• Title/Summary/Keyword: Melting temperature

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Water Gas Shift Reaction Research of the Synthesis Gas for a Hydrogen Yield Increase (수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구)

  • Kim, Min-Kyung;Kim, Jae-Ho;Kim, Woo-Hyun;Lee, See-Hoon
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.9-14
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    • 2009
  • Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

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Melting Characteristics of Asbestos Cement Slate on Basicity Control (염기도 조절에 의한 석면슬레이트 용융특성)

  • Yun, Jinhan;Keel, Sangin;Min, Taijin;Lee, Chungkyu;Jang, Duhun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.159.2-159.2
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    • 2010
  • Asbestos is the collective name for a group of naturally occurring minerals in their fibrous form and hydrous silicates of magnesium and a mineral fiber that has been used commonly in a variety of building construction materials for insulation and as a fire-retardant. Asbestos has been used for a wide range of manufactured goods, because of its fiber strength and heat resistant properties. Nevertheless harmful of asbestos is quite serious. Exposure to airborne friable asbestos may result in a potential health risk because persons breathing the air may breathe in asbestos fibers. Continued exposure can increase the amount of fibers that remain in the lung. Fibers embedded in lung tissue over time may cause serious lung diseases including asbestosis, lung cancer. In this paper, we carried out as fundamental study for dispose of asbestos cement slate safely and perfectly. Melting Temperature of asbestos need to more than $1,520^{\circ}C$ and specially asbestos cement slate need more energy than that of pure asbestos. We need to decrease melting temperature of asbestos cement slate for economical efficiency. To the purpose, glass and bottom ash were chosen as additives for basicity control. we analyzed about properties of asbestos cements slate, melting characteristics on the additives ratio and temperature. We confirmed about harmlessness of melting slag through analysis of scanning electron microscope(SEM) and x-ray diffractometer(XRD).

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The Melting Process in an Ice-Ball Capsule (아이스볼내의 융해과정에 대한 해석)

  • Suh, J.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.4
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    • pp.577-588
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    • 1995
  • A numerical study is made on the melting process of an unconstrained ice inside an isothermal ice-ball capsule. The unmelted ice core is continuously ascending on account of buoyancy forces. Such a buoyancy-assisted melting is commonly characterized by the existence of a thin liquid film above the ice core. The present study is motivated to present a full-equation-based analysis of the influences of the initial subcooling and the natural convection on the fluid flow associated with the buoyancy-assisted melting. In the light of the solution strategy, the present study is substantially distinguished from the existing works in that the complete set of governing equations in both the melted and unmelted regions are resolved in one domain. Numerical results are obtained by varying the wall temperature and initial temperature. The present results reported the transition of the flow pattern in a spherical capsule, as the wall temperature was increased over the density inversion point. In addition, time wise variation of the shapes for the liquid film and the lower ice surface, the time rate of change in the melt volume fraction and the melting distance at symmetric line is analyzed and is presented.

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Calculating the Threshold Energy of the Pulsed Laser Sintering of Silver and Copper Nanoparticles

  • Lee, Changmin;Hahn, Jae W.
    • Journal of the Optical Society of Korea
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    • v.20 no.5
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    • pp.601-606
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    • 2016
  • In this study, in order to analyze the low-temperature sintering process of silver and copper nanoparticles, we calculate their melting temperatures and surface melting temperatures with respect to particle size. For this calculation, we introduce the concept of mean-squared displacement of the atom proposed by Shi (1994). Using a parameter defined by the vibrational component of melting entropy, we readily obtained the surface and bulk melting temperatures of copper and silver nanoparticles. We also calculated the absorption cross-section of nanoparticles for variation in the wavelength of light. By using the calculated absorption cross-section of the nanoparticles at the melting temperature, we obtained the laser threshold energy for the sintering process with respect to particle size and wavelength of laser. We found that the absorption cross-section of silver nanoparticles has a resonant peak at a wavelength of close to 350 nm, yielding the lowest threshold energy. We calculated the intensity distribution around the nanoparticles using the finite-difference time-domain method and confirmed the resonant excitation of silver nanoparticles near the wavelength of the resonant peak.

Heat Transfer Characteristics for Inward Melting in a Paraffin-Filled Vertical Cylinder (파라핀을 채운 수직원관 내에서의 열전달 특성)

  • Yum, Sung-Bae;Hong, Chang-Shik
    • Solar Energy
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    • v.12 no.3
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    • pp.60-69
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    • 1992
  • Heat transfer characteristics and heat storage rate for vertical cylinder packed with paraffin as a latent heat storage material were theoretically studied. Conduction and convection mechanism were applied to the solid and liquid phase, respectively, and the results were compared with that of pure conduction model. The effects of heating temperature, initial solid temperature and aspect ratio on rate of storage were also studied. In the initial stage of melting, the natural convection is nearly restricted by the friction at the wall and the phase boundary. But it is generated when about 40% of solid melts and again it shrinks by the hot liquid situated on the upper part of the cylinder. So overall melting rate is higher then that for pure conduction model. The increase in heating temperature and aspect ratio activates the natural convection, so melting rate becomes higher. And the larger the aspect ratio, the greater the difference between upper and lower size of the solid. In the initial stage of melting, the initial temperature of solid paraffin has great effect on the melting rate, but as melting proceeds its effect lessens gradually.

