• Title/Summary/Keyword: Material separation

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Relation between Huggins Constant and Compatibility of Binary Polymer Mixtures in the Aqueous Ternary Systems

  • Isamu Inamura;Makoto Kittaka;Tatsuya Aikou;Kazuhiko Akiyama;Tomoyuki Matsuyama;Masatsugu Hiroto;Hirade, Ken-ichi;Yuji Jinbo
    • Macromolecular Research
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    • v.12 no.2
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    • pp.246-250
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    • 2004
  • We have classified a number of aqueous ternary systems containing two different polymers into three types by focusing on the deviation of the Huggins constant k'from the additivity line. Systems of type I have negative deviations of k'; the repulsive interaction between the two different polymers dominates. In systems of type II, k' almost follows the additivity relation; the repulsive and attractive interactions between the two different polymers are balancing. Type III systems have positive deviations of k'; the attractive interactions are relatively dominant. This classification of systems is supported by the fact that the positive and negative deviations of k' from the additivity line also correspond to the sign of interaction parameter between polymer 2 and 3, Δb$\_$23/. Furthermore, we have verified the relatively high compatibility between dextran and poly(vinyl alcohol) by determining the binodal concentration of a liquid-liquid phase separation for a water/dextran/poly(vinyl alcohol) system, which is classified as type III. Thus, we found that the compositional dependence of k' closely relates to the compatibility of binary polymer mixtures in aqueous ternary systems.

Study on the Electro-Optic Characteristics Depending on UV Condition in the Normally Scattering(NS)/Normally Transparent(NT) Polymer Dispersed Liquid Crystal Mode (Normally Scattering(NS)/Normally Transparent (NT) 고분자 분산형 액정 모드에서 UV 조건에 따른 전기 광학특성 연구)

  • Kim, M.S.;Seo, Y.H.;Lee, M.H.;Rhee, J.M.;Lee, T.S.;Lee, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1050-1053
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    • 2003
  • Polymer dispersed liquid crystal mode can be classified into two cases, normally scattering mode (NS) and normally transparent (NT) mode according to an initial state. Electro-optic characteristic NS/NT PDLC mode can be improved by controlling the factors to influence the phase separation. In case of NS PDLC mode, we inspected change of a phase separation as a function of curing temperature for the mixture of E7 and NOA65 with different ratios. When the LC concentration is less than polymer such as LC : NOA65 = 40 : 60wt%, the PDLC cell is influenced strongly by the curing temperature. However, when LC concentration is much less than polymer such as LC : NOA65 : 80 : 20wt%, it is influenced slightly by the curing temperature. In case of NT PDLC mode, we observed change of a phase separation as a function of the ratio of the mixture and UV conditions such as curing temperature, UV intensity The cell made with strong UV intensity and curing temperature of $20^{\circ}C$, in case that the ratio of LC to polymer is 70:30wt%, showed good electro-optic characteristics.

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Separation of Molybdenum and Tungsten from Sulfuric acid Solution by Solvent Extraction with Alamine 336 (황산용액에서 Alamine 336에 의한 용매추출로 몰리브덴과 텅스텐의 분리)

  • Nguyen, Thi Hong;Lee, Man Seung
    • Resources Recycling
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    • v.25 no.1
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    • pp.16-23
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    • 2016
  • The separation behaviour of Mo and W from sulfuric acid solution by solvent extraction with Alamine 336 was investigated as a function of solution pH and extractant concentration. Selective extraction of Mo over W by Alamine 336 was obtained in the pH range of 3-5 with low amine concentration. The mixture of Alamine 336 and acidic extractants improved the separation factor between Mo and W and was in the following order: D2EPHA > PC88A > Decanol > Versatic acid. The stripping efficiency of Mo and W from the loaded mixture of Alamine 336 and D2EHPA was very poor, while complete stripping of Mo and W was possible from the mixture of Alamine 336 and Decanol by using a mixture of $NH_4OH$ and $NH_4Cl$.

