• Journal of the Korean earth science society
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• v.23 no.8
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• pp.697-706
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• 2002

Authigenic siderite grains, ranging 100 to 250-${\mu}$m in diameter, are abundant in an about 8,600-year-old sediment layer in Namyang Bay, west coast of Korea. The siderites exhibit the aggregated spherulitic morphology with well-developed rhombs on the grain surfaces. They consist mostly of FeCO$_3$ (average, 65%) and MnCO$_3$ (average, 22%) with low Mg/Ca ratio (less than 0.4) in their bulk composition. A series of compositional ternary discrimination diagrams, together with high Mn and low Mg contents, show that only meteoric porewater was involved in siderite precipitation, assuming that depositional environment of host sediment is an organic-rich freshwater system. Considering a series of results such as radiocarbon age, authigenic Mn-rich siderite and lithological features, siderite-hosting sediment (unit Tl) is interpreted as freshwater swamp or bog deposition, infilling the topographic depressions that locally existed before the formation of mid-to-late Holocene tidal deposits. Center-to-margin compositional variation within individual grain is very systematic; Mn and Ca decrease towards the margin of a siderite grain, while Fe and Mg increase. It suggests that the spherulitic siderites were precipitated in this sedimentary layer in a series during the early diagenesis of MnOx-FeOx reduction under steady-state.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.663-666
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• 2005

Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately $300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed.

• Journal of the Mineralogical Society of Korea
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• v.15 no.3
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• pp.231-240
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• 2002

Microbial metal reduction influences the biogeochemical cycles of carbon and metals as well as plays an important role in the bioremediation of metals, radionuclides, and organic contaminants. The use of bacteria to facilitate the production of magnetite nanoparticles and the formation of carbonate minerals may provide new biotechnological processes for material synthesis and carbon sequestration. Metal-reducing bacteria were isolated from a variety of extreme environments, such as deep terrestrial subsurface, deep marine sediments, water near Hydrothemal vents, and alkaline ponds. Metal-reducing bacteria isolated from diverse extreme environments were able to reduce Fe(III), Mn(IV), Cr(VI), Co(III), and U(VI) using short chain fatty acids and/or hydrogen as the electron donors. These bacteria exhibited diverse mineral precipitation capabilities including the formation of magnetite ($Fe_3$$O_4$), siderite ($FeCO_3$), calcite ($CaCO_3$), rhodochrosite ($MnCO_3$), vivianite [$Fe_3$($PO_4$)$_2$ .$8H_2$O], and uraninite ($UO_2$). Geochemical and environmental factors such as atmospheres, chemical milieu, and species of bacteria affected the extent of Fe(III)-reduction as well as the mineralogy and morphology of the crystalline iron mineral phases. Thermophilic bacteria use amorphous Fe(III)-oxyhydroxide plus metals (Co, Cr, Ni) as an electron acceptor and organic carbon as an electron donor to synthesize metal-substituted magnetite. Metal reducing bacteria were capable of $CO_2$conversion Into sparingly soluble carbonate minerals, such as siderite and calcite using amorphous Fe(III)-oxyhydroxide or metal-rich fly ash. These results indicate that microbial Fe(III)-reduction may not only play important roles in iron and carbon biogeochemistry in natural environments, but also be potentially useful f3r the synthesis of submicron-sized ferromagnetic materials.

• Journal of fish pathology
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• v.6 no.2
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• pp.205-218
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• 1993

On the development of hirame(Paratichtys olivaceus) culture, outbreak of scuticociliata infection was reported to cause severe damage in Japan. To establish effective measures for isolation and cultivation of this ciliate, we tried to culture this pathogenic ciliate using medium for bacteria and fish cell lines in vitro. Scuticociliata from the brain tissues of infected fish was aseptically inoculated to CHSE-214 cells cultured in MEM-10 without antibiotic. Scuticociliata grew well and the number of ciliate reached $10^6\;cells/ml$ at temperatures of $15^{\circ}C$ to $20^{\circ}C$ for 10d. The number of ciliate cultured in the cell lines is 10 times higher than the numbers cultured in the liquid medium alone. This ciliata could be cloned by dilution method. Scuticociliata isolated could grow well on 42 different cell lines that were established from marine fish, warm freshwater fish, and salmonids. This ciliate could be preserved in liquid nitrogen for more than 6 months. Subsequently, we observed the optimal temperature and salinity for growth, and tested the sensitivities of this organism to formaldehyde, flagyl(Metronidazole), Ekuteshin(Combination compound of sulfamonometoxin and ormethoprim), and ozonixation. Optimal temperature for growth was $25^{\circ}C$ and salinity was 1.0 to 1.5%. Washed scuticociliata was killed by formaldehyde at the concentration of 50ppm for 10min, but was not completely killed even at a high concentration of 400ppm for 20min in MEM-5. Flagyl and Ekuteshin can inhibit the growth of scuticociliata at the concentration of 1,000 and $100{\mu}g/ml$ in MEM-10, respectively. More than 99% of this scuticociliata could be killed by ozonization at a dose equivalent to $1.0mg/\ell$ oxidant for 30sec in sea water. Isolated scuticociliata showed the pathogenicity to the cultured hirame by artificial infection(I. P. injection, $10^5\;cells$/fish). The number of scuticociliata in the water could be counted by most probable number(MPN) method using tissue culture, and the minimum detectable number was $1.8\;cells/\ell$. The number in the reservoir tank for water supply to the culture tank was 110 cells/l. After cleaning by elimination of the sediments from of the reservoir tank and disinfected with formaldehyde, number of scuticociliata decreased and was counted less than $1.8\;cells/\ell$ and infection rate of cultured hirame was decreased.