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The Effect of the Injection Molding Conditions of Plastics on the Stress Relaxation (플라스틱의 사출성형조건이 응력완화에 미치는 영향)

  • 정석주;황봉갑
    • Journal of the Korean Society of Safety
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    • v.13 no.1
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    • pp.19-25
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    • 1998
  • In this study, proper injection molding condition has been studied through stress relaxation tests in order to experimentally investigate the effect of the condition on softening of mold product, using specimens produced under the different conditions according to the recommendation of resin manufactures. As a result, softening of the specimens was found to be strongly influenced by material melting temperature. The specimen with higher material melting temperature is found to have lower softening. However, softening of the specimen with lower mold temperature has an decrement, compared with other specimens. In particular, specimen with notch is influenced by mold temperature. The softening increase with higher injection speed and pressure. Finally in order to improve softening, material melting temperature, injection speed and injection pressure were found to be increased with low mold temperature.

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Frozen and Melting Characteristics of Urea-aqueous Solution for Urea-SCR System by Circulation of Engine Coolant (엔진 냉각수 순환에 의한 urea-SCR 시스템용 요소수의 동결 및 해동 특성)

  • Choi, B.C.;Kim, Y.K.;Kim, H.N.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.42-47
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    • 2011
  • The purpose of this study is to investigate the best melting condition with various winding number of a heating pipe, supplying quantity of engine coolant and coolant temperature at the inlet of the heating pipe. Also, it is to suggest getting method of an appropriate quantity of the agent for the urea-SCR system within 10 minutes. For this matter, this study identifies the temperature distribution of inside of urea-tank while it is frozen at the low temperature condition, and suggests the best melting condition of the frozen urea within 10 minutes. From the results, it was found that 2L of melted urea was obtained by the coolant flow rate of 200L/hr at $70^{\circ}C$ for 10 minutes from the start of engine operating.

Preparation of Zone-melted NdBaCuO under Low Oxygen Pressure

  • Soh, Dea-Wha;Fan, Zhan-Guo;Gao, Wei-Ying;Jeon, Jong-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.85-88
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    • 2001
  • The NdBaCuO superconductor samples were Zone-melted in low oxygen partial pressure (1% $O_{2}+ 99% Ar$ ). The Zone-melting temperature was decreased about $120^{\circ}C$ from $1060^{\circ}C$ the zone-melting temperature in air. Thus the loss of liquid phase ($BaCuO_{2}$ and CuO) was reduced during the zone-melting process. The content of non-superconducting phase Nd422 in zone-melted NdBaCuO samples was clearly decreased, so was the substitution of Nd for Ba. The superconductivity of zone-melted $Nd_{1+x}Ba_{2-x}Cu_{3}O_{y}$ prepared under low oxygen partial pressure was distinctively improved.

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Preparation of Zone-melted NdBaCuO under Low Oxygen Pressure

  • wha, Soh-Dea;guo, Fan-Zhan;ying, Gao-Wei;Jeon Yongwoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.85-88
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    • 2001
  • The NdBaCuO superconductor samples were Zone-melted in low oxygen partial pressure (1% O$_2$+99% Ar). The Zone-melting temperature was decreased about 120$^{\circ}C$ from 1060$^{\circ}C$ the zone-melting temperature in air. Thus the loss of liquid phase (BaCuO$_2$ and CuO) was reduced during the zone-melting process. The content of non-superconducting phase Nd422 in zone-melted NdBaCuO samples was clearly decreased, so was the substitution of Nd for Ba. The superconductivity of zone-melted Nd$\sub$1+x/Ba$\sub$2-x/Cu$_3$O$\sub$y/ prepared under low oxygen partial pressure was distinctively improved.

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An Evaluation and Prediction of Performance of Road Snow-melting System Utilized by Ground Source Heat Pump (지열원히트펌프를 활용한 도로융설시스템의 성능 평가 및 예측)

  • Choi, Deok-In;Hwang, Kwang-Il
    • Journal of the Korean Solar Energy Society
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    • v.32 no.3
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    • pp.138-145
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    • 2012
  • Because of the climate changes and the development of building technologies, the cooling loads have been increased. Among the various renewable energies, geothermal energy is known as very useful and stable energy for heating and cooling of building. This study proposes a road snow-melting system of which heat is supplied from GSHP(Ground source heat pump) in viewpoint of the initial investment and annual running performance, which is also operating as a main facility of heating and cooling for common spaces. The results of this study is as followings. From the site measurement, it is found out that the road surface temperature above the geothermal heating pipe rose up to $5^{\circ}C$, which is the design temperature of road snow-melting, after 2 hours' operation and average COP(Coefficient of performance) was estimated as 3.5. The reliability of CFD has confirmed, because the temperature difference between results of CFD analysis and site measurement is only ${\pm}0.4^{\circ}C$ and the trend of temperature variation is quite similar. CFD analysis on the effect of pavement materials clearly show that more than 2 hours is needed for snow-melting, if the road is paved by ascon or concrete. But the road paved by brick is not reached to $5^{\circ}C$ at all. To evaluate the feasibility of snow-melting system operated by a geothermal circulation which has not GSHP, the surface temperature of concrete-paved road rise up to $0^{\circ}C$ after 2 hour and 40 minutes, and it does never increase to $5^{\circ}C$. And the roads paved by ascon and brick is maintained as below $0^{\circ}C$ after 12 hours geothermal circulation.