous materials, etc, have been developed. Their applications in energy industry, petrochemical industry, clean coal process and other industrial fields were introduced and discussed.

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이산화탄소 분리를 위한 이온성 액체 기반 복합 멤브레인: 총설 (Ionic Liquid Consisted of Composite Membrane for Carbon Dioxide Separation: A Review)

  • 영 사이먼 시 영;라즈쿠마 파텔
    • 멤브레인
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    • 제33권5호
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    • pp.240-247
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    • 2023
  • 가스 분리 방법 중에서도, 멤브레인을 이용한 CO2 포집 및 분리는 지속적으로 개발되고 있는 꾸준히 성장하는 분야이다. 이온성 액체(IL) 기반 복합 막은 CO2를 분리하는 데 있어 우수한 성능값을 보여준다. 유사하게, 다양한 공중합체/IL 복합막 또한 향상된 성능을 보여준다. 이러한 공중합체/IL 복합만에 산화그래핀과 같은 필러를 첨가하면 IL과 유기 필러 사이에서 발생하는 강한 상호작용으로 인해 필러의 효과가 더욱 향상되며, 이는 결과적으로 CO2의 친화도, 선택도 및 흡착과 같은 요소를 향상시킨다. 금속-유기 구조체(MOF)를 사용하는 공중합체/IL 복합 막은 향상된 CO2 투과도를 보여주었다. 이 총설에서는 이온성 액체와 공중합체복합막의 다양한 조합에 따른 이산화탄소분리성능에 대한 상관관계를 논의한다.

Properties of Graded Open-celled Metal Foams

  • Adler, J.;Kummel, K.;Quadbeck, P.;Standke, G.;Stephani, G.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.601-601
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    • 2006
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Synthesis and Properties of Open-celled Metal Foams

  • Adler, J.;Kummel, K.;Quadbeck, P.;Standke, G.;Stephani, G.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.103-103
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    • 2006
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전기방사를 이용한 슈퍼캐퍼시터용 금속산화물/탄소나노섬유 복합체 (Electrospun Metal Oxide/Carbon Nanofiber Composite Electrode for Supercapacitor Application)

  • 양갑승;김보혜
    • 공업화학
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    • 제26권3호
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    • pp.239-246
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    • 2015
  • 나노 탄소재료를 복합화하면 기존 재료의 특성을 유지하면서 그 효율을 극대화할 수 있다. 여기에 이종원소를 부가하면 전기화학적인 특성이 디자인되므로, 나노 탄소재료의 복합화를 통해 한 종류의 나노 재료로부터 여러 강점을 얻을 수 있다. 특히 탄소나노섬유와 금속산화물을 복합화하면 탄소나노섬유의 전기이중층 뿐만 아니라 금속산화물의 산화 환원 반응을 이용하여 비축전 용량, 고율 특성, 수명 특성이 향상되고 높은 수준의 출력밀도가 유지되는 고용량 슈퍼 캐퍼시터용 전극 소재를 개발할 수 있다. 본 총설에서는 탄소의 고출력특성과 금속산화물의 고에너지 특성이 동시에 발현되는 금속산화물계 탄소나노섬유복합체의 제법과 응용에 대한 최신연구를 다루도록 하겠다.

자기 강화형 폴리프로필렌을 이용한 섬유 금속 적층판의 성형성에 관한 수치해석적 연구 (Numerical Study of the Formability of Fiber Metal Laminates Based on Self-reinforced Polypropylene)

  • 이병언;김정;강범수;송우진
    • 소성∙가공
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    • 제22권3호
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    • pp.150-157
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    • 2013
  • Fiber metal laminates (FMLs) are layered materials comprised of thin metal sheets and fiber reinforced plastic (FRP). This paper presents the numerical study of the formability enhancement of FMLs composed of an aluminum alloy and self-reinforced polypropylene (SRPP) composite. In this study, a numerical simulation based on finite element (FE) modeling is proposed to evaluate the formability of FMLs using ABAQUS/Explicit. The FE model, which included a single layer of solid and shell elements to model the blank, used discrete layers of the solid element with a contact model and shell elements with a friction based model for the aluminum alloy-composite interface conditions. This method allowed the description of each layer of FMLs and was able to simulate the interaction between the layers. It is noted through this research that the proposed numerical simulation described properly the formability enhancement of the FMLs and the simulation results showed good agreement with experimental results.