• Korean Journal of Environmental Biology
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• v.22
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• pp.47-53
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• 2004

Among the phthalic esters, di-butyl phthalate (DBP) and di-2-ethylhexyl phthalate (DEHP), which are categorized endocrine disrupting chemicals, account toy up to 80％ of the world production. Nine phthalic esters were quantitatively determined in water and in sediment samples from Gawngyang Bay and Seomjin River estuary. This might be the first report in contamination of phthalates in the marine environment of Korea. DBP and DEHP were detected with the high concentration and high frequency, while the other phthnlic compounds were below the detection limits. The aveyage concentyations of DBP and DEBP in sediment from Gawngyang Bay were 33.8 ng g$\^$-1/ and 67.4 ng g$\^$-1/ on a dry weight basis, respectively. The concentrations in surface watey from Seomjin River estuary were in the range of 62.7∼333.8 ng L$\^$-1/ for DBP and 25.6 ng L$\^$-/∼116.1 ng L$\^$-1/ for DBHP. In sediments from Seomjin River estuary, DBP ranged 9.1∼149.3 ng g$\^$-1/, and DEHP 46.3∼156.3 ng g$\^$-1/. Phthalic esters concentrations found in Seomjin River estuary were much less than those in other rivers in Korea. Distribution pattern of DBP and DEHP concentrations in Seonliin River estuary indicates that both compounds aye introduced to Gwangyang Bay through run-off.

• Economic and Environmental Geology
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• v.45 no.4
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• pp.407-429
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• 2012

There has been much debates on the geologic age of the sediments of the Domi Basin, since age results varied after research methods and fossil groups. This study carried out palynological analysis and seismic interpretation to establish a stratigraphy and environmental reconstruction mainly based on fossil dinoflagellates and Seismic data from the Domi-1 and Sora-1 wells. The dinocyst assemblages found enabled zonation of the well sediment sequence resulting in 4 ecozones. Index fossils among dinocysts and palynomorphic substances indicate geologic age of the well ranges from Eocene to Pleistocene, and paleoenvironment varies from freshwater to inner-neritic marine. The fossil association also suggests strong relationship to Japanese Tertiary basins in Kyushu area in terms of stratigraphy and basin developmental history.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.41 no.1
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• pp.46-53
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• 2005

This paper describes the mean grain size and shear strength properties related to subsidence characteristics using sediment samples and acoustic images obtained from artificial reef areas in Tongyoung and Jangsungpo offshore. The acoustic images collected from chirp sonar and side scan sonar show well the attitude/orientation, the distribution pattern, and the degree of subsidence of artificial reefs, suggesting the possibility of suitable site investigation and the management of the reefs using acoustic sonar. The sediments were largely composed of clayey silt and silty clay. The mean grain sizes in Tongyoung and Jangsungpo offshore show the ranges of 5${\sim}$9${\Phi}$ and 8${\sim}$9${\Phi}$, respectively. The shear strength was significantly increased at the depths of 20cm in Tongyoung offshore and 80cm in Jangsungpo offshore, corresponding to the subsidence depth of artificial reefs. The relationship between mean grain size and shear strength did not show a correlation, suggesting the shear strength does not totally depend on mean grain size. Provided subsidence characteristics with respect to various artificial reefs and seabed condition are investigated in more details, the constructing area of the reef can be more extended.

