• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.416-420
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• 2018

A comprehensive kinetic study has been conducted on dimethyl carbonate synthesis by transesterification reaction of ethylene carbonate with methanol. An alkali base metal (KOH) was used as catalyst in the synthesis of DMC, and its catalytic ability was investigated in terms of kinetics. The experiment was performed in a batch reactor at atmospheric pressure. The reaction orders, the activation energy and the rate constants were determined for both forward and backward reactions. The reaction order for forward and backward reactions was 0.87 and 2.15, and the activation energy was 12.73 and 29.28 kJ/mol, respectively. Using the general factor analysis in the design of experiments, we analyzed the main effects and interactions according to the MeOH/EC, reaction temperature and KOH concentration. DMC yield with various reaction conditions was presented for all ranges using surface and contour plot. Furthermore, the optimal conditions for DMC yield were determined using response surface method.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.7 s.172
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• pp.54-61
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• 2005

A simulator for virtual laser machining is developed to help understanding and predicting the effects of machining parameters on the final machined results. Main program is based on the model for polymer ablation with short pulse excimer lasers. Version f of the simulator is built using Visual Fortran to make the user work under visual environment such as Windows on PC, where the important machining parameters can be input via dialog box and the calculated results for machined shape, beam fluence, and temperature distribution can be plotted through the 2-D graphics windows. Version II of the simulator is built using HTML, CGI and JAVA languages, allowing the user to control the input parameters and to see the results plot through the internet.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.79.3-80
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• 2016

We have investigated the correlation analysis between global temperature anomaly and two main factors: geomagnetic activity (aa index) of Earth external factor and CO2 of Earth internal factor. For this, we used NOAA Global Surface Temperature anomaly (Ta) data from 1868 to 2015. The aa index indicates the geomagnetic activity measured at two anti-podal subauroral stations (Canberra Australia and Hartland England) and the CO2 data come from historical ice core records and NOAA/ESRL data. From the comparison between (Ta) and aa index, we found several interesting things, First, the linear correlation coefficient between two parameters increases until 1985 and then decreases rapidly. Second, the scattered plot between two parameters shows a boundary of the correlation tendency (positive and negative correlation) near 1985. A partial correlation of (Ta) and two main factors (aa index, CO2) also shows that the geomagnetic effect (aa index) is dominant until about 1985 and the CO2 effect becomes much more important after then. These results indicate that the CO2 effect become very an important factor since at least 1985. For a further analysis, we simply assume that Ta = Ta(aa)+Ta(CO2) and made a linear regression between (Ta) and aa index from 1868 to 2015. A linear model is then made from the linear regression between energy consumption (a proxy of CO2 effect) and Ta-Ta(aa) since 1985. Our results will be discussed in view of the prediction of global warming.

• Research in Plant Disease
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• v.12 no.3
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• pp.240-248
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• 2006

Control of white rot which is one of the most serious apple diseases in Korea has mainly relied on periodical spray of protective fungicides. As the main inoculum source of the disease is pycnidiospores produced in the warts formed on affected stems of apple tree, it can be conceivable that inhibition of spore production might be an effective means for controlling the disease. Inhibitory efficacy of eight selected fungicides against sporulation of the fungus was assessed by counting the number of spores produced at detached warts treated with the fungicides of recommended dilution. They showed diverse effect on sporulation. Carbendazim and azoxystrobin suppressed sporulation almost completely, the former irreversively. Thiram and folpet promoted sporulation as producing much more number of spores than untreated control. Others showed almost no effect on sporulation. Effects of suppression and promotion in the sporulation shown by the fungicides on the control of white rot were examined by incidences of disease and infection at the plots adopted the spray programs of which the fungicide at late May was substituted by carbendazim, azoxystrobin, folpet and thiram, respectively. Disease incidence and infection frequency at the plots sprayed former two chemicals which suppressed sporulation were much lower than those of the plots adopted latter two chemicals and untreated plot at which the fungicide spray was skipped at that time. These facts were reconfirmed in the experiments conducted with carbendazim and thiram, in which 100 fruits were bagged just prior to each spray from late May to late July for elucidating the effect of the two fungicides on the action of subsequent ones. Disease incidence and infection frequency on the fruit bagged just prior to each spray were gradually increased as the seasons going on. The increase rate at the carbendazim plot was much lower than that of thiram. Especially, the fruit infected till late July at the carbendazim plot were almost completely cured by the three fungicides, iminoctadine-triacetate, tebuconazole and samzinwang, a combined formular of iminoctadine-triacetate and difenoconazole, sprayed at late July and hence. In thiram plot, infected fruit were also cured by the 3 fungicides but not remarkable. From these results, it can be concluded that control efficiency of white rot can be greatly enhanced by selecting the fungicide capable of suppress the sporulation of white rot fungus at the season when the mass dispersal of spores is not initiated.

