• 제목/요약/키워드: MOD13

검색결과 52건 처리시간 0.027초

DCA-MOD 법으로 YBCO 박막 제조시 하소열처리의 승온속도 효과 (Effect of heating rate on calcination heat treatment of YBCO thin films by DCA-MOD method)

  • 김병주;김혜진;조한우;권연경;유정희;이희균;홍계원
    • Progress in Superconductivity
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    • 제8권2호
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    • pp.186-192
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    • 2007
  • High $J_c\;YBa_2Cu_3O_{7-x}$ superconducting films have been fabricated $LaAlO_3(100)$ substrate by MOD method using dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. Heating rate was varied in order to optimize the calcination heat treatment condition in DCA-MOD method. Coated films were calcined at lower temperature up to $500^{\circ}C$ in flowing humid oxygen atmosphere. The heating rate was calcined from $13.3^{\circ}C/min\;to\;0.28^{\circ}C/min$. Conversion heat treatment was performed $800^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. Surface and cross sectional SEM microstructures showed that particle sizes were increased with heating rate at a calcination step. The amount of pores was increased with heating rate in the calcined films. Dense microstructure and sharp texture were developed in an YBCO films after conversion heat treatment. A high critical current density (Jc) of $1.26MA/cm^2$ (@77 K and self-field) was obtained for the YBCO film which was prepared with a heating rate of $0.28^{\circ}C/min$.

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MOD 방법을 이용한 Bi2Sr2CaCu2O8+d 박막제작 (Bi2Sr2CaCu2O8+d Thin Films Grown on (100) MgO Substrate by Metallorganic Decomposition Method)

  • 김선미;박미화;이기진;차덕준
    • 한국전기전자재료학회논문지
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    • 제16권11호
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    • pp.1035-1040
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    • 2003
  • High $T_{c}$ superconducting B $i_2$S $r_2$CaC $u_2$ $O_{8+d}$ (BSCCO2212) films were prepared by a metallorganic decomposition (MOD) method. The metal organic solution of BSCCO2212 was spin-coated on MgO (100) substrates at 3000 rpm for 1 min. To achieve a high critical current density, we controlled heat-treatment conditions and atmosphere. The films were annealed at temperature 75$0^{\circ}C$ ∼ 80$0^{\circ}C$ in $O_2$ or air. We obtained c-axis orientated BSCCO thin films on MgO substrates. The annealed sample at 77$0^{\circ}C$ with $O_2$ showed the critical temperature about 77 K and critical current denstity of 1.19 ${\times}$ 10$^{5}$ A/$\textrm{cm}^2$ about 13 K.

TFA-MOD 방법에 의한 YBCO 박막제조에서 nano size $Y_2O_3$ 첨가효과 (Effect of nano size $Y_2O_3$ addition on the superconducting properties and microstructure of YBCO thin film prepared by TFA-MOD method.)

  • 박진아;김병주;홍계원;이희균;유재무;김영국
    • 한국초전도ㆍ저온공학회논문지
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    • 제8권3호
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    • pp.13-17
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    • 2006
  • The effect of the addition of the nano size $Y_2O_3$ powder on the microstructurte and superconducting properties of YBCO thin film deposited on LAO single crystalline substrate by TFA-MOD method was studied. Nano size $Y_2O_3$ powder was added to the stoichiometric precursor solution with a cation ratio of Y : Ba . Cu = 1 : 2 : 3 prepared using TFA as chelating agent. Precursor solutions with and without $Y_2O_3$ addition were coated on $LaAlO_3(100)$ single crystalline substrates by dip coating method. Calcination and conversion heat treatments were performed in controlled atmosphere containing moisture Current carrying capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping and it is thought to be due to the better connectivity of YBCO grains and/or the flux pinning by the $Y_2O_3$ particles embedded in YBCO grains.

DCA-MOD 방법으로 제조된 YBCO 박막의 미세조직에 미치는 열처리 효과 (Effects of Heat Treatments on the Microstructure of YBCO Films Prepared by DCA-MOD Method)

  • 김병주;김혜진;조한우;유석구;유정희;이희균;홍계원
    • Progress in Superconductivity
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    • 제9권1호
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    • pp.96-101
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    • 2007
  • [ $YBa_2Cu_3O_{7-{\delta}}$ ] films have been prepared on $LaAlO_3$ (100) single-crystal substrates by a metalorganic deposition using dichloroacetate precursors (DCA-MOD). Calcination conditions were varied in order to optimize the microstructure and the superconducting properties of YBCO film. Coated films were calcined at various temperatures ranging from $400{\sim}700^{\circ}C$ in flowing humid oxygen atmosphere. Ramping rate to calcination tempertures was $2.22^{\circ}C/min$. Conversion heat treatment was performed at $800^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. Observations of surface and cross sectional SEM microstructure showed that the particle size in the calcined film increased in the range of 100-200 nm with heating rate and the calcination temperature. SEM EDS analysis showed that 13 a/o of chlorine was contained in the calcined film. It was also observed that the porosity increased with the heating rate and temperature. Porous microstructure was developed when YBCO films were prepared using porous calcined film. Dense microstructure and high $J_c$ over $1\;MA/cm^2$ was obtained when calcination was carried out at the temperature of $500^{\circ}C$ with a heating rate of $2.22^{\circ}C/min$.

