• 대한화학회지
• /
• 제39권9호
• /
• pp.722-727
• /
• 1995

순환 전압-전류법으로 합성한 폴리아닐린 막의 전기화학적 임피던스 측정을 0.1M 황산용액에서 수행하였다. 전기 전도성을 갖는 퍼텐셜 영역에서 전하-이동 정항은 낮은 값을 나타냈으며, 따라서 교환 전류밀도는 큰 값으로 측정되었다. 고분자의 축전 용량은 이중층 축전 용량보다 크게 나타났으며 이값은 전극 퍼텐셜에 따라 변하였다. 측정된 임피던스 데이터로부터 전극의 등가 회로를 추정하였으며, 이 등가 회로를 토대로 하여 폴리아닐린 막대에서 혼입된 이온의 물질 이동 파라미터를 산출하였다.

• 한국재료학회지
• /
• 제6권1호
• /
• pp.57-66
• /
• 1996

MoSi2 heating elements were fabricated by sintering of MoSi2 powders which were synthesized through SHS(Self-propagating high-temperature synthesis). Their high-temperature oxidation behavior in air through SHS(Self-propagating high-temperature synthesis). Their high-temperature oxidation behavior on air at 1000-1600$^{\circ}C$ was investigated through a high-temperature X-ray diffractomer and isothermal heating in a muffle furnace. The thermal expansion of MoSi2 and SiO2 was studied by measuring their lattice parameters on heating. The linear expansion coeffcient of MoSi2 along c-axis was about 1.5 times larger than that along a-axis showing a strong thermal anisotropy. Few $\mu\textrm{m}$-thick Mo5Si3 layer was found beneath SiO2 layer suggesting that The major reaction products would be SiO2 and Mo5Si3. The Si-rich bentonite resulted in the faster growth of MoSi2 grains probably by enhancing the mass transport when they are melted during high-temperature oxidation.

• 한국연소학회지
• /
• 제17권4호
• /
• pp.21-29
• /
• 2012

Due to a significant leap in the science and technology, the manned space exploration that has started with suborbital flights is now being expanded into the deep space. The space superpowers such as the U.S. and Russia have been making an effort to further develop the manned space technology. Among such technologies, the fire safety technology in microgravity has recolonized as one of the most critical factors that must be considered for the manned space mission design since the realistic fire broke out onboard the Mir station in 1997. In the present study, the flame characteristics such as flame ignition, shape, spread, and extinction that are critical to understand the fire behavior under microgravity conditions are described and discussed. The absence of buoyancy in microgravity dominates the mass transport driven by diffusiophoretic and thermophorectic fluxes (that are negligible in normal gravity) and influences the overall flame characteristics-flame ignition, shape, spread, and extinction. In addition, the cabin environments of the pressurized module (PM) including the oxygen concentration, ambient pressure, and ventilation flow(which are always coupled with microgravity condition during the ISS operation) are found to be the most important aspects in characterizing the fire behavior in microgravity.

• 전기화학회지
• /
• 제11권4호
• /
• pp.273-283
• /
• 2008

고분자 전해질 연료전지의 구성요소인 기체 확산층(Gas Diffusion Layer)은 반응물을 채널에서 MEA로 전달하며 동시에 생성물을 MEA에서 채널로 전달하는 역할을 한다. 기체 확산층의 기체 투과도가 클수록 기체 확산층을 통과하는 반응기체의 양이 증가하여 고분자전해질 연료전지 성능이 향상되며 물질전달과 함께 열전달이 이루어지기 때문에 생성열에 의한 MEA의 온도상승을 억제해준다. 본 연구에서는 기체 확산층의 기체투과도를 달리하여 전기화학 반응과 열 생성을 고려한 3차원 수치해석 모델을 통해 동일 반응면적을 가지는 직선형 채널과 곡사형 채널에 대해 열전달 및 물질전달 특성을 분석하였다. 수치해석 결과 직선형 채널의 경우 곡사형 채널에 비해 기체 확산층의 기체투과도에 따른 성능 변화가 크지 않았다. 이러한 이유는 직선형 채널에서 주된 물질전달은 확산에 의해 이뤄지기 때문이다. 곡사형 채널의 경우 기체투과도가 높을수록 대류에 의한 물질전달로 원활한 물질전달이 이뤄졌기 때문에 연료전지 성능이 증가 되었으며 원활한 물질전달이 열전달을 촉진하여 MEA의 온도를 낮추었다. 또한 곡사형 채널에서는 기체투과도가 작아질수록 확산에 의한 물질 및 열전달 특성을 보여주었다.