• Magazine of the Korean Society of Agricultural Engineers
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• v.12 no.2
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• pp.1937-1947
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• 1970

This experiment was conducted, making use of the 'NONG-RIM No, 6' a recommended variety of rice plant for the year of 1969. Main purpose of the experiment are to explore possibilities of; a) ways and means of saving irrigation water and, b) overcoming drought at the same time so that an increaded yield in rice production could be resulted in Specifically, it was tried to determine the effects of the Rotation Irrigation method combined with differentiated thickess of Lining upon the growth and Yield of rice production. Some of the major finding are summarized in the follows. 1) The Different thicknesses show a significant relationship with the weight of 1000 grains. In the case of 3cm Lined plot, the grain weight is 39.0 Grams, the heaviest. Next in order is 6 cm lined plnt, 5 day control plot, 6 day control plot. 2) In rice yield, it is found that there is a considerably moderate signicant relationship with both the different thickness of lining and the number of irrgation, as shown in the table No,7. 3) There is little or no difference among different plot in terms of; a) physical and chemical properties of soil, b) quality of irrgation water, c) climatic condition, and rainfalls. 4) It is found that there is no significant relationship between differences in the method of rotation irrgation and the number of ears per hill because of too much rainydays and low temperature during irrigation season. 5) In uyny1-treated plots, it is shown that there is on difference among different plots, but the irrigation water requirement saved as much as 1/2 to actual irrigation water compare to uncontroled plot. 6) The irrigation water requirement for 48 days is saved as much 67% compared to uncontroled plot, the order are; the 9cm lined plot, the plot of vinyl with no hole, the plot with a hole of $1cm/m^2$ as shows in fig 15. 7) The rate of percolation of 40-30mm/day is decreased to 30-20/day. It is found that the decreasad rate of percolation due to vinyl-cutoff in footpath. 8) The growing condition was fine, and there was no found that decease and lageing as always submerged plot. 9) It is found that it must be constructed irrigation and drainage system, inlet and outlet perpect, respectly, of which could be irrigation water saved and would be inereased the irrigation water temperature.

• Journal of The Korean Society of Grassland and Forage Science
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• v.21 no.4
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• pp.191-202
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• 2001

Experiments were conducted on established grassland sward at Gongiam, Kwangju, and Kyung-gi in Korea from 1995 to 1997. The influence of mineral-N fertilizer or animal manure(AW) on herbage dry matter(DM) yield, N yield, the recovery of AM-N, and soil N and organic matter(0M) content in the mixed sward('potomac' orchardgrass, 'fawn' tall fescue, and 'kenblue' Kentuky bluegrass) was investigated. The treatments were replicated three times in a split plot block design. AM(the main plots) was applied at 200kg N ha ' year ' on each plot. The types of AM were cattle feedlot manure(CFM), pig manure fermented with sawdust(PMFS) and Korea native cattle slurry(KNCS). Three levels of mineral-N fertilizer, as urea, ranging from 0 to 200kg N $ha^{-1}\;year^{-1}$ in 100kg increments, were superimposed on each plot. The fertilizers and AM were applied in two equal dressings(the end of March and middle of November). AM and mineral fertilizer had significant effects(p<0.05) on herbage DM and N yields. Herbage yields in KNCS were higher than those in CFM and PMFS(p

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.6
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• pp.533-539
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• 2014

Mine wastes such as acid mine drainage (AMD) can cause the detrimental effects on surrounding environment, thereby eventually threatening human health. Main objective of this study was to evaluate the neutralizing effect of fly ash (FA) as a stabilizing material AMD. Field plot was constructed in a coal waste depot which has caused aluminium-whitening adjacent to the stream. Different mixing ratios of FA were applied on a top of the soil, and then the physicochemical properties of runoff and soil were monitored. Constructed plots were as following: control (mine waste only (W)), mine waste + 20% ($w\;w^{-1}$)of FA (WC20M), mine waste + 40% ($w\;w^{-1}$)of FA (WC40M), and WC40M dressed with a fresh soil at the top (WC40MD). Result showed that initial pH of runoff in control was 5.09 while that in WC40M (7.81) was significantly increased. For a plot treated with WC40M, the concentration of Al in runoff was decreased to $0.22mg\;L^{-1}$ compared to the W as the control ($4.85mg\;L^{-1}$). Moreover, the concentration of Fe was also decreased to less than half at the WC40M compared to the control. Application of FA can be useful for neutralizing AMD and possibly minimizing adverse effect of AMD in mining area.

