• 대한환경공학회지
• /
• 제39권4호
• /
• pp.180-185
• /
• 2017

안료 페인트 생산 업체 7개를 방문하여 제품 21개(안료 17개, 페인트 4개)를 시료채취 하였으며, 대형 온라인 판매상을 통하여 50개 제품을 구매하였다. 총 71개 제품에 대하여 EPA 7473 방법으로 수은 함량분석을 하였고, 물질흐름 분석을 위한 폐기물 내 수은함량은 타 연구(2010)의 안료 페인트 제조 업체에서 발생되는 분진 슬러지 폐페인트 38건의 수은 함량 자료를 사용하였다. 물질흐름분석은 제품 또는 특정 화학물질을 대상으로 하는 Micro 수준의 물질흐름 추적방식을 이용하여 흐름도를 작성하였다. 수은분석 결과, 71개 제품에서 0~0.25 mg-Hg/kg, 38개 폐기물에서 0.23~0.69 mg-Hg/kg으로 나타났다. 물질흐름을 살펴보면 유통단계의 수은흐름량이 연간 10.06 kg인데 반해 폐기되는 수은의 양은 25.27 kg으로 유통량 보다 폐기량이 더 높게 나타났다. 이는 제품과 폐기물의 시료채취 시기가 달라 발생된 현상으로 제품은 2014년도 제품, 폐기물은 2010년 분석된 자료를 사용하여 RoHS 등과 같은 규제의 영향으로 수은 함유 페인트 제품이 감소됨에 따른 것으로 판단된다. 현재 생산되는 제품 중 수은의 농도는 매우 낮고 페인트에 의한 수은의 유출은 미미한 것으로 판단된다.

• Asian Journal of Atmospheric Environment
• /
• 제12권1호
• /
• pp.37-46
• /
• 2018

The Minamata Convention on Mercury entered into force on August 16, 2017. It requires Parties to the Convention to control and, where feasible, reduce mercury emissions from the listed sources. To implement the Convention, Japan amended the Air Pollution Control Law and added clauses that force operators to control their mercury emissions below emission limit values (ELVs). The ELVs have been established separately for new and existing sources, targeting the source categories listed in the Convention: coal-fired boilers, smelting and roasting processes used in the production of non-ferrous metals (lead, zinc, copper and industrial gold), waste incineration facilities and cement clinker production facilities. The factors used to establish the ELVs include the present state of mercury emissions from the targeted categories as well as the mercury content in fuels and materials, best available techniques (BATs) and best environmental practices (BEPs) to control and reduce mercury emissions and ELVs or equivalent standards to control mercury emissions in other countries. In this regard, extensive data on mercury emissions from flue gas and the mercury content of fuels and materials were collected and analyzed. The established ELVs range from $8{\mu}g/Nm^3$ for new coal-fired boilers to $400{\mu}g/Nm^3$ for existing secondary smelting processes used in the production of copper, lead and zinc. This paper illustrates the ELVs for the targeted source categories, explaining the rationales and approaches used to set the values. The amended Law is to be enforced on April 1, 2018. From future perspectives, checks of the material flow of mercury, following up on the state of compliance, review of the ELVs and of the measurement and monitoring methods have been noted as important issues.

• Bulletin of the Korean Chemical Society
• /
• 제24권10호
• /
• pp.1433-1436
• /
• 2003

A new method for the simultaneous determination of heavy metal ions in cigarette material by microwave digestion and reversed-phase high-performance liquid chromatography (RP-HPLC) has been developed. The cigarette material was digested by microwave digestion. Lead, cadmium, mercury, nickel and tin ions in the digested samples were pre-column derivatized with tetra-(2-chlorophenyl)-porphyrin ($T_2$-CPP) to form color chelates, which were then enriched by solid phase extraction with a $C_{18}$ cartridge. The chelates were separated on a Waters Xterra$^{TM}RP_{18}$ column by gradient elution with methanol (containing 0.05 mol/L pyrrolidine-aceticacid buffer salt, pH = 10.0) and acetone (containin0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0)as mobile phase at a flow rate of 0.5mL/min and analyzed with a photodiode array detector from 350-600 nm. The detection limits of lead, cadmium, mercury, nickel and tin were 4,3,3,8 and 5 ng/L, respectively, in the original samples. This method was afforded good results.

• Mass Spectrometry Letters
• /
• 제3권2호
• /
• pp.58-61
• /
• 2012

A method based on flow injection-isotope dilution-cold vapor-inductively coupled plasma mass spectrometry (FI-IDCV-ICP/MS) has been applied to determine trace level of mercury in fly ash. $^{200}Hg$ isotopic spike was added to 0.25 g of BCR176R fly ash and then decomposed by microwave digestion procedure with acid mixture A (8 mL $HNO_3$ + 2 mL HCl + 2 mL HF) and acid mixture B (8 mL $HNO_3$ + 2 mL $HClO_4$ + 2 mL HF) for applying IDMS. Mercury cold vapor was generated by using reductant solution of 0.2% (w/w) $NaBH_4$ and 0.05% (w/w) NaOH. The measurements of n($^{200}Hg$)/n($^{202}Hg$) isotope ratio was made using a quadrupole ICP/MS system. The accuracy in this method was verified by the analysis of certified reference material (CRM) of fly ash (BCR 176R). The indicative value of Hg in BCR 176R fly ash was $1.60{\pm}0.23$ mg/kg (k = 2). The determined values of Hg in BCR 176R fly ash by the method of FI-CV-ID-ICP/MS described in this paper were $1.60{\pm}0.24$ mg/kg (k = 3.18) and the analysis results were in well agreement with the indicative value within the range of uncertainty.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
• /
• pp.3-9
• /
• 2002