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MOD법에 의한 강유전성 $Sr_xBi_yTa_2O_{9+\alpha}$(SBT) 박막의 제조 및 후열처리 효과에 관한 연구 (Fabrication and Post-Annealing Effects of Ferroelectric $Sr_xBi_yTa_2O_{9+\alpha}$(SBT) Thin Films by MOD Process)

  • 정병직;신동석;윤희성;김병호
    • 한국전기전자재료학회논문지
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    • 제11권3호
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    • pp.229-236
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    • 1998
  • Ferroelectric $Sr_xBi_yTa_2O_{9+\alpha}$/(0.7$\leqSr\leq1.0,\; 2.0\leqBi\leq2.6)$ solutions were prepared by MOD (Metalorganic Deposition) process. These solutions were made into thin films with thickness ranging from 1500~2000${\AA}$ by spin coating. The phase transformation of the SBT thin films by variation of annealing temperature and annealing time were observed using high temperature XRD and SEM. The crystallization and grain growth of SBT thin film were accomplished at $800^{\circ}C$ for 30 minutes after deposition of Pt top electrode by sputtering to prevent electrical breakdown. Ferroelectric properties of the SBT thin films were measured in the range of $\pm$3V\; and\; \pm5V$. The specimen with composition ratio of Sr/Bi/Ta (0.8/2.4/2.0) has the excellent ferroelectric properties ; $2P_r = 10.5,\; 13.2\muC/cm^2 \;at\; \pm3V\; and\; \pm5V$ respectively. Observing the post annealed Pt/SBT/Pt interface by SEM, it was found that Pt electrode sputtered on to the SBT thin film penetrated into the hollow on the SBT thin film, thus decreasing the effective insulation thickness. The effective insulation thickness recovered by post annealing, and this was confirmed by leakage current density measurement.

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POINTS COUNTING ALGORITHM FOR ONE-DIMENSIONAL FAMILY OF GENUS 3 NONHYPERELLIPTIC CURVES OVER FINITE FIELDS

  • Sohn, Gyo-Yong
    • Journal of applied mathematics & informatics
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    • 제30권1_2호
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    • pp.101-109
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    • 2012
  • In this paper, we present an algorithm for computing the number of points on the Jacobian varieties of one-dimensional family of genus 3 nonhyperelliptic curves over finite fields. We also provide the explicit formula of the characteristic polynomial of the Frobenius endomorphism of the Jacobian of $C:y^3=x^4+{\alpha}$ over a finite field $\mathbb{F}_p$ with $p{\equiv}1$ (mod 3) and $p{\neq}1$ (mod 4). Moreover, we give some implementation results using Gaudry-Schost method. A 162-bit order is computed in 97 s on a Pentium IV 2.13 GHz computer using our algorithm.

High-$I_c$ single-coat YBCO films prepared by the MOD process

  • Lee, J.W.;Shin, G.M.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제13권4호
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    • pp.22-25
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    • 2011
  • A single-coat $YBa_2Cu_3O_{7-{\delta}}$ (YBCO) film of high critical currents ($I_c$) could be successfully fabricated by optimizing the viscosity of the coating solution in the metal-organic deposition (MOD) process. From a Ba-deficient coating solution (Y: Ba: Cu = 1: 1.5: 3) having the viscosity of 212 $mPa{\cdot}sec$, 0.9 ${\mu}m$-thick single coat YBCO film with the $I_c$ value of 289 A/cm-width ($J_c$ = 3.2 MA/$cm^2$) at 77 K was achievable on the $SrTiO_3$ (STO) substrate, which was superior to that of our previous report for 0.8 ${\mu}m$-thick single coat YBCO film from a stoichiometric coating solution (Y: Ba: Cu = 1: 2: 3) on the $LaAlO_3$ (LAO) substrate. This result might be attributed to denser and more homogeneous microstrcuture in the case of the YBCO film from the Ba-deficient coating solution.

MODIS NDVI를 이용한 북한의 벼 수량 추정 연구 (A Study on Estimating Rice Yield of North Korea using MODIS NDVI)

  • 홍석영;최은영;김건엽;강신규;김이현;장용선
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2009년도 춘계학술대회 논문집
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    • pp.116-120
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    • 2009
  • 원격탐사 기술은 사람이 직접 방문하여 조사하기 힘든 극지라든가 농업환경에 대한 자료 요구도가 높으면서도 직접 수집이 어려운 비접근 지역에 대한 정보를 추출하는데 유용한 관측수단이다. 본 연구는 MODIS(Moderate Resolution Imaging Spectroradiometer) 제공 산출물 중 16일 단위로 작성되는 NDVI(Normalized Difference Vegetation Index, MOD13)를 이용하여 북한의 벼 수량을 추정하는 것을 목적으로 하였고, 그 가능성과 한계에 대하여 알아보았다. 2000년부터 2008년까지 촬영된 MODIS MOD13 자료를 미국 NASA로부터 제공받아 좌표체계를 우리나라에 맞게 투영하고 NDVI를 추출하여 자료분석에 사용하였다. 통계청에서 발표한 벼 수량 및 생산량 통계자료를 이용하였다. 농촌진흥청 국립농업과학원에서 작성한 북한의 토지피복분류도를 이용하여 서해안 평야지대에 위치한 논을 위도별로 네군데 정하여 관심지역(area of interest)으로 설정하였다. 이 관심지역에 대한 시계열 값을 추출하여 연중 연간 변화를 분석하고 2000년부터 2007년까지 수잉기의 NDVI 값을 이용하여 수량에 대한 상관계수(r)는 $0.77^*$로 5%에서 유의하여 NDVI 값에 따라 벼 수량에 큰 영향을 주는 것으로 나타났다. 수잉기의 NDVI 값과 벼 수량에 대해 회귀분석한 결과($R^2=0.591^*$), NDVI에 따른 벼 수량의 변이를 59.1% 설명할 수 있었다. 이와 같이 회귀식을 이용하여 2008년 북한의 벼 수량은 약 2.80 ton/ha로 추정되었다.

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