• Journal of the Korean Society of Combustion
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• v.16 no.2
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• pp.16-22
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• 2011

It is a challenging task to apply large detailed chemical mechanisms of fuel oxidation in simulation of complex combustion phenomena. There exist a few systematic methodologies to reduce detailed chemical mechanisms to smaller sizes involving less computational load. This research work concerns generation of a skeletal chemical mechanism by a directed relation graph with specified accuracy requirement. Two sequential stages for mechanism reduction are followed in a perfectly stirred reactor(PSR) for high temperature chemistry and to consider the autoignition delay time for low and high temperature chemistry. Reduction was performed for the detailed chemical mechanism of n-heptane consisting of 561 species and 2539 elementary reaction steps. Validation results show acceptable agreement for the autoignition delay time and the PSR calculation in wide parametric ranges of pressure, temperature and equivalence ratio.

• Korean Journal of Metals and Materials
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• v.47 no.3
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• pp.182-187
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• 2009

The molten salt electrolysis is applied to reduce titanium dioxide to titanium metal using calcium chloride as an electrolyte and the reaction mechanism of the reduction process is examined by analyzing the reaction products. The process conditions to obtain titanium metal for $900^{\circ}C$ correspond to 2.9~3.2 V and 24 hours. The reaction products for 2.9 V at $900^{\circ}C$ include irregular-shaped titanium oxides such as $Ti_4O_7$, $Ti_3O_5$ and $Ti_2O_3$ and polyhedral $CaTiO_3$. Using these microstructure analysis, the sequential reaction mechanism for the electrochemical reduction of titanium dioxide to titanium is proposed.

• Advances in environmental research
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• v.1 no.1
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• pp.37-55
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• 2012

Here we show that perchlorate reduction during pitting corrosion of zero-valent titanium (ZVT) is likely caused by dissolved titanium species, especially Ti(II). Several possible mechanisms were suggested based on the literature and were evaluated based on experimental observations. Direct reduction of perchlorate on the bare metal of the ZVT electrode was thermodynamically infeasible due to the high anodic potential that was applied. Other potential mechanisms were considered such as reduction by small ZVT metal particles released from the electrode and direct reduction on the oxide layer of the electrode where potential was sufficiently reduced by a high ohmic potential drop. However, these mechanisms were not supported by experimental results. The most likely mechanism for perchlorate reduction was that during pitting corrosion, in which ZVT is partially oxidized to form dissolved ions such as Ti(II), which diffuse from the electrode surface and react with perchlorate in solution. This mechanism is supported by measurements of the dissolution valence and the molar ratio of ZVT consumed to perchlorate reduced (${\Delta}Ti(0)/{\Delta}ClO_4{^-}$). The results shown in this study demonstrate that ZVT undergoing pitting corrosion has the capability to chemically reduce perchlorate by producing dissolved Ti(II) and therefore, it has the potential to be applied in treatment systems. On the other hand, the results of this research imply that the application of ZVT undergoing pitting corrosion in treatment systems may not be feasible now due to several factors, including material and electricity costs and possible chloride oxidation.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1990.10a
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• pp.163-167
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• 1990

이 논문에서는 기구학적 특성을 고려, 크랭크 축과 프로펠러 축의 비틈 진동 의 주요 발생 Mechanism에 관하여 요약하고, 발생된 진동 및 소음을 감소시 키기 위한 방법을 저자의 연구수행 결과의 일부와 비교한다[1,2].

• Journal of the Korean Chemical Society
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• v.30 no.5
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• pp.409-414
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• 1986

The reduction of $VO_2^+$ ion by ethanol in sulfuric acid leads to the formation of vanadyl sulfate. Spectrophotometric measurements on the solution containing products, vanadyl sulfate, are also reported. Kinetic studies on reduction of $VO_2^+$ by ethanol have been carried out at 35${\circ}C$ and 50${\circ}C$. The reaction mechanism for reduction of $VO_2^+$ is discussed.

