• Title/Summary/Keyword: Martensite phase

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Development of High Erosion Resistant Fe-based Alloy for Continuous Hot Dipping Line (연속용융 도금라인 용 고내침식 Fe계 합금 개발)

  • Baek, Min-Sook;Kim, Yong-Cheol;Baek, Kyeong-Cheol;Kwak, Joon-Seop;Yoon, Dong-Joo
    • Journal of Surface Science and Engineering
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    • v.53 no.3
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    • pp.95-103
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    • 2020
  • In this study, the material used in the hot dip galvanizing equipment was poorly corrosion-resistant, so it was performed to solve the cost and time problems caused by equipment replacement. The theoretical calculation was performed using the DV-Xα method(Discrete Variational Local-density approximation method). The alloy (STS4XX series) of the equipment currently used has a martensite phase. Therefore, the theoretical calculation was performed by applying P4 / mmm, which is a tetragonal structure. The new alloy was chosen by designing theoretical values close to existing materials. Considering elements that contribute to corrosion, most have high prices. Therefore, the design was completed by adjusting the content using only the components of the reference material in the theoretical design. The final design alloys were chosen as D6 and D9. Designed D6 and D9 were dissolved and prepared using an induction furnace. After the heat treatment process was completed, the corrosion rate of the alloys was confirmed by using the potentiodynamic polarization test. The surface of the prepared alloys were processed horizontally and then polished to # 1200 using sand paper to perform potentiodynamic polarization test. Domestic products: 4.735 mpy (mils / year), D6: 0.9166 mpy, D9: 0.3372 mpy, alloys designed than domestic products had a lower corrosion rate. Therefore, the designed alloy was expected to have better erosion resistance.

Synthesis and Magnetic Properties of Body-centered-tetragonal Fe-Co Alloy (체심정방정 구조 Fe-Co계 합금상의 합성 및 그 자기적 특성)

  • Kim, K.M.;Kwon, H.W.;Lee, J.G.;Yu, J.H.
    • Journal of the Korean Magnetics Society
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    • v.27 no.4
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    • pp.129-134
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    • 2017
  • Bulk-type body-centered-tetragonal Fe-Co alloy was synthesised by utilising a conventional alloy preparation technologies, such as melting, solidification, and homogenising treatments, and its magnetic properties were investigated. In the $(Fe_{100-x}Co_x)_{1-y}C_y$ alloy, the composition range, from which single phase body-centered-tetragonal alloy (martensite phase) was obtained, was severely limited: Co content x = 2.5, and C content y = 0.062. Tetragonality(c/a) of the synthesised body-centered-tetragonal $(Fe_{97.5}Co_{2.5})_{0.938}C_{0.062}$ alloy was 1.05. Magnetocrystalline anisotropy constant ($K_1$) of the body-centered-tetragonal $(Fe_{97.5}Co_{2.5})_{0.938}C_{0.062}$ alloy was measured to be $9.8{\times}10^5J/m^3$), which was 3.1 time as high as the pure iron (${\alpha}-Fe$).

Change of Compressive Deformation Behaviors of Ti-5Mo-xFe Metastable Beta Alloy According to Fe Contents (Fe 함량에 따른 Ti-5Mo-xFe 준안정 베타 합금의 압축 변형거동 변화)

  • Yong-Jae Lee;Jae Gwan Lee;Dong-Geun Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.5
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    • pp.303-310
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    • 2023
  • β titanium alloys are widely used in aerospace industry due to their excellent specific strength and corrosion resistance. In particular, mechanical properties of metastable β titanium can efficiently be controlled by various deformation mechanisms such as slip, twinning, and SIM (Stress-Induced Martensite Transformation), making it an ideal material for many industrial applications. In this study, Ti-5Mo-xFe (x=1, 2, 4 wt%) alloy was designed by adding a relatively inexpensive β element to ensure price competitiveness. Additionally, microstructural analysis was conducted using OM, SEM, and XRD, while mechanical properties were evaluated through hardness and compression tests to consider the deformation mechanisms based on the Fe content. SIMT occurred in all three alloys and was influenced by the presence of βm (metastable beta) and beta stability. As the Fe content decreased, the α'' phase increased due to SIMT occurring within the βm phase, resulting in softening. Conversely, as the Fe content increased, the strength of the alloy increased due to a reduction in α'' formation and the contributions of solid solution strengthening and grain strengthening. Moreover, unlike the other alloys, shear bands were observed only in the fracture of the Ti-5Mo-4Fe alloy, which was attributed to differences in texture and microstructure.

The Effect of Deformation Induced Phase on Tensile Properties and Fatigue Behavior of Austenitic High Mn steel (오스테나이트계 고망간강에서 인장 특성과 피로거동에 미치는 변형유기상의 영향)

  • Choi, S.M.;Kwun, S.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.4
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    • pp.277-287
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    • 1994
  • The effect of grain size on the tensile properties and fatigue behavior of austenitic high Mn steel has been investigated. The recrystallized austenite grain size of the cold rolled high Mn steel was increased as the annealing temperature increased from $600^{\circ}C$ to $1000^{\circ}C$. Larger austenite grain size decreased the yield strength and the tensile strength, and increased the uniform elongation due to transformation of some austenite into twins or E-martensite phase during deformation. Austenite grain refinement increased the tendency to form dislocation cells, instead. The specimen annealed at $1000^{\circ}C$ with large grain size showed lower fatigue crack propagation rate in low ${\Delta}K$ region due to rougher fracture surface caused by formation of deformation twins during fatigue at the crack tip region.

