• Title/Summary/Keyword: Magnesium ($Mg^{++}$)

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Preparation of Mg(OH)2-Melamine Core-Shell Particle and Its Flame Retardant Property (멜라민이 코팅된 수산화마그네슘 입자의 제조와 그 복합입자의 난연특성)

  • Lim, Hyung-Mi;Yoon, Joon-Ho;Jeong, Sang-Ok;Lee, Dong-Jin;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.20 no.12
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    • pp.691-698
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    • 2010
  • Magnesium hydroxide-melamine core-shell particles were prepared through the coating of melamine monomer on the surface of magnesium hydroxide in the presence of phosphoric acid. The melamine monomer was dissolved in hot water but recrystallized on the surface of magnesium hydroxide by quenching to room temperature in the presence of phosphoric acid. The core-shell particle was applied to low-density polyethylene/ ethylene vinyl acetate (LDPE/EVA) resin by melt-compounding at $180^{\circ}C$ as flame retardant. The effect of magnesium hydroxide and melamine content has been studied on the flame retardancy of the core-shell particles in LDPE/EVA resin according to the preparation process and purity of magnesium hydroxide. Magnesium hydroxide prepared with sodium hydroxide rather than with ammonia solution revealed higher flame retardancy in core-shell particles with LDPE/EVA resin. At 50 wt% loading of flame retardant, core-shell particles revealed higher flame retardancy compared to that of the exclusive magnesium hydroxide in LDPE/EVA composite, and it was possible to satisfy the V0 grade in the UL-94 vertical test. The synergistic flame retardant effect of magnesium hydroxide and melamine core-shell particles was explained as being due to the endothermic decomposition of magnesium hydroxide and melamine, which was followed by the evolution of water from the magnesium hydroxide and porous char formation due to reactive nitrogen compounds, and carbon dioxide generated from melamine.

Electrode Life Test of Resistance Spot Welding on Mg Alloy Using Dome Type Electrode (돔형 전극을 사용한 마그네슘 합금 저항 점용접의 전극 수명 평가)

  • Choi, Dong-Soon;Hwang, In-Sung;Kim, Dong-Cheol;Kang, Moon-Jin
    • Journal of Welding and Joining
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    • v.31 no.6
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    • pp.27-31
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    • 2013
  • Magnesium alloy is used on parts of aircraft and electronic equipment because of the highest specific strength among the common metal materials. Recently, studies about appling magnesium alloy sheet to automotive bodies are on the increase rapidly. For application to automotive bodies, researches about characteristics of resistance spot welding of magnesium alloy sheet are essential. Magnesium alloy has low boiling point, so getting sound bead shape is difficult when appling varies welding processes. Resistance spot welding is also particular about setting optimum welding conditions because of spatter generation, pores and cracks occurrence in nugget. And life of electrodes is very short because of alloying with copper that main material of electrodes. This requires frequent dressing and replacement of electrodes and decrease in productivity of resistance spot welding on magnesium alloy. Therefore in this study, for effective analysis of changes in tensile shear load and nugget size during electrode life test, evaluate detail characteristics of resistance spot welding on magnesium alloy sheet using dome type electrode.

Effects of Supplementary Blood Meal on Carnosine Content in the Breast Meat and Laying Performance of Old Hens

  • Namgung, N.;Shin, D.H.;Park, S.W.;Paik, I.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.7
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    • pp.946-951
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    • 2010
  • The objective of this research was to evaluate the effects of dietary supplementation of blood meal (BM) as a source of histidine, and magnesium oxide (MgO) as a catalyst of carnosine synthetase, on carnosine (L-Car) content in the chicken breast muscle (CBM), laying performance, and egg quality of spent old hens. Four hundred eighty laying hens (Hy-Line$^{(R)}$ Brown), 95wk old, were allotted randomly into five replicates of six dietary treatments: T1; 100% basal diet, T2; 100% basal diet+MgO, T3; 97.5% basal diet+2.5% BM, T4; 97.5% basal diet+2.5% BM+MgO, T5; 95% basal diet+5% BM, T6; 95% basal diet+5% BM+MgO. Magnesium oxide was added at 0.3% of diets. The layers were fed experimental diets for 5wk. There were no significant differences in the weekly L-Car content in CBM among all treatments during the total experimental period, but some of the contrast comparisions showed higher L-Car in CBM of T6. The L-Car contents linearly decreased (p<0.01 or p<0.05) as the layers got older except in T4 (p>0.05). There were significant differences in egg weight (p<0.01) and soft and broken egg ratio (p<0.05). The control (T1) was highest in egg weight and T6 was lowest in soft and broken egg ratio. Among the parameters of egg quality, there were significant differences in eggshell strength (p<0.01) and egg yolk color (p<0.05). Magnesium oxide supplementation increased the eggshell strength and BM tended to decrease egg yolk color. Eggshell color, eggshell thickness, and Haugh unit were not influenced by BM and MgO. In conclusion, BM and MgO did not significantly influence the L-Car in CBM of spent layers. The L-Car content rapidly decreased as the layers became senescent. Eggshell strength was increased by MgO supplementation.