풍차형 초음파 선형 모터의 양방향 운동 (Bidirectional Motion of the Windmill Type Ultrasonic Linear Motor)

  • 이재형;박태곤;정영호
    • 한국전기전자재료학회논문지
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    • 제16권6호
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    • pp.484-489
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    • 2003
  • In this paper, a single phase driven piezoelectric motor design was presented for linear motion Two metal/ceramic composite actuators, a piezoelectric ring which was bonded to a metal endcap from one side, were used as the active elements of this motor. The motor was composed of a piezoelectric ceramic, a metal ring which has 4 arms, and a guider. Motors with 30 [mm] and 35 [mm] diameter were studied by finite element analysis and experiments. As results, the maximum speed of motor was obtained at resonance frequency. When the applied voltage of the motor increased, the speed was increased. Also, bidirectional motion of the motor was achieved by combining two motors which have different resonance frequency. But the characteristics of bidirectional motion were not equaled, because of the problem of reproduction on the fabrication and the experiment. If present motor is used at the auto-zoom device of a camera, it will have much advantage. Because the direct linear motion can be achieved with a simple structure of motor and no gearbox of total system.

Realistic adsorption behaviors of the copper onto the functionalized CNTs

  • 박미나;김병현;이광렬
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.476-476
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    • 2011
  • Introduction of CNTs into a metal matrix has been considered to improve the mechanical properties of the metal matrix. However, the binding energy between metals and pristine CNTs wall is known to be so small that the interfacial slip between CNTs and the matrix occurs at a relatively low external stress. The interfacial strength between CNT and metal matrix is thus one of the key factors for successful development of the CNT/metal composites. Defective or functionalized CNT has been considered to enhance the interfacial strength of nanocomposites. In the present work, we design the various realistic hybrid structures of the single wall CNT/Cu complexes and characterize the interaction between single wall CNTs and Cu nano-particle and Cu13 cluster using first principle calculations. The characteristics of functionalized CNTs with various surface functional groups, such as -COOH, -OH, and -O interacting with Cu are investigated. We found that the binding energy can be enhanced by the surface functional group including oxygen since the oxygen atom can mediate and reinforce the interaction between carbon and Cu. These results strongly support the recent experimental work which suggested the oxygen on the interface playing an important role in the excellent mechanical properties of the CNT/Cu composite.

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Development of Alkali Metal Thermal-to-Electric Converter Unit Cells Using Mo/TiN Electrode

  • Seog, Seung-won;Choi, Hyun-Jong;Kim, Sun-Dong;Lee, Wook-Hyun;Woo, Sang-Kuk;Han, Moon-Hee
    • 한국세라믹학회지
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    • 제54권3호
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    • pp.200-204
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    • 2017
  • Molybdenum (Mo), an electrode material of alkali metal thermal-to-electric converters (AMTEC), facilitates grain growth behavior and forms Mo-Na-O compounds at high operating temperatures, resulting in reduced performance and shortened lifetime of the cell. Mo/TiN composite materials have been developed to provide a solution for such issues. Mo is a metal that possesses excellent electrical properties, and TiN is a ceramic compound with high-temperature durability and catalytic activity. In this study, a dip-coating process with an organic solvent-based slurry was used as an optimal coating method to achieve homogeneity and stability of the electrodes. Cell performance was evaluated under various conditions such as the number of coatings, ranging from 1 to 3 times, and heat treatment temperatures of $800-1100^{\circ}C$. The results confirmed that the cell yielded a maximum power of 9.99 W for the sample coated 3 times and heat-treated at $900^{\circ}C$.