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Effect of Internal Stress due to Plastic Costraint On Fracture Ductility of Dual Phase Steel (複合組織鋼 의 破斷延性 에 미치는 塑性拘束 에 의한 內部應力 의 영향)

  • 김정규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.7 no.2
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    • pp.123-129
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    • 1983
  • The effect of the micro-internal stress which is induced in the ferrite grain by plastic constraint, on fracture behavior was investigated. The specimen used has combined microstructure with matrix of ferrite encapsulated by second phase of martensite. The micro-internal stress in the ferrite grain was estimated using a simple mechanical model, and its effect on micro and macro fracture behaviors was discussed. The results obtained are summarized as follows; The micro-internal stress promotes the formation of cleavage cracks in the ferrite during deformation. Consequently, it was concluded that the internal stress is one of the significant factors which cause the fracture ductility to decrease.

Analysis of Hardenability for Carbon Steel using Finite Element Method(II) (유한요소법을 이용한 탄소강의 경화능해석(II))

  • Kim, O.S.
    • Journal of Power System Engineering
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    • v.3 no.3
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    • pp.76-82
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    • 1999
  • This study presents a methodology to predict the hardenability of quenched carbon steels. The equation of transient heat conduction is analyzed to formulate a cooling curve by a finite element method which incorperates coupled effects of temperature on physical properties, the metallic structures and also the latent heat by phase transformation. The volume traction of martensite and pearlite are the structural analysis for hardenability analysis. In order to demonstrate the feasibility of adopting a full quench model respectively. This procedure could be used as the database for optimal condition of heat treatment processes.

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Characteristics of Ti-Ni-(XCu) Shape Memory Alloy Powders made by Gas Atomization Process (가스 분무법으로 제조한 Ti-Ni-XCu 형상기억합금분말의 특성)

  • 징동훈
    • Journal of Powder Materials
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    • v.6 no.2
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    • pp.171-177
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    • 1999
  • Ti-45.2at.%Ni-5at.%Cu and Ti-40.2at.%Ni-10atat.%Cu alloy powders were fabricated by gas atomization process. The microstructures, Shape, hardness and phase transformation behaviors of the powders were investigated by means of optical microscopy, scanning electron microscopy, micro-hardness measurement, x-ray diffraction analyses and differential scanning calorimetry. The hardness of the Ti-Ni-XCu alloy powders decreased as Cu-content increased. The x-ray diffraction analyses were carried out for powders without heat treatment, and those that treated at 85$0^{\circ}C$ for an hour in a vaccum state($10^5$ torr) and then quenched into ice water. The intensity of B$19^t$ phase increased with heat treating. The monoclinic B$19^t$ martensite was formed in the Ti-Ni-XCu alloy powders during cooling.

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The Sliding Wear behavior of Fe-Cr-C-Si Alloy in Pressurized Water (Fe-Cr-C-Si 계 경면처리 합금의 고압ㆍ수중 마모거동)

  • Lee, Kwon-yeong;Lee, Min-Woo;Oh, Young-Min;;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.224-227
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    • 2003
  • The sliding wear behavior of a Fe-base hardfacing alloy was investigated in the temperature range of $25∼250^{\circ}C$ under a contact stress of 15 ksi (103 MPa). The wear loss of this Alloy in pressurized water was less than that of NOREM 02. And galling did not occurred at this alloy in all temperature ranges. It was considered that the wear resistance of this Alloy was attributed to the strain-induced phase transformation from austenite to $\alpha$'martensite during sliding wear.

An Analysis Finite Element for Elasto-Plastic Stresses Considerating Phase Transformation at the Quenching Process(II) -From Austenite to Martensite- (퀜칭과정에서 상변태를 고려한 탄소성 열응력의 유한요소 해석(II) -오오스테나이트에서 마르텐사이트로의 변태-)

  • Kim, O.S.;Song, G.H.;Koo, B.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.12-23
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    • 1995
  • In this a set of constitutive equation relevant to the analysis of thermo-elasto-plastic materials with phase transformation during quenching process was presented on the basis of continuum thermo-dynamic. In calculating the transient thermal stresses, temperature between coolant and specimen(SM45C) surface was determined from the heat transfer coefficient. A calculation was made for specimen with 40mm in diameter quenched in coolant from $820^{\circ}C$ and the results are as follow. Stresses at starting point of transformation always show the maximum tensile value. Reverse of stresses takes place after completion of transformation of inner part at specimen.

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Investigation on the phase transition of $Ni_2$MnGa alloy by using impedance spectroscopy

  • Park, S.Y.;Cho, K.H.;Lee, Y.P.
    • Journal of Korean Vacuum Science & Technology
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    • v.7 no.1
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    • pp.13-17
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    • 2003
  • The influence of structural transition on the resistance and impedance behavior of Ni$_2$MnGa alloy was investigated. The temperature-dependent resistance and impedance were measured in a temperature range of 4 - 350 K and 185 - 300 K, respectively. The dependence of temperature coefficient of resistivity on temperature shows a kink at 220 K, which is related to the structural transition. The change in dominant scattering mechanism results in the observed kink. Significant increases were also observed around the transition temperature for both real and imaginary parts of impedance. It is thought that this phenomenon originates from disappearance of the martensite twin boundaries during the structural transformation.

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