• Title/Summary/Keyword: Materials property

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Mixing and Strength Properties of 150MPa Ultra High Strength Concrete (150MPa 초고강도 콘크리트 배합 및 강도발현 특성)

  • Ahn, Jong-Mun;Kang, Hoon;Kim, Jong-Keun;Shin, Sung-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.373-376
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    • 2008
  • Ultra High Strength Concrete(UHSC) is necessary a clear presentation about mechanical property that is different from normal strength concrete and an evaluation of serviceability of high rise building which is used ultra high strength concrete. To mixing ultra high strength concrete with $f_{ck}$=150MPa pre-mix cement were manufactured and experimental study were conducted to evaluated on the mixing properties and compressive strength with major variables as unit cement contents, water-binder ratio and type of pre-mix cement. As a test result, it is shown that the concrete mixing time is required about 5$^{\sim}$6 minute untill the each materials(ordinary portland cement, silica fume, blast-furnace slag powder and anhydrite) are revitalized enough. A slump flow of fresh concrete are shown about 700$^{\sim}$750mm with proper viscosity. And average value of concrete compressive strength are shown about 77% in 7days, 87% in 14days and 102% in 56days for 28days of concrete material age. From this experimental study, a proper mixture proportion of pre-mix cement are recommended about 54$^{\sim}$59% OPC, 25$^{\sim}$30% blast-furnace slag powder and 10$^{\sim}$15% silica fume for mix the ultra high strength concrete with $f_{ck}$=150MPa.

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Performance of Modified-Silicon Carbide Fiber Composites Membrane for Polymer Exchange Membrane Fuel Cells (표면처리된 실리콘 카바이드 섬유 복합막의 고분자 전해질 막 연료전지 성능)

  • Park, Jeong Ho;Kim, Taeeon;Juon, Some;Cho, Yongil;Cho, Kwangyeon;Shul, Yonggun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.28-38
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    • 2014
  • The organic-inorganic composite membrane in polymer exchange membrane fuel cells (PEMFCs) have several fascinating technological advantages such as a proton conductivity, thermal stability and mechanical properties. As the inorganic filler, silicon carbide (SiC) fiber have been used in various fields due to its unique properties such as thermal stability, conductivity, and tensile strength. In this study, composite membrane was successfully fabricated by modified-silicon carbide fiber. Modified process, as a novel process in SiC, takes reaction by phosphoric acid after oxidation process (generated homogeniusly $SiO_2$ layer on SiC fiber). The mechanical property which was conducted by tensile test of the 5wt% modified-$SiO_2@SiCf$ composite membrane was better than that of Aquivion casting membrane as well as ion cxchange capacity(IEC) and proton conductivity. In addition, the single cell performance was observed that the 5wt% modified-$SiO_2@SiCf$ composite membrane was approximately $0.2A/cm^2$ higher than that of a Aquivion casting electrolyte membrane and electrochemical impedance was improved with the charge transfer resistance and membrane resistance.

A Study on the Dielectric Characteristics of Non-Cross Linked Polyolefin for Distribution Power Cables (배전용 전력 케이블을 위한 비-가교 폴리올레핀 재질의 절연특성 연구)

  • Kim, Junil;Lee, Onyou;Bang, Seungmin;Kang, Jong O;Lee, Hongseok;Jeong, Yeong-Ho;Kang, Hyoungku
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.4
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    • pp.373-377
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    • 2014
  • A cross linked polyethylene (XLPE) material has been widely used to develop a distribution power cable due to its excellent electrical characteristics and mechanical strength. However, several problems such as environmental disruption, electrical aging, thermosetting property, and impurities which cause degradation also arise. Therefore, a novel dielectric material should be developed to substitute for the XLPE. Several kinds of polyolefin materials to substitute for the conventional dielectric material, XLPE are developed and A cylindrical rod to cylindrical rod electrode system made with stainless steel is used to perform the experiments according to the ASTM D-149 protocol under an AC and Impulse input voltage condition. The experimental results are calculated by the Weibull distribution method and analyzed by an Finite Element Method(FEM). Finally, the dielectric characteristics of the conventional XLPE and novel polyolefin are experimented compared with each other in this study.

