• 공업화학
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• 제9권7호
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• pp.1047-1052
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• 1998

본 연구에서는 시판용 99.8% 금속알루미늄을 정전류 방식을 이용하여 황산, 수산, 인산 및 크롬산 전해조에서 양극산화를 행하여 다공성 알루미나 막을 제조하였다. 양극산화시 전해액의 종류에 따른 반응온도, 전해액의 농도 및 전류밀도에 따라 형성되는 다공성 알루미나 막의 세공직경과 분포, 막의 두께 및 형태와 결정구조를 조사함으로서 각 전해질 용액하에서의 최적 반응조건을 결정하고 우수한 다공성 알루미나 막을 제조하고자 하였다. 황산, 수산전해질하에서는 한외여과(Ultrafiltration)막이, 인산, 크롬산전해질하에서는 정밀여과(Microfiltration)막의 얻어짐을 알수 있었다. 황산, 수산 및 인산 전해조에서 제조된 막의 결정구조는 무정형임을 알 수 있으며, 크롬산 전해조에서 제조된 막은 ${\gamma}-Al_2O_3$의 결정구조를 보이고 있다.

• Membrane and Water Treatment
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• 제6권3호
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• pp.205-224
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• 2015

A novel hydrophilic poly (vinylidene fluoride)/poly (p-phenylene terephthalamide) (PVDF/PPTA) blend membrane was prepared by in situ polycondensation of p-phenylene diamine (PPD) and terephthaloyl chloride (TPC) in PVDF solution with subsequent nonsolvent induced phase separation (NIPS) process. For comparison, conventional solution blend membrane was prepared directly by adding PVDF powder into PPTA polycondensation solution. Blend membranes were characterized by means of viscometry, X-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM). The effects of different blending methods on membrane performance including water contact angle (WCA), mechanical strength, anti-fouling and anti-compression properties were investigated and compared. Stronger interactions between PVDF and PPTA in in situ blend membranes were verified by viscosity and XPS analysis. The incorporation of PPTA accelerated the demixing rate and caused the formation of a more porous structure in blend membranes. In situ blend membranes exhibited better hydrophilicity and higher tensile strength. The optimal values of WCA and tensile strength were $65^{\circ}$ and 34.1 MPa, which were reduced by 26.1% and increased by 26.3% compared with pure PVDF membrane. Additionally, antifouling properties of in situ blend membranes were greatly improved than pure PVDF membrane with an increasing of flux recovery ratio by 25%. Excellent anti-compression properties were obtained in in situ blend membranes with a stable pore morphology. The correlations among membrane formation mechanism, structure and performance were also discussed.

• Bulletin of the Korean Chemical Society
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• 제27권3호
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• pp.386-388
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• 2006

Membrane proteins in highly oriented lipid bilayer samples are useful for membrane protein structure determination. We used in the past planar lipid bilayers which were aligned and supported on the glass slide. These samples were mechanically aligned in a magnetic field. However, these stacks of glass slides with planar lipid bilayers are not well suited for use with a commercial solid-state NMR probe with a round coil. Therefore, a homebuilt solid-state NMR probe was built and used with a stack of thin glass plates wherein the RF coil was wrapped directly around the flat square sample. Recently, we began to use magnetically aligned bicelles that are suitable for the structure determination of membrane proteins by solid-state NMR spectroscopy without any effort to build a flat square coil probe. These bicelle samples are well suited for use with a commercial solidstate NMR probe with a round coil, are very easy to prepare and are very stable, so that they can be kept for more than a year. In this paper, we present the solid-state NMR spectra of optimized and magnetically oriented bicelle samples of membrane proteins.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1999년도 봄 학술발표회 논문집
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• pp.268-275
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• 1999

The purpose of this study is to propose the method of determining the initial pneumatic membrane structures surface and stresses and displacements. Tension structure such as pneumatic membrane structures is stabilized by their initial prestress and air pressure. The process to find initial structural overall shape of tension structures produced by initial prestress called shape finding. One of the most important factor for the design of membrane structures is to search initial smooth surface, because unlike steel or concrete building elements which resist loads in bending, all tension structure forces are carried within the surface by membrane stress. The result for initial surface of pneumatic membrane element and maximum displacement in large deformation in analysis is compared with well-known nonlinear numerical method such as Newton-raphson method and dynamic relaxation method