Granulations of SiOx Nanoparticles to Improve Electrochemical Properties as a Li-Ion Battery's Anode (리튬이온전지 음극용 SiOx 나노입자의 조대화를 통한 전기화학 특성 향상)

  • Lee, Bora;Lee, Jae Young;Jang, Boyun;Kim, Joonsoo;Kim, Sung-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.70-77
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    • 2019
  • $SiO_x$ nanoparticles were granulated, and their microstructures and effects on electrochemical behaviors were investigated. In spite of the promising electrochemical performance of $SiO_x$, nanoparticles have limitations such as high surface area, low density, and difficulty in handling during slurry processing. Granulation can be one solution. In this study, pelletizing and annealing were conducted to create particles with sizes of several decades of micron. Decrease in surface area directly influences the initial charge and discharge process when granules are applied as anode materials for Li-ion batteries. Lower surface area is key to decreasing the amount of irreversible phase-formation, such as $Li_2Si_2O_5$, $Li_2SiO_3$ and $Li_4SiO_4$, as well as forming the solid electrolyte interface. Additionally, aggregation of nanoparticles is required to obtain further enhancement of the electrochemical behavior due to restrictions that there be no $Li_4SiO_4$-related reaction during the first discharge process.

Structural Analysis of TPU Membrane Plate in Multi-purpose Module for Solid-liquid Separation (TPU 재질을 적용한 다목적 고액분리 모듈의 여과판 구조해석)

  • Jung, Hee Suk;Oh, Doo Young;Ko, Dong Shin;Song, Hyoung Woon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.1
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    • pp.5-13
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    • 2017
  • Polypropylene is the main existing material in the domestic market being used for the filter plate because of its moldability, low cost, and commercial availability. Polypropylene filter plate once distorted due to the high-pressure during operation may cause the problem in the continuous operation of the solid-liquid separation module. Thermoplastic Poly Urethane (TPU) can be a high-performance alternative material for the filter plate in the solid-liquid separation module of the dehydration process. Hence, to predict and evaluate the TPU for structural stability in the filter plate through analytical techniques designed and experimental verification is essential. As a result, TPU filter plate had maximum strain of 27.85 MPa at 20 bar pressure condition. This result is less than TPU stress-strain limit, which ensures the structural stability of the TPU material.

Pneumatic Separation on Separating Unit of a Combine Harvester (콤바인 선별실(選別室)의 기류선별(氣流選別)에 관한 연구(硏究))

  • Chung, C.J.;Nam, S.I.;Joo, B.C.
    • Journal of Biosystems Engineering
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    • v.13 no.3
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    • pp.32-43
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    • 1988
  • This study was attempted to investigate the pneumatic separation on separating unit of a combine harvester. The aerodynamic characteristics of threshed materials were analyzed by experiments. The air velocity distribution within the separation chamber was measured for various speeds of the winnower and suction fans to find out the operational and design conditions of the separating unit which would serve for reducing the grain loss from chaff outlet. The results of study arc summarized as follows: 1. Based on the separation curve of threshed materials analyzed, it was shown that three different kind. of materials-kernels, straw chaff, and leaf chaff were as a whole able to be separated pneumatically, regardless of varieties. However, a small amount of the separation grain loss may be expected to occur if the complete separation between kernels and straw chaff would be undertaken because some portion of their separation curve were overlapping. 2. The analysis of air velocity distribution showed that the separation chamber may be divided into two regions, the discharging and separating. The air velocity of the discharging region was 5-15 m/s and that of the separating region 2-5 m/s. 3. The air movement of the separation chamber may be a turbulence flow, being its speed became greater as it moves from the left to the right section of the separation chamber. The equi-speed line. of air flow had a steep gradient in between the discharging and the separation regions. The air velocity in the discharging region was much higher than the terminal velocity of kernels, because of which those kernels appearing in the region could be possibly exhausted as the grain loss from the chaff outlet. 4. The motion trajectory of threshed material in the separating region was dominantly affected by the winnower fan, on the other hand, its motion in the discharging region was affected by suction fan. 5. The grain loss from the chaff outlet was affected greatly by the winnower fan and the trace of kernel movement. It was observed that the optimum working speed to give minimum grain loss from chaff outlet for the combine tested should be maintained at 950~1,150 rpm for the winnower fan and 1,850 rpm for the suction fan. 6. It was shown that a large portion of grain loss from chaff outlet may occur when the kernels may bump against a portion of separation chamber wall and those kernels thus scattered into the discharging region were sucked by the suction fan. It was accordingly recommended that a new design of the wall of separation chamber so as to bump down kernels may be necessary to reduce grain loss from the chaff outlet.