Lifetime Prediction and Aging Behaviors of Nitrile Butadiene Rubber under Operating Environment of Transformer

  • Qian, Yi-hua;Xiao, Hong-zhao;Nie, Ming-hao;Zhao, Yao-hong;Luo, Yun-bai;Gong, Shu-ling
    • Journal of Electrical Engineering and Technology
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    • v.13 no.2
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    • pp.918-927
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    • 2018
  • Based on the actual operating environment of transformer, the aging tests of nitrile butadiene rubber (NBR) were conducted systematically under four conditions: in air, in transform oil, under compression in air and under compression in transform oil to studythe effect of high temperature, transform oil and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber and predict the lifetime. The effects of liquid media and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber were studied by using characterization methods such as IR spectrosc-opy, thermogravimetric measurements, Differential Scanning Calorimetry (DSC) measurements and mechanical property measurements. The changes in physical properties during the aging process were analyzed and compared. Different aging conditions yielded materials with different properties. Aging at $70^{\circ}C$ under compression stress in oil, the change in elongation at break was lower than that aging in oil, but larger than that aging under compression in air. The compression set or elongation at break as evaluation indexes, 50% as critical value, the lifetime of NBR at $25^{\circ}C$ was predicted and compared. When aging under compression in oil, the prediction lifetime was lower than in air and under compression in air, and in oil. It was clear that when predicting the service lifetime of NBR in oil sealing application, compression and media liquid should be involved simultaneously. Under compression in oil, compression set as the evaluation index, the prediction lifetime of NBR was shorter than that of elongation at break as the evaluation index. For the life prediction of NBR, we should take into account of the performance trends of NBR under actual operating conditions to select the appropriate evaluation index.

Ferroelectric Properly of Bi3.75La0.25Ti3O12 Ceramic Sintered in the Ambient (분위기 소결공정에 의한 Bi3.75La0.25Ti3O12세라믹의 강유전특성)

  • 김응권;박춘배;박기엽;송준태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.9
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    • pp.783-787
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    • 2002
  • In recent year, B $i_{4-}$x L $a_{x}$ $Ti_3$ $O_{12(BLT)}$ is one of promising substitute materials for the ferroelectric random access memory(FRAM) applications. But the systematic composition is still insufficient, so this experiment was carried out in ceramic ambient sintering process which has the very excellent ferroelectric property. Samples were prepared by a bulk and the purpose which was estimated with a suitability of thin films applications. The density of B $i_{3.75}$ L $a_{0.25}$ $Ti_3$ $O_{12}$ was high and the XRD pattern showed that the intensity of main peak (117) was increased at the argon ambient sintering. Controlling the quantity of oxygen, crystallization showed a thin, long plate like type, and we obtained the excellent dielectric and polarization properties at the argon atmosphere sintering. Also this sintering process was effective at the bulk sample. Argon ambient sintered sample produced higher permittivity of 154, the remanent polarization(2Pr) of 6.8 uC/$\textrm{cm}^2$ compared with that sintered in air and oxygen ambient. And this sintering process showed a possibility which could be applied to thin films process..

The crystal growth and the electrochemical property of $LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) cathode material ($LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) 정극 활물질의 결정 성장 변화와 전기 화학적 특성)

  • Jeong, In-Seong;Gu, Hal-Bon;Lee, Jin;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.133-136
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    • 1999
  • We report on the electrochemical properly of LiZ $n_{x}$Mn $_{2-x}$ $O_4$ for different degrees of Zn substitution(x) Though all cathode material showed spinel phase based on cubic phase in X-ray diffraction, other peaks(M $n_2$ $O_3$ or M $n_3$ $O_4$) gradually exhibited and became intense with the increase of x vague in LiZ $n_{x}$Mn $_{2-x}$ $O_4$. In addtion, TG-DTA analysis exhibited that both LiM $n_2$ $O_4$ and LiZ $n_{0.1}$ M $n_{1.9}$ $O_4$ occurred the weight loss(TG) and the endothermic and exothermic reaction(DTA) until 80$0^{\circ}C$ When x=0.1 in LiZ $n_{x}$Mn $_{2-x}$ $O_4$ cathode materials showed the charge and discharge capacity of about 100mAh/g at first cycle and about 70mAh/g after tooth cycle.cle.e.cle.e.e.e.

