Mechanism of the Reduction of Nitrobenzene in Basic Solution

염기성 용액에서 니트로벤젠의 환원 메카니즘에 대한 고찰

  • In Kyu Kim (Department of Chemistry, Sungkyunkwan University) ;
  • Jasoo Whang (Department of Chemistry, Sungkyunkwan University)
  • 김인규 (성균관대학교 이과대학 화학과) ;
  • 황재수 (성균관대학교 이과대학 화학과)
  • Published : 1976.02.29

Abstract

A new mechanism is proposed for the reduction of nitrobenzene in basic solution that does not involve hydroxylamine as an intermediate. This paper presents evidence that the azoxybenzene is not formed from the hydroxylamine, but formed instead from the dimerization of nitrosobenzene.

염기성 용액에서 니트로벤젠의 환원에 대한 새로운 메카니즘을 제안하였다. 페닐히드록실아민이 중간체로서 관여하지 않고, 니트로소벤젠이 이합화(dimerization)하여 아족시벤젠으로 변환한다.

Keywords

References

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