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Evaluation on Properties of Mortar Using Magnetically Separated Bottom Ash (자력 선별된 바텀애쉬를 활용한 모르터의 물성 평가)

  • Choi, Ik-Je;Jang, Bo-Kil;Kim, Ji-Hyun;Chung, Chul-Woo;Lee, Jae-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.99-100
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    • 2015
  • Significant amount of bottom ash has been produced in the power plant located at southeast region of Korea, but those were abandoned in the pond site without any treatment. In these days, there is a strong move to enforce environmental regulations to protect surrounding nature, a lot of pressure is given to the power plant industry to remove hazardous chemicals from their waste material before landfill or site storage. The overall objective of this research is to separate hazardous chemicals from the bottom ash, and use it safely as sustainable construction material. In this specific study, magnetic separation of bottom ash was applied, and used as a fine aggregates to make mortar specimens. According to the results, it was found that the use of bottom ash decreased 28-day compressive strength. However, using non-magnetic bottom ash provides best results in terms of thermal conductivity, showing strong possibility to be used as heat insulating material.

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Recovery of Roasting-Molybdenite Concentrate by Froth Flotation (부유선별법에 의한 제련용 몰리브덴 정광의 회수)

  • Park, Chul-Hyun;Jeon, Ho-Seok;Kim, Byoung-Gon;Han, Oh-Hyung
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.661-666
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    • 2009
  • Froth flotation has been carried out in order to produce roasting-molybdenite concentrate from molybdenite ore in the Shin-yeomi mine. In our study, roasting-molybdenite (Mo 0.43%) from Shin-yeomi mine was recovered by varying the conditions of regrinding time, dosage of collector and alkalinity. Liberation and flotation efficiency more were effective at regrinding time of six minutes than at single grinding. Mo recovery curves increased considerably as dosage of kerosene increased, whereas Mo grade curves decreased gradually. The separation efficiency of molybdenite was effective when the dosage of collector (kerosene) was adjusted to 300 g/t. The molybdenite concentrate was agglomerated in the range of pH 5-7 and its separation efficiency increased to pH 9-10. The concentrate of 49.5% Mo grade ($MoS_2$, 82.6%) with 81.5% recovery from Shin-yeomi molybdenite ores was obtained under conditions of 20% pulp concentration, 300 g/t kerosene 325 g/t frother (AF65), 2.5 kg/t depressant ($Na_2SiO_3$), pH 9-10 and four cleaning times. In the future, a trial run that can separate up to 50% Mo grade from Shin-yeomi molybdenite ores will be performed.

Effects of Tube Materials and Cooling Media on the Energy Separation in Vortex Tubes

  • Riu, Kap-Jong;Kim, Hyun-Woo;Park, In-Su;Kim, Byung-Ha
    • International Journal of Air-Conditioning and Refrigeration
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    • v.10 no.3
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    • pp.138-146
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    • 2002
  • The phenomena of energy separation in vortex tubes was investigated experimentally to see the subsidiary effect of the conductivity of tube material and cooling conditions around the outer surface of the tube. The experiment was carried out with pyrex, stainless steel and copper tubes, and the heat transfer conditions of the tubes were with insulation, without in-sulation and water cooling modes respectively The results were obtained that the hot exit fluid temperature was highly affected by a change of conductivity of a tube when the outer surface was cooled by the water, while the working fluid through the tubes was air. How-ever, the cold exit temperature was little affected by the heat transfer modes on the outer surface of the vortex tube.

A Study on the Utilization of Yun Chun Andalusite as a Raw Material of High Alumina Refractories (II) -On the Concentration and Purification- (고 알루미나질 내화물 원료로서 연천산 홍주석의 이용에 관한 연구(II) -홍주석의 선광 및 정제-)

  • Ahn, Young-Pil;Choi, Long
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.23-28
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    • 1974
  • 1. Stage crushing by jaw crusher, steel mortar, and ball mill in turn has shown an inclination to increase the distribution of andalusite in coarse particles as well as to increase that of micas in fine particles. 2. Water elutriation was effective for the removal of muscovite and magnetic separation was effective for that of Mg-Fe micas such as biotte and chlorite. The process of concentration and that of purification are diagramatized respectively as follows: Concentration; Raw andalusite${\lightarrow}$Crushing${\lightarrow}$Screening${\lightarrow}$Water elutriation${\lightarrow}$Magnetic separation Purification; Concentrated andalusite${\lightarrow}$Calcination${\lightarrow}$Ball milling${\lightarrow}$Screening${\lightarrow}$Water elutriation${\lightarrow}$Magnetic separation${\lightarrow}$Acid washing.

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