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Electrical and Mechanical Properties of Indium-tin-oxide Films Deposited on Polymer Substrate Using Organic Buffer Layer

  • Han, Jeong-In;Lee, Chan-Jae;Rark, Sung-Kyu;Kim, Won-Keun;Kwak, Min-GI
    • Journal of Information Display
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    • v.2 no.2
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    • pp.52-60
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    • 2001
  • The electrical and mechanical properties in indium-tin-oxide films deposited on polymer substrate were examined. The materials of substrates were polyethersulfone (PES) which have gas barrier layer and anti-glare coating for plastic-based devices. The experiments were performed by rf-magnetron sputtering using a special instrument and buffer layers. Therefore, we obtained a very flat polymer substrate deposited ITO film and investigated the effects of buffer layers, and the instrument. Moreover, the influences of an oxygen partial pressure and post-deposition annealing in ITO films deposited on polymer substrates were clarified. X-ray diffraction observation, measurement of electrical property, and optical microscope observation were performed for the investigation of micro-structure and electro-mechanical properties, and they indicated that as-deposited ITO thin films are amorphous and become quasi-crystalline after adjusting oxygen partial pressure and thermal annealing above $180^{\circ}C$. As a result, we obtained 20-25 ${\Omega}/sq$ of ITO films with good transmittance (above 80 %) of oxygen contents with under 0.2 % and vacuum annealing. Furthermore, using organic buffer layer, we obtained ITO films which have a rather high electrical resistance (40-45 ${\Omega}/sq$) but have improved optical (more than 85 %) and mechanical characteristics compared to the counterparts. Consequently, a prototype reflective color plastic film LCD was fabricated using the PES polymer substrates to confirm whether the ITO films could be realized in accordance with our experimental results.

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Estimation of the thickness of refractory ceramics using the impact-echo method (충격반향기법을 이용한 내화물 두께 추정)

  • Lee, Seongmin;Shin, Namho;Roh, Yongrae
    • The Journal of the Acoustical Society of Korea
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    • v.36 no.4
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    • pp.247-253
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    • 2017
  • Generally, the vibration characteristics of refractory ceramics are identified by assuming them as isotropic materials. However, in practice, refractory ceramics exhibit anisotropic properties as they are manufactured by pressing ceramic powders along a particular direction. Therefore, in this research, the frequency responses of a refractory ceramic brick along its width, length, and height directions were acquired using finite element analysis by assuming that the ceramics had tetragonal symmetry in their material properties. The validity of the numerical analysis results was verified by comparing them with those from experimental measurements. Based on the frequency response, the thicknesses of the refractory brick along three different directions were estimated using the impact-echo technique. The maximum difference between the estimated and actual thicknesses was observed to be less than 5 %. This result confirms the effectiveness of the impact-echo technique along with anisotropic property characterization to evaluate the thickness of the refractory ceramic.

Energy Band Structure and Photocatalytic Property of Fe-doped Zn2TiO4 Material

  • Jang, Jum-Suk;Borse, Pramod H.;Lee, Jae-Sung;Lim, Kwon-Taek;Jung, Ok-Sang;Jeong, Euh-Duck;Bae, Jong-Seong;Won, Mi-Sook;Kim, Hyun-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.3021-3024
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    • 2009
  • $Zn_2Ti_{1-x}Fe_xO_4\;(0\;{\leq}\;x\;{\leq}\;0.7)$ photocatalysts were synthesized by polymerized complex (PC) method and investigated for its physico-chemical as well as optical properties. $Zn_2Ti_{1-x}Fe_xO_4$ can absorb not only UV light but also visible light region due to doping of Fe in the Ti site of $Zn_2TiO_4$ lattice because of the band transition from Fe 3d to the Fe 3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped $Zn_2TiO_4$ samples for hydrogen production under UV light irradiation decreased with an increase in Fe concentration in $Zn_2TiO_4$. Consequently, there exists an optimized concentration of iron for improved photocatalytic activity under visible light (${\lambda}{\leq}$420 nm)

A study on the variation of in-plane and out-of-plane properties of T800 carbon/epoxy composites according to the forming pressure (성형 압력에 따른 T800 탄소섬유/에폭시 복합재료의 평면 내.외 물성 변화에 대한 연구)

  • Park, Myong-Gil;Cho, Sung-Kyum;Chang, Seung-Hwan
    • Composites Research
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    • v.23 no.6
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    • pp.61-66
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    • 2010
  • In this paper, the variation of mechanical properties of T800 carbon/epoxy composites according to the forming pressure, which was referred to previous studies on a filament winding process, were investigated. The specimens of all the tests were fabricated by an autoclave de-gassing molding process controlling forming pressure (absolute pressures of 0.1MPa, 0.3MPa, 0.7MPa including vacuum) and water jet cutting after fabricating composite laminates. Various tensile tests were performed for in-plane properties and interlaminar properties were also measured by using Iosipescu test jig. Fiber volume fraction was measured to correlate the property variation and the forming pressure. This properties are expected to be utilized in the design of Type III pressure vessel for hydrogen vehicles which uses the same carbon fiber (T800 carbon fiber) for the filament winding process.