• Ocean and Polar Research
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• v.28 no.1
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• pp.1-12
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• 2006

Analyses of sedimentological and geochemical parameters from two radiocarbon-dated sediment cores (JM98-845-PC and JM98-818-PC) retrieved from the central part of Isfjorden, Svalbard, in the Arctic Sea, reveal detailed paleoclimatic and paleoceanographic histories over the last 15,000 radiocarbon years. The overconsolidated diamicton at the base of core JM98-845-PC is supposed to be a basal till deposited beneath pounding glacier that had advanced during the LGM (Last Glacial Maximum). Deglaciation of the fjord commenced after the glacial maximum, marked by the deposition of interlaminated sand and mud in the ice-proximal zone by subglacial meltwater discharge, and prevailed between 13,700 and 10,800 yr B.P. with enriched-terrigenous organic materials. A return to colder conditions occurred at around 10,800 yr B.P. with a drop in TOC content, which is probably coincident with the Younger Dryas event in the North Atlantic region. At this time, an abrupt decrease of TOC content as well as an increase in C/N ratio suggests enhanced terrigenous input due to the glacial readvance. A climatic optimum is recognized between 8,395 and 2,442 yr B.P., coinciding with 'a mid-Holocene climatic optimum' in Northern Hemisphere sites (e.g., the Laurentide Ice sheet). During this time, as the sea ice receded from the fjord, enhanced primary productivity occurred in open marine conditions, resulting in the deposition of organic-enriched pebbly mud with evidence of TOC maxima and C/N ratio minima in sediments. Fast ice also disappeared from the coast, providing the maximum of IRD (ice-rafted debris) input. Around 2,442 yr B.p. (the onset of Neoglacial), pebbly mud, characterized by a decrease in TOC content, reflects the formation of more extensive sea ice and fast ice, which might cause decreased primary productivity in the surface water, as evidenced by a decrease in TOC content. Our results provide evidence of climatic change on the Svalbard fjords that helps to refine the existence and timing of late Pleistocene and Holocene millennial-scale climatic events in the Northern Hemisphere.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.8
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• pp.579-592
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• 2020

This study was designed to assess the water quality and phytoplankton community including chlorophyll a in blood cockle (Tegillarca granosa) farms in May, August and November of 2017 in the northwestern Yeoja Bay, Korea. As a result, the seasonal characteristics of water types by water temperature and salinity were clear. Nutrients were abundant in silicate throughout the season, but phosphate was scarce in spring and summer, and nitrogen sources were scarce in autumn. The species composition of phytoplankton community was a very simple distribution, and the standing crop was also very low. The annual dominant species is dominated by the diatoms, with Skeletonema costatum-ls, Nitzschia longissima in spring, Pleurrosigma normanii, Coscinodiscus gigas in summer, and N. longissima, Pseudonitschia pungens, Chaetoceros curvisetus, Eucampia zodiacus in autumn. In summer the results were different from other coastal waters of Korea. The principal component analysis(PCA) and correlation analysis showed that the characteristics of water quality and biological environments differed according to the season. Furthermore, it was determined by the supply of materials through fresh water on land, seawater congestion caused by the refueling of surface sediments with lower depth, and the balance of biological production and mineralization of organic matters in blood cockle farms.

• Journal of Environmental Science International
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• v.18 no.3
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• pp.245-254
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• 2009

In recent years, environmental pollution by phannaceuticals and personal care products (PPCPs) in the aquatic environment is of great concern worldwide. Recent studies have been reported to occur in a variety of environmental organisms such as surface, drinking and ground water, soils, sediments and hospitals. The purpose of this study was to evaluate the occurrence and environmental behavior of fourteen human PPCPs in surface waters of Mankyung River in South Korea. We were conducted to field survey for water quality and PPCPs analysis at November, 2006. PPCPs were analyzed by liquid chromatograph coupled with a tandem mass spectrometer (HPLC-MS/MS). The concentration of COD was measured to be 2.37$\sim$19.71 mg/L, which was belong to 4$\sim$5 grade in water quality criteria of lake. Station 2 that there is no pollution in upper stream, was appeared to lower concentration. The concentration of TN and TP, that is cause matter of eutrophication, were found to be 7.78$\sim$35.42 mg/L and 0.08$\sim$0.95 mg/L, respectively, which were exceeding 5 grade in Lake water quality criteria. The 11 kind of PPCPs compounds except levofloxacin and triclosan were detected to Mankyung river. PPCPs concentrations of STP(Sewer Treatment Plant) effluents and aquatic environment in Mankyung river have been detected in the range from dozens of ng/L to hundreds of ${\mu}g/L$ that by order of atenolol, carbamazepine, propranolol, Ibuprofen, erythromycin, ifenprodil, clarithromycin, mefenamic acid, fluconazole, indomethacin, disopyramide. PPCPs concentration of Station 1 and 5, which was influenced by Jeonju STP and Wanju STP, was detected high values. Station 2 that there is no pollution, showed lower values. Station 3 which joined Gosan stream and Jeonju stream and station 4 which influenced by stock wastewater was detected to low values.