Polarization of THP-1-Derived Macrophage by Magnesium and MAGT1 Inhibition in Wound Healing

  • Mun Ho Oh;JaeHyuk Jang;Jong Hun Lee
    • Archives of Plastic Surgery
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    • v.50 no.4
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    • pp.432-442
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    • 2023
  • Background Macrophages play a major role in wound healing and prevent infection from the outside. Polarization conversion of macrophages regulates aspects of inflammation, and two macrophages, M1 (classically activated) and M2 (alternatively activated), exist at both ends of broad-spectrum macrophage polarization. Thus, we aimed to investigate whether macrophage polarization can be artificially regulated. To this end, MgSO4 and small-interfering RNA (siRNA) targeting magnesium transport 1 (MAGT1) were used to investigate the effects of intracellular magnesium (Mg2+) concentrations on the differentiation of macrophages in vitro. Methods THP-1 derived macrophages maintained in a culture medium containing 5 mM MgSO4 and siRNA to inhibit the expression of MAGT1. As comparative groups, THP-1 derived macrophages polarized into M1 and M2 macrophages by treatment with M1, M2 inducer cytokine. The polarization status of each group of cells was confirmed by cell surface antigen expression and cytokine secretion. Results We found that MgSO4 treatment increased CD163 and CD206, similar to the effect noted in the M2 group. The expression of CD80 and HLA-DR was increased in the group treated with MAGT1 siRNA, similar to the effect noted in the M1 group. Functional assays demonstrated that the group treated with MgSO4 secreted higher levels of IL-10, whereas the MAGT1 siRNA-treated group secreted higher levels of IL-6 cytokines. Additionally, the conditional medium of the Mg2+ treated group showed enhanced migration of keratinocytes and fibroblasts. Conclusion Mg2+ can help to end the delay in wound healing caused by persistent inflammation in the early stages.

Dynamic Stiffness and Frequency Response Analysis for the Development of Magnesium Oil Pans (마그네슘 합금 오일팬 개발을 위한 동적 강성 및 주파수 응답 해석)

  • Shin, Hyun-Woo;Chung, Yeon-Jun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.2
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    • pp.141-149
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    • 2009
  • The oil pan is an important factor for the noise behavior of the engine system. In this paper a new Magnesium oil pan was designed and analyzed to replace the current Aluminium oil pan. Dynamic stiffness and sound pressure level of the newly designed Mg oil pan were compared with the AI oil pan using the finite element method. NVH characteristics of the Mg oil pan is slightly insufficient when we changed the material of the oil pan from Al to Mg without modifying the design. Some design modifications of the Mg oil pan resulted in equal or superior characteristics compared to the Al oil pan. New ribs were added to stiffen the structure of the Mg oil pan. Thickness of thin plate area was increased to reduce the radiated noise. Through the changes of shape, higher dynamic stiffness than the current Al oil pan were achieved. Results of frequency response analysis show that we can reduce the sound pressure level of the oil pan if we increase the thickness of the thin plate area. It is shown that the new Mg oil pan could reduce the weight of the engine system and improve NVH quality of an automobile.

Concentrations of Major Minerals and Trace Elements in Sera of The Breast-fed and Formula-fed Infants (모유영양아와 인공영양아의 혈청무기질 및 미량원소 함량비교)

  • 안홍석;박성혜;박윤신
    • Korean Journal of Community Nutrition
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    • v.2 no.2
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    • pp.133-140
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    • 1997
  • The serum concentrations of the major minerals(calcium, phosphorus, magnesium, sodium, potassium) and trace elements(iron, Zinc, copper manganese)were datermined in 23 breast fed infants living in Eumsung, Choong-buk region. The results obtained are summarized as follows: 1)The mean levels of calcium, phosphorus, magnesium, sodium and potassium of the serum of total subjects were 8.15$\pm$0.33mg/dI, 11.06$\pm$0.16mg/dI, 2.00$\pm$0.14mg/dI, 3.4476$\pm$17.99mg/dI and 9.06$\pm$2.04mg/dI respectively. 2)The serum concentrations of iron, zinc, copper and manganese in total subjects averaged 95.83$\pm$0.33mg/dI, 93.79$\pm$7.06$\mu$g/dI and 98.57$\pm$7.06 $\mu$g/dI and 4.93$\pm$0.62$\mu$g/dI respecitively. 3)Breast fed infants had significantly higher serum calcim, magnesium, sodium and iron concentrations than the formula fed groups. Otherwise, serum potassium, copper and manganese levels in breast milk fed infants were significantly lower than those in formula fed infants. 4) In formula fed infants, serum potassium and copper levels increased increased significantly with months after birth.