Paper sludge ash was assured as material of a sort of pozzolan. For the reason of fluidity decrease caused by the strong absorption of paper stooge ash and the decrease of compressive strength in case of using over30% replacement by the weight of cement, paper sludge ash is not suitable for blending material. Therefore, it is necessary to find proper replacement ratios between paper sludge and blast furnace slag to insure compressive compensation and appropriate slump. Accordingly, as varied the blending ratios of paper sludge and blast furnace slag, testing mortar was made. This study was aimed to investigate the possibility of using blending replacement of paper sludge ash and blast furnace slag throughout compressive test, flow test, SEM(Scanning Eletron Microscope), MIP(Mercury Intrusion Porosity test), and TG-DTA(Thermal analysis).

• Transactions on Electrical and Electronic Materials
• /
• 제17권5호
• /
• pp.252-256
• /
• 2016

This paper deals the study of a linear MHD pump solution used to eliminate and to avoid the dangers of the mercury appearing through pollution and contamination. The formulation of the magnetohydrodynamic phenomena is derived from Maxwell and Navier-Stokes equations are solved using the finite volume method. Simulation results highlight the performance of the pump such as the electromagnetic force, the velocity, and the pressure, the application of Ansys-Fluent software validation these results.

• 한국세라믹학회지
• /
• 제53권5호
• /
• pp.548-556
• /
• 2016

Recently, porous alumina-based ceramics have been extensively applied in the semi-conductor and display industries, because of their high mechanical strength, high chemical resistance, and high thermal resistance. However, the high electrical resistance of alumina-based ceramics has a negative effect in many applications due to the generation of static electricity. The low electrical resistance and high air permeability are key aspects in using porous alumina-based ceramics as vacuum chucks in the semi-conductor industry. In this study, we tailored the pore structure of porous alumina-based ceramics by adjusting the mixing ratio of the starting alumina, which has different particle sizes. And the electrical resistance was controlled by using chemical additives. The characteristics of the specimens were studied using scanning electron microscopy, mercury porosimetry, capillary flow porosimetry, a universal testing machine, X-ray diffraction, and a high-resistance meter.

• 한국세라믹학회지
• /
• 제54권4호
• /
• pp.331-339
• /
• 2017

Porous alumina-based ceramics are of special interest due to their outstanding mechanical properties and their thermal and chemical stability. Nevertheless, the high electrical resistance of alumina-based ceramics, due to the generation of static electricity, leads to difficulty in applying a vacuum chuck in the semi-conductor process. Therefore, development of alumina-based ceramics for applications with vacuum chucks aims to have primary properties of low electrical resistance and high air permeability. In this study, we tailored the electrical resistance of porous alumina-based ceramics by adjusting the amount of $MnO_2$ (with $TiO_2$ fixed at an amount of 2 wt%) and by using coarse alumina powder for high air permeability. The characteristics of the specimens were studied using scanning electron microscopy, mercury porosimeter, capillary flow porosimetry, universal testing machine, X-ray diffraction and high-resistance meter.

• 헤리티지:역사와 과학
• /
• 제55권2호
• /
• pp.6-21
• /
• 2022

본고는 귀이개라는 특정 공예품이 시대의 흐름에 따라 변화하는 양상을 통해 당대의 물질문화에 주목하고자 하였다. 2장에서 귀이개에 관한 용어 정리를 하고, 조선후기 단편적인 문헌을 통해 귀이개의 사용 문화를 살펴보았다. 귀이개는 첫 번째로 개인의 수신을 위한 위생도구였고, 두 번째로 남성들의 선추에 다는 구성품으로 상징적인 역할을 하였다. 3장에서는 시대별로 귀이개의 형태를 분류하고, 각 형태별 특징적인 장식기법을 살펴보았다. 고려시대 귀이개는 사용목적이 위생도구였으며, 형태에 따라 단독형, 복합형으로 구분된다. 단독형에는 각봉형, 손잡이형, 판형이 있으며, 복합형에는 족집게일체형, 리벳분리형이 있다. 손잡이형 귀이개에서 고려시대의 장식기법을 살펴볼 수 있었다. 선각, 금도금, 바탕에 누정기법으로 찍은 첩호(疊弧)문, 납입사로 화려하게 장식되었다. 조선시대 귀이개는 사용목적에 따라 위생도구와 장신구로 크게 분류된다. 위생도구는 단독형, 복합형으로 나뉘고, 장신구로 사용되는 귀이개 종류로는 뒤꽂이, 노리개, 선추 등이 있다. 귀이개 장신구는 성별에 따라 여성은 뒤꽂이, 노리개로, 남성은 선추로 사용되었다. 조선시대 귀이개의 장식기법은 주로 귀이개 뒤꽂이에서 볼 수 있었다. 칠보기법으로 다양한 색을 내거나 보석감장으로 장식하였다. 그동안 공예품 중 일상도구에 관한 연구가 미진하였다. 일상도구를 통해 시대의 흐름을 읽고 물질문화에 접근하려는 시도가 활발하게 이루어지길 바란다.