• Title/Summary/Keyword: Material dispersion

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Analytical wave dispersion modeling in advanced piezoelectric double-layered nanobeam systems

  • Ebrahimi, F.;Haghi, P.;Dabbagh, A.
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.175-183
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    • 2018
  • This research deals with the wave dispersion analysis of functionally graded double-layered nanobeam systems (FG-DNBSs) considering the piezoelectric effect based on nonlocal strain gradient theory. The nanobeam is modeled via Euler-Bernoulli beam theory. Material properties are considered to change gradually along the nanobeams' thickness on the basis of the rule of mixture. By implementing a Hamiltonian approach, the Euler-Lagrange equations of piezoelectric FG-DNBSs are obtained. Furthermore, applying an analytical solution, the dispersion relations of smart FG-DNBSs are derived by solving an eigenvalue problem. The effects of various parameters such as nonlocality, length scale parameter, interlayer stiffness, applied electric voltage, relative motions and gradient index on the wave dispersion characteristics of nanoscale beam have been investigated. Also, validity of reported results is proven in the framework of a diagram showing the convergence of this model's curve with that of a previous published attempt.

In-Line Monitoring the Dispersion of Highly Energetic Material Simulant (고에너지 물질 시뮬란트의 분산도의 In-Line 모니터링)

  • Lee, Sangmook;Hong, In-Kwon;Ahn, Youngjoon;Lee, Jae Wook
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.272-277
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    • 2014
  • We studied in-line monitoring the dispersion of highly energetic material simulant by a twin screw extruder having a high temperature ultrasonic system. The simulant suspension system consisted of ethylene vinyl acetate and Dechlorane plus 25 as binder and filler, respectively. With increasing filling fraction, the ultrasonic velocity was not changed but the attenuation linearly decreased. It was possible to estimate the solid fraction of well dispersed suspension system by measuring ultrasonic attenuation. The ultrasonic attenuation of samples filled over 60 v% approached straight line with increasing filling fraction when the samples was extruded repeatedly. It was due to the enhanced dispersion of solid particles in the suspension system. It was believed that the degree of dispersion and filling fraction could be obtained by combination of on-line measurement like ultrasonic attenuation and off-line analysis like TGA and SEM with image analyzer.

$SnO_2$ Dispersion of Sintered Body in $In_2O_3-SnO_2$ Binary System ($In_2O_3-SnO_2$ 이성분계 소결특성에 있어서 $SnO_2$ 분산성)

  • Chun, Tae-Jin;Park, Wan-Soo;Cho, Muyung-Jin;Kim, Jong-Su;Kim, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.198-198
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    • 2006
  • Tin doped $In_2O_3$ sputtering target is widely used to produce a various kinds of flat panel display because of high transmittance in visible region and high electrical conductivity. In2O3 and SnO2 powders were prepared by a homogeneous precipitation method using metal source, respectively, the calcining and sintering behavior of the indium-tin oxide(In2O3-SnO2) composite powders were studied. The tin oxide(SnO2) dispersion condition in ITO sputtering target was improved by increasing calcining temperature. And the tin oxide dispersion was also improved by reducing the tin oxide contents in the ITO target from 30 to 5wt%. SnO2 dispersion and densification of ITO target is very difficult to control due to sublimation of SnO2 at over 1150C.

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Preparation and Characterization of Simvastatin Solid Dispersion using Aqueous Solvent

  • Kim, Kwang-Hyeon;Park, Jun-Bom;Choi, Won-Jae;Lee, Han-Seung;Kang, Chin-Yang
    • Journal of Pharmaceutical Investigation
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    • v.41 no.4
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    • pp.239-247
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    • 2011
  • Simvastatin is an inhibitor of 3-hydroxy-3-methylglutaryl-coenzyme A (HMG-CoA) reductase, which catalyzes the conversion of HMG-CoA to mevalonate, an early and rate-limiting step in the biosynthesis of cholesterol. Simvastatin has good permeability, but it also has low solubility (BCS class II), which reduces its bioavailability. To overcome this problem, a solid dispersion is formed using a spray-dryer with polymeric material carrier to potentially enhance the dissolution rate and extend drug absorption. As carriers for solid dispersion, Gelucire$^{(R)}$44/14 and Gelucire$^{(R)}$ 50/13 are semisolid excipients that greatly improve the bioavailability of poorly-soluble drugs. To avoid any toxic effects of an organic solvent, we used aqueous medium to melt Tween$^{(R)}$ 80 and distilled water. The structural behaviors of the raw materials and the solid dispersion were analyzed by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). The DSC and PXRD data indicated that the crystalline structure of simvastatin was transformed to an amorphous structure through solid dispersion. Then, solid dispersion-based tablets containing 20 mg simvastatin were prepared with excipients. Dissolution tests were performed in distilled water and artificial intestinal fluid using the USP paddle II method. Compared with that of the commercial tablet (Zocor$^{(R)}$ 20 mg), the release of simvastatin from solid dispersion based-tablet was more efficient. Although the stability study is not complete, this solid dispersion system is expected to deliver poorly water-soluble drugs with enhanced bioavailability and less toxicity.