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Recycling of Waste Bittern from Salt Farm (I) : Recovery of Magnesium (염전 폐간수의 재활용(I) : 마그네슘 회수)

  • Na, Choon-Ki;Park, Hyunju
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.427-432
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    • 2016
  • The purpose of the research was to examine the utilization of waste bittern from salt farm as a source for producing magnesium (Mg). In this work, a precipitation process for recovering Mg, where Mg is precipitated as $Mg(OH)_2$ by the addition of NaOH solution, was investigated. At the NaOH/Mg molar ratios of 2.70 : 1 to 2.75 : 1 and pH 9.5-10, > 99% of Mg could be precipitated from the bittern. The molar concentration of NaOH solution added as an alkaline reagent had no significant influence on the recovery efficiency of Mg precipitate. The particle size of Mg precipitate was strongly affected by the flow rate of caustic addition. The faster the flow rate of caustic addition, the smaller particles were formed. The Mg precipitate recovered was 100-120 g per 1 L of bittern and contained 94% $Mg(OH)_2$ after washing with water. Our results showed that the bittern can be used as a potential resource for Mg production.

Influence of hot deformation and composition on microstructure development of magnesium-stannide alloys

  • Pandel, Divija;Banerjee, Malay K.
    • Advances in materials Research
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    • v.9 no.3
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    • pp.171-187
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    • 2020
  • The microstructural evolution of different compositions of Mg-Sn alloys (30%Sn-70%Mg, 40%Sn-60%Mg and 50%Sn-50%Mg) is studied at first to understand the changes observed with change in tin content and deformation conditions. The Mg2Sn phase increases with increase in tin content and a significant substructure development is found in 50%Sn-50%Mg alloy. The above observation led to further deformation studies on Mg2Sn based thermoelectric materials with higher tin percentage. The microstructure in terms of Electron backscatter diffraction (EBSD)measurements is studied in detail followed by the determination of thermoelectric properties i.e., Seebeck coefficient and electrical conductivity for both as cast and extruded Mg(2+x)Sn-Ag alloys. The electrical conductivity of the extruded Mg(2+x)Sn-.3wt%Ag {x =1} alloy was found to be more than its as cast counterpart while the Seebeck coefficient values remained almost the same.

Effect of MgSO4/MgO on the Synthesis of 5Mg(OH)2·MgSO4·3H2O Whiskers using One-step Ambient Pressure (상압 공정을 이용한 침상형 5Mg(OH)2·MgSO4·3H2O 합성에 대한 MgSO4/MgO 효과)

  • Yu, Ri;Pee, Jae-Hwan;Kim, Hyung Tae;Kim, YooJin
    • Journal of the Korean Ceramic Society
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    • v.50 no.3
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    • pp.201-205
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    • 2013
  • Magnesium hydroxide sulfate hydrate ($5Mg(OH)_2.MgSO_4{\cdot}3H_2O$, abbreviated 513 MHSH) whiskers were synthesized using MgO and $MgSO_4.7H_2O$ as reactants without addition of basic solution. Previously, MHSH whiskers were prepared by hydrothermal method using $MgSO_4$ in aqueous ammonia. In this work, for the first time, we synthesized a high purity MHSH via ambient pressure. In addition, a high molar ratio of $MgSO_4$ : MgO is an important key to the formation of high purity MHSH. Also, it was possible to prepare whiskers with high aspect ratio using an increasing reaction time in the reaction between the remaining $SO_4^{2-}$ ions and the ${Mg(OH)_6}^{4-}$ fragment, finally producing one-dimensional whiskers.

Effects of Magnesium Deficiency on Induction of Activity of Antioxidative Enzymes (Magnesium 결핍이 항산화효소의 활성유도에 미치는 영향)

  • Kim, B.C.;Lee, J.J.
    • Korean Journal of Weed Science
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    • v.17 no.4
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    • pp.431-438
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    • 1997
  • The influence of deficient(7${\mu}M$) and suffcient(1000${\mu}M$) magnesium(Mg) supply on the content of mg, chlorophyll, protein and the activity of superoxide dismutase(SOD), scavengers of superoxide radical($O_2$), and ascorbate peroxidase(AP), $H_2O_2$scavenging enzyme, and glutathione redutase(GR) were studied in pumpkin(Cudurbita moscata $D_{UCHESNE}$) plants over a 11-day period. Over the 11 days Period of growth in nutrient solution with sufficient and deficient Mg supply, the contents of Mg, chlorophyll protein and the activities of the antioxidative enzymes remained more or less constant in Mg-sufficient leaves. In Mg-deficient leaves, the contents of Mg, chlorophyll and protein was seriously decreased with time, however the activities of SOD, AP and GR highly enhanced compared to those of Mg-sufficient. The results indicated the stimulative effect of Mg deficiency on toxic oxygen species and scavenging enzymes in plants.

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