• Journal of The Korean Society of Grassland and Forage Science
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• v.20 no.2
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• pp.115-122
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• 2000

This study was carried out to determine a fertilization rate for productivity and nutritive value improvement of silage corn, using two kinds of composts, and to examine the potential possibility of utilization as an organic fertilizer. The experiment was conducted on the field plot at Gongiam, Kwangju, Kyunggi-Do for 3 years, from 1996 to 1998, and arranged in split-plot design with three replications. The main plots were two kinds of composts such as swine manure fermented with sawdust (SMFWS) and swine manure fermented without sawdust (SMF). Subplots were the nitrogen fertilization rates (0, 100, 200, 300 and 400kgN/ha/year). The dry matter (DM) yield increased as the nitrogen fertilization rate increased up to a rate of 300 kg N/ha, but decreased at rate of 400 kg N/ha. Dry matter yield in SMFWS treatment was higher than that of SMF treatment, but there was no significant difference between SMFWS and SMF treatments. Net energy for lactation (NEI) and total digestible nutrients (TDN) in corn increased as the fertilization rate of SMFWS and SMF increased, and crude protein (CP) content increased by the fertilization of SMFWS and SMF. No difference of CP, NEI and TDN was found between SMFWS and SMF treatments.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.29 no.1
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• pp.50-54
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• 1984

To study the effects of planting dates and mulching on the growth and yield of summer type soybean, a variety, Damamidori introduced from Japan, was planted four times from April 13 with 10 days interval. Experimental plot in each planting date was devided into two sub-plots, polyethylene film mulching and non-mulching. By mulching, days to emergence and first flowering were shortened, especially in the early plantings; e.g. as much as 11 and 12 days, respectively, in the first planting. Compared to non-mulching, plant height, number of nodes of main stem, number of branches, and dry weight of stem and branches per unit area were also much increased by mulching. As the plantings were delayed, plant height, the total number of nodes and dry weight of main stem and branches, and 100 seed weight showed increasing trends, which were mainly due to lower infection rate of soybean seeds to pod and stem blight (Diaporthe phaseolorum) in the later plantings. The higher infection rate of soybean seeds to pod and stem blight, the lower infection rate to purple seed stain (Cercospora kikuchii) was shown in mulching but not in non-mulching.

• Korean Journal of Weed Science
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• v.7 no.1
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• pp.52-57
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• 1987

To know the effects of weeding periods (weeding from 12 days, 28 days and 42 days after seeding to harvest, and weeding from seeding to 14 days, 28 days and 42 days after seeding) and growing conditions such as transparent polyethylene film mulch (P.E. mulch) and bare soil on growth and yield of peanuts, "Yeongho-Tangkong" was planted on May 10, 1984. Under P.E. mulch, the number of weeds was higher, but the weed dry weight was lower than in bare soil by the middle of July. Sixty days after seedings, the length of main stems in weedy check plots was longer, but shoot dry weight was lower compared to weed free plot. In the correlation coefficients between weed dry weight and the shoot dry weight of peanut on July 14, the growth retardation of peanuts due to weeds was showed earlier under P.E. mulch than in bare soil. Shoot dry weight, shelling ratio, number of seeds per pod, 100 pod weight, and seed yield were higher under P.E, mulch compared to bare soil. But weed dry weight, length of branches, number of pod bearing branches, number of pods per square meters, and pod yield were similar between P.E. mulch and bare soil. Shoot dry weight of peanuts, length of branches, number of pod bearing branches, number of pods per square meters, pod yield, 100 pod weight, 100 seed weight, and seed yield in weed free plots from 28 days after seeding to harvest (28 DAS-Harvest) were higher compared to weed free plots from 42 DAS-Harvest. However, in the weed free plot from seeding to 42 days after seeding seed yield was lower than that of the continuous weeding plot due to lower number of pod bearing branches and number of pods per square meters. When weed was not controlled at the later growth stages of peanuts, reduction in seed yield due to weeds was greater in bare soil than that under P.E. mulch.