Quantitative Dispersion Evaluation of Carbon Nanotubes Reinforced Polymer Nano-composites (탄소나노튜브 첨가 고분자 나노복합재료의 정량적 분산도 평가)

  • Lee, Sang-Bok;Jeong, Bo-Hwa;Yi, Jin-Woo;Lee, Won-Oh;Um, Moon-Kwang
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.60-65
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    • 2011
  • In order to maximize the performance of polymer nano-composites, it is essential to understand an effect of a dispersion state on material properties as well as to achieve highly dispersed composites. In this work, a simple quantitative approach to evaluate the degree of dispersion was suggested for carbon nanotube (CNT) embedded polymer nano-composites. Through UV-visible spectroscopy analysis, the transmittance of nano-composites was measured at various dispersion states and it was found that the transmittance reduced as the dispersion state of CNT improved. Based on the results, an effective concentration factor for quantitative evaluation of dispersion state was introduced into the Beer-Lambert transmittance law. The proposed method and parameter to evaluate the degree of dispersion were verified by analyzing the transmittances at different dispersion states of CNT, concentrations of CNT and sample thicknesses.

Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.

The influence of the rheological parameters on the dispersion of the flexural waves in a viscoelastic bi-layered hollow cylinder

  • Kocal, Tarik;Akbarov, Surkay D.
    • Structural Engineering and Mechanics
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    • v.71 no.5
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    • pp.577-601
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    • 2019
  • The paper investigates the influence of the rheological parameters which characterize the creep time, the long-term values of the mechanical properties of viscoelastic materials and a form of the creep function around the initial state of a deformation of the materials of the hollow bi-layered cylinder on the dispersion of the flexural waves propagated in this cylinder. Constitutive relations for the cylinder's materials are given through the fractional exponential operators by Rabotnov. The dispersive attenuation case is considered and numerical results related to the dispersion curves are presented and discussed for the first and second modes under the first harmonic in the circumferential direction. According to these results, it is established that the viscosity of the materials of the constituents causes a decrease in the flexural wave propagation velocity in the bi-layered cylinder under consideration. At the same time, the character of the influence of the rheological parameters, as well as other problem parameters such as the thickness-radius ratio and the elastic modulus ratio of the layers' materials on the dispersion curves, are established.

Solving partial differential equation for atmospheric dispersion of radioactive material using physics-informed neural network

  • Gibeom Kim;Gyunyoung Heo
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2305-2314
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    • 2023
  • The governing equations of atmospheric dispersion most often taking the form of a second-order partial differential equation (PDE). Currently, typical computational codes for predicting atmospheric dispersion use the Gaussian plume model that is an analytic solution. A Gaussian model is simple and enables rapid simulations, but it can be difficult to apply to situations with complex model parameters. Recently, a method of solving PDEs using artificial neural networks called physics-informed neural network (PINN) has been proposed. The PINN assumes the latent (hidden) solution of a PDE as an arbitrary neural network model and approximates the solution by optimizing the model. Unlike a Gaussian model, the PINN is intuitive in that it does not require special assumptions and uses the original equation without modifications. In this paper, we describe an approach to atmospheric dispersion modeling using the PINN and show its applicability through simple case studies. The results are compared with analytic and fundamental numerical methods to assess the accuracy and other features. The proposed PINN approximates the solution with reasonable accuracy. Considering that its procedure is divided into training and prediction steps, the PINN also offers the advantage of rapid simulations once the training is over.

Improvement of Electrical Conductivity of Transparent Conductive Single-Walled Carbon Nanotube Films Fabricated by Surfactant Dispersion

  • Lee, Seung-Ho;Kim, Myoung-Su;Goak, Jeung-Choon;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.17-17
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    • 2009
  • Single-walled carbon nanotubes (SWCNTs) have attracted much attention as promising materials for transparent conducting films (TCFs), thanks to their superior electrical conductivity, high mechanical strength, and complete flexibility. The CNT-based TCFs can be used in a variety of application fields as flexible, transparent electrodes, including touch panel screens, flexible electronics, transparent heaters, etc. First of all, this study investigated the effect of a variety of surfactants on the dispersion of SWCNTs in an aqueous solution. Following the optimization of the dispersion by surfactants, flexible TCFs were fabricated by spraying the CNT suspension onto poly(ethylene terephthalate) (PET) substrates. The sheet resistances of the TCFs having different surfactants were investigated with treatment in nitric acid ($HNO_3$) whose concentration and period of treatment time were varied. It seems that the $HNO_3$ removes the surfactants from and is simultaneously doped into the SWCNT network, reducing the contact resistance between CNTs. TCFs were characterized by UV-VIS spectroscopy, thermogravimetric analyzer (TGA), scanning electron microscopy (SEM), and four-point probe.

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