• 한국공간구조학회논문집
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• 제14권3호
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• pp.67-74
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• 2014

The author has proposed and verified the accuracy through experiments on a method of measurement through the use of sound waves that not only can quantitatively measure each of the dual directions of the fiber axis with high accuracy of membrane tension created on the surface of the membrane structure, but also can be easily operated in the field of construction. This paper reports the solution for problems of variables caused in the process of downsizing of the measurement equipment in order for practical use, and verifies the correspondence possibility of various stress ratios.

• Korean Membrane Journal
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• 제10권1호
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• pp.1-7
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• 2008

Polystyrene-co-divinylbenzene (PS-co-DVB) asymmetric membranes were prepared. In order to control their structure and mechanical properties the degree of cross-linking and the composition of casting solution were varied. The rubber added PS-DVB membranes was also prepared to overcome the mechanical limitation of cross-linked membrane, and their mechanical properties were investigated. It was revealed that the concentration of polymer in the casting solution affected the determination of skin formation. When the PS-co-DVB membrane consists of styrene-butadiene (SB) rubber or liquid polybutadiene (PBD), the structures formed showed that the PS content in the PS/DVB system played an important role in determining the porous sublayer structure.

• 한국공간구조학회:학술대회논문집
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• 한국공간구조학회 2008년도 춘계 학술발표회 논문집
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• pp.19-24
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• 2008

본 논문은 풍동실험과 정적하중 실험을 실시하여 강풍 설계시 대공간 구조물의 막구조 동적응답을 확인하여 거스트 계수(gust factor)를 산출해 보고자한다. 이를 위해 섬유재료의 변형률에 따라 하중을 구할 수 있는 막재료 성능실험과 4가지(saddle형, wave형, arch형, point형) 막구조 모형에 따른 횡방향 동적하중과 동적변형응답을 측정할 수 있는 풍동실험, 동적변형응답에 따라 정적하중을 구할 수 있는 정적하중실험을 실시함으로써 거스트 계수(gust factor)를 산출하였다.

• 대한조선학회논문집
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• 제54권5호
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• pp.361-367
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• 2017

A membrane type LNG cargo tank is equipped with a pump tower and a liquid dome for loading and unloading of LNG. However, the membrane running continuously on the tank wall to prevent leakage of LNG is interrupted by the liquid dome, hence care should be taken in the design of liquid dome and its substructures. In case of GTT NO96 membrane type cargo containment system, chair structure is arranged along the periphery of the liquid dome targeting to support the membrane which is exposed to the both hull girder and thermal load. This paper proposes a new and simple chair structure, which outperforms traditional design from productivity point of view maintaining same level of structural safety. Strength assessment on the new design was performed to guarantee the structural safety of the new design, which includes strength, fatigue and crack propagation analysis.

• 한국해양공학회지
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• 제31권2호
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• pp.91-102
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• 2017

Recently, a new type of LNG membrane Tank called the "KC-1 membrane LNG Tank" was developed by KOGAS (Korean Gas Corporation). It is necessary to estimate the temperature distribution of the hull structure and insulation system for this new LNG tank, as well as the BOR (Boil-Off Rate) when exposed to outside temperature conditions to ensure the integrity of the tank structure and limit LNG evaporation, from a safety evaluation point of view. In this study, temperature distribution calculations for the hull structure and insulation system of the KC1 membrane tank were compared by employing four numerical approaches under the IGC condition. Approaches 1-3 studied 2D simulations and approach 4 used a 3D numerical simulation. Approach 1 was calculated by in-house Excel VBA codes and the three other approaches utilized ANSYS Fluent. The BOR of approach 4, the 3D simulation case, for the IGC condition was 0.0986%/day.

• 한국막학회:학술대회논문집
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• 한국막학회 1999년도 추계 총회 및 학술발표회
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• pp.33-36
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• 1999