• Journal of the Society of Naval Architects of Korea
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• v.41 no.4
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• pp.59-67
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• 2004

Direct numerical simulations of turbulent flows over riblet-mounted surfaces are performed to educe the mechanism of drag reduction by riblets. Numerical simulations are performed for flow fields with R $e_$\tau$/=180. For riblet ridge angle $\alpha$=60$^{\circ}$, two different riblet spacings of $s^+/=20 and 40 are used in this study. The computed drag on the riblet surfaces is in good agreement with existing computational and experimental data. The mean velocity profiles show upward and downward shifts in the log-law for drag-decreasing and drag-increasing cases, respectively Turbulence statistics above the riblets are computed and compared with those above a flat plate. The purpose of this study is in two categories: first, to understand the drag reduction mechanism on riblet surface, second, to verify our own code by comparison of the present results with those from previous studies.udies.

• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.392-397
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• 1995

o-Phenylenediamine (o-PD) was electropolymerized on glassy carbon electrodes under a potential cycling condition. The resulting polymer films mediated electrons for the reduction of molecular oxygen at pH=1.0. It was found from the RDE, RRDE, and cyclic voltammetry experiments that the modified electrodes reduce oxygen to hydrogen peroxide at about 300 mV lower potential than the bare glassy carbon electrode. The polymer film consisted of more than two components. Among those, only one component was active in oxygen reduction, which was formed mainly in the earlier stage of the electropolymerization. 2,3-Diaminophenazine, a cyclic dimer of o-PD, was also active in the oxygen reduction reaction, from which it was suggested that the active polymeric component has a structural unit similar to the cyclic dimer. Finally, the electropolymerization mechanism for the formation of the active and inactive components has been proposed.

• Journal of the Korean Chemical Society
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• v.20 no.1
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• pp.56-58
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• 1976

A new mechanism is proposed for the reduction of nitrobenzene in basic solution that does not involve hydroxylamine as an intermediate. This paper presents evidence that the azoxybenzene is not formed from the hydroxylamine, but formed instead from the dimerization of nitrosobenzene.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.279-281
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• 2012

A short chemical mechanism was developed with the chemical model reduction strategy based on the use of Simulation Error Minimization Connectivity Method(SEM-CM). We examined the accuracy resulting from using this mechanism, as compared with the full mechanism, for premixed flames and auto-ignition of methane-air mixture under high pressures. These comparisons are in good agreement, but it has a little divergence to predict the ignition delay time at high pressure conditions as compared with experiment results.

• Transactions of Materials Processing
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• v.32 no.3
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• pp.129-135
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• 2023

The use of engineering plastic products in internal combustion engine and electric cars to improve stiffness and reduce weight is increasing significantly. Among various lightweight materials, engineering plastics have significant advantages such as cost reduction, improved productivity, and weight reduction. In particular, engineering plastics containing glass fibers are used to enhance stiffness. However, the stiffness of glass fibers can increase or decrease depending on their orientation. Before developing plastic products, optimal designs are determined through injection molding and structural analysis to enhance product reliability. However, reliable analysis of products with variable stiffnesses caused by anisotropy cannot be achieved via the conventional isotropic structural analysis, which does not consider anisotropy. Therefore, based on the previously reported study "the Effect of Impacted Fracture in Glass Fiber Orientation with Injection Molding & Structural Coupled Analysis," this study aims to investigate the structural analysis and degradation mechanisms of various polymers. In particular, this study elucidates the actual mechanism of plastic fracture by analyzing various fracture conditions and their corresponding simulations. Furthermore, the objective of this study is to apply the injection molding and structural coupled analysis mechanism to develop engineering plastic products containing glass fibers. In addition, the study aims to apply and improve the plastic fracture mechanism in actual products by exploring anisotropy and stiffness reduction owing to the unfilled polymer weld line.