• 한국지반환경공학회 논문집
• /
• 제4권3호
• /
• pp.79-88
• /
• 2003

비균질 다공성 매질을 통과하는 선형 흡착 용질의 공간적 거동에 대한 특성이 수치적 기법을 통해 분석되었다. 공간적으로 서로 상관된 투수계수의 대수적 분포를 지구통계학적 기법인 TBM(Turning Bands Method)을 사용하여 2차원 공간 내에 발생시켰으며, 이를 통한 지하수 흐름의 수리수두분포와 유속벡터장은 정상상태의 포화된 2차원 지하수 흐름 방정식에 Galerkin 유한요소법을 적용하여 계산하였다. 또한, 용질이동에 대한 수치모의는 시간간격을 자동으로 보정해주는 CD(constant displacement)기법이 포함된 난보모형(Random Walk Particle Tracking Model, RWPTM)을 통해 수행되었다. 본 연구에서 용질의 공간적 거동의 특성은 종방향 질량중심 이동거리, 종방향 공간 퍼짐 모멘트 그리고 용질분포의 종방향 왜곡계수를 통해 분석되었다.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2010년도 추계학술대회 초록집
• /
• pp.76.2-76.2
• /
• 2010

The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

• 한국전기전자재료학회논문지
• /
• 제13권6호
• /
• pp.520-525
• /
• 2000

Glucose oxidase was immobilized in polypyrrole by electrosynthesis. The enzyme had an influence on the redox properties of a complex enzyme electrode. In the cyclic voltammograms of the enazyme electrode new peaks were appeared at the potential around 0.7V vs. Ag/AgCl in additional to the typical peaks for polypyrrole. The more immobilized the stronger the peaks became. During the cycling the pH of electrolyte solution was decreased to about 4.4 The reason for that is to be the proton released from the carboxyl in the glucose oxidase in order to keep on a charge neutrality of the oxidized enzyme. This fact suggests that the new peaks in the voltammograms are caused by the redox of glucose oxidase. In the AC impedance spectrum analysis of the electrode the diffusion of electrolyte anion was limited because of chained structure of the enzyme. The faradic impedance was large since the glucose oxidase is an insulator. Therefore when glucose oxidase is entrapped the enzyme should be limited in amount. Because the growth of the polypyrrole is accompanied both charge transfer and mass transport. For the traditional electrosynthesis that means amount of enzyme present in the electrode is limited to as much as film growable.

• 대한화학회지
• /
• 제40권1호
• /
• pp.37-43
• /
• 1996

텅스텐을 작업 전극으로 사용하여 순환 전압-전류법으로 합성한 폴리아닐린 막의 전기화학적 임피던스를 0.1M 황산 용액에서 측정하였다. 전기 전도성을 갖는 퍼텐셜 영역에서는 고분자 막의 큰 축전-용량과작은 저항이 직렬로 연결된 전기화학 쎌이 관측되었다. 순수한 텅스텐에 입혀진 폴리아닐린은 접촉 저항을 무시할 수 있었으나, 산화 전극 막이 입혀진 텅스텐의 경우는 산화 전극 막의 저항과 접촉 저항이 관측되었다. 측정된 임피던스 데이터로부터 전극의 등가 회로를 추정하였으며, 이 등가 회로를 토대로 하여 폴리아닐린-막 안에 혼입된 이온의 물질 이동 파라미터를 산출하였다.

• Journal of Electrochemical Science and Technology
• /
• 제5권2호
• /
• pp.37-44
• /
• 2014

The $Li-O_2$ battery has been attracting much attention recently, due to its very high theoretical capacity compared with Li-ion chemistries. Nevertheless, several studies within the last few years revealed that Li-ion derived electrolytes based on alkyl carbonate solvents, which have been commonly used in the last 27 years, are irreversibly consumed at the $O_2$ electrode. Accordingly, more stable electrolytes are required capable to operate with both the Li metal anode and the $O_2$ cathode. Thus, due to their favorable properties such as non volatility, chemical inertia, and favorable behavior toward the Li metal electrode, ionic liquid-based electrolytes have gathered increasing attention from the scientific community for its application in $Li-O_2$ batteries. However, the scale-up of Li-$O_2$ technology to real application requires solving the mass transport limitation, especially for supplying oxygen to the cathode. Hence, the 'LABOHR' project proposes the introduction of a flooded cathode configuration and the circulation of the electrolyte, which is then used as an oxygen carrier from an external $O_2$ harvesting device to the cathode for freeing the system from diffusion limitation.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2003년도 추계학술발표회
• /
• pp.140-143
• /
• 2003

Air permeabilities in unsaturated fractured tuff at the Apache Leap Research Site (ALRS) near Superior, Arizona, exhibit a self-affine behavior, thus renders a field random fractal. Based up fractal scaling, the observed scale effect has been interpreted [Hyun et al., 2002]. Recently, Frantziskonis and Hansen [2000] presented that fractal scaling can be represented based on wavelets. This study deals with the way of using wavelets for fractal scaling. A numerical study is presented to examine the applicability of wavelet-based approach to determining upscaled air permeability values on various data supports at the site. To characterize the scaling property of self-affine fields generated based upon wavelets, Hurst coefficient, H. was inferred by applying the average wavelet coefficient (AWC) method. The result yielded H = 0.24, which is very close to the result of geostatistical analysis using a power variogram (H = 0.22). The study concludes that wavelet-based scaling is a useful way of determining parameter values on different data supports, which is an essential task for modeling of subsurface flow and mass transport in a numeric grid with